Yıl 2021, Cilt 8 , Sayı 1, Sayfalar 9 - 20 2021-02-28

Electrochemical and in-situ spectroelectrochemical behaviors of non-peripherally tetra substituted zinc(II) and magnesium(II) phthalocyanines

Duygu AKYÜZ ÇUBUKÇU [1]


The electrochemical behaviors of non-peripherally tetra substituted zinc(II) and magnesium(II) phthalocyanines were studied at glassy carbon electrode in dimethylformamide using cyclic and square wave voltammetry techniques. Electrochemical mechanisms of complexes were illuminated by using the relationship between scan rate and peak current. The complexes exhibited reversible and diffusion controlled behaviors. The effect of metal center on redox properties of complexes were investigated and compared. Electrochemical results were supported with in-situ spectroelectrochemical measurements. Moreover, the color changes were recorded and observed sharp color transitions during the reduction and oxidation redox process.
Phthalocyanines, electrochemistry, spectroelectrochemistry
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Birincil Dil en
Konular Elektrokimya
Bölüm Makaleler
Yazarlar

Orcid: 0000-0002-9258-9531
Yazar: Duygu AKYÜZ ÇUBUKÇU (Sorumlu Yazar)
Kurum: GEBZE TEKNİK ÜNİVERSİTESİ
Ülke: Turkey


Tarihler

Başvuru Tarihi : 17 Ağustos 2020
Kabul Tarihi : 24 Ekim 2020
Yayımlanma Tarihi : 28 Şubat 2021

Vancouver Akyüz Çubukçu D . Electrochemical and in-situ spectroelectrochemical behaviors of non-peripherally tetra substituted zinc(II) and magnesium(II) phthalocyanines. Journal of the Turkish Chemical Society Section A: Chemistry. 2021; 8(1): 9-20.