Surface Physicochemical Characterization of Shepherd’s Purse (Capsella bursa-pastoris) by Inverse Gas Chromatography

Yıl 2023, Cilt: 10 Sayı: 4, 1071 - 1080, 11.11.2023

Birol Isik

https://doi.org/10.18596/jotcsa.1278025

Öz

Shepherd’s purse (Capsella bursa-pastoris) is one of the plants widely utilized in conventional medicine and can grow in different parts of the world. The determination of the surface properties of a solid material is extremely important for the industrial use of the material and the improvement of material properties. Therefore, in this study, this plant was used as a stationary phase, and its surface characterization was performed by inverse gas chromatography technique. In this context, firstly, the plant was prepared with several pretreatments to be used in the experimental tests. The V_N values were found from the retention data obtained by passing organic solvents over the plant filled into the chromatographic column in the temperature range of 303.2–328.2 K and linear retention diagrams were drawn. The γ_S^D of the plant was calculated according to Schultz, Dorris-Gray, and Donnet-Park methods, and the suitability of the methods was compared. The 〖∆G〗_A^S values were calculated with the data obtained from the Schultz method, and the 〖∆H〗_A^S values were calculated using these data. The acidity and basicity of the plant surface were examined. According to the K_D⁄K_A value (0.93), it was determined that the surface of the plant was acidic.

Anahtar Kelimeler

Adsorption, Surface properties, Inverse gas chromatography, Shepherd’s purse

Kaynakça

• 1. Dettmer-Wilde K, Engewald W. Practical gas chromatography [Internet]. Berlin, Heidelberg: Springer; 2014. 904 p. Available from: <URL>.
• 2. Smidsrød O, Guillet JE. Study of polymer-solute interactions by gas chromatography. Macromolecules [Internet]. 1969 May 1;2(3):272–7. Available from: <URL>.
• 3. Aresta AM, De Vietro N, Picciariello A, Rotelli MT, Altomare DF, Dezi A, et al. Volatile organic compounds determination from intestinal polyps and in exhaled breath by gas chromatography–mass spectrometry. Appl Sci [Internet]. 2023 May 15;13(10):6083. Available from: <URL>.
• 4. Bai W, Pakdel E, Li Q, Wang J, Tang W, Tang B, et al. Inverse gas chromatography (IGC) for studying the cellulosic materials surface characteristics: a mini review. Cellulose [Internet]. 2023 Apr 6;30(6):3379–96. Available from: <URL>.
• 5. Boudriche L, Calvet R, Chamayou A, Hamdi B. Influence of different wet milling on the properties of an attapulgite clay, contribution of inverse gas chromatography. Powder Technol [Internet]. 2021 Jan 22;378:29–39. Available from: <URL>.
• 6. Cakar F, Ocak H, Ozturk E, Mutlu-Yanic S, Kaya D, San N, et al. Investigation of thermodynamic and surface characterisation of 4-[4-(2-ethylhexyloxy)benzoyloxy]benzoic acid thermotropic liquid crystal by inverse gas chromatography. Liq Cryst [Internet]. 2014 Sep 2;41(9):1323–31. Available from: <URL>.
• 7. Yampolskii Y, Belov N. Investigation of polymers by inverse gas chromatography. Macromolecules [Internet]. 2015 Oct 13;48(19):6751–67. Available from: <URL>.
• 8. Cakar F. Synthesis and thermodynamic characterization of poly(methyl methacrylate) /multiwall carbon nanotube nanocomposite. Surf Interface Anal [Internet]. 2021 Feb 4;53(2):258–67. Available from: <URL>.
• 9. Adıgüzel A, Korkmaz B, Çakar F, Cankurtaran, Şenkal BF. Investigation of the surface properties of dibutyl amine modified poly(styrene) based polymer by inverse gas chromatography method. J Polym Res [Internet]. 2021 Mar 1;28(3):83. Available from: <URL>.
• 10. Nawawi WMFW, Lee K-Y, Kontturi E, Bismarck A, Mautner A. Surface properties of chitin-glucan nanopapers from Agaricus bisporus. Int J Biol Macromol [Internet]. 2020 Apr 1;148:677–87. Available from: <URL>.
• 11. Zhu Q-N, Wang Q, Hu Y-B, Abliz X. Practical Determination of the Solubility Parameters of 1-alkyl-3-methylimidazolium bromide ([CnC1im]Br, n = 5, 6, 7, 8) ionic liquids by inverse gas chromatography and the hansen solubility parameter. Molecules [Internet]. 2019 Apr 5;24(7):1346. Available from: <URL>.
• 12. Saada A, Papirer E, Balard H, Siffert B. Determination of the surface properties of illites and kaolinites by inverse gas chromatography. J Colloid Interface Sci [Internet]. 1995 Oct 1;175(1):212–8. Available from: <URL>.
• 13. Cordeiro N, Gouveia C, John MJ. Investigation of surface properties of physico-chemically modified natural fibres using inverse gas chromatography. Ind Crops Prod [Internet]. 2011 Jan 1;33(1):108–15. Available from: <URL>.
• 14. van Asten A, van Veenendaal N, Koster S. Surface characterization of industrial fibers with inverse gas chromatography. J Chromatogr A [Internet]. 2000 Aug 4;888(1–2):175–96. Available from: <URL>.
• 15. Ocak H, Mutlu-Yanic S, Cakar F, Bilgin-Eran B, Guzeller D, Karaman F, et al. A study of the thermodynamical interactions with solvents and surface characterisation of liquid crystalline 5-(( S )-3,7-dimethyloctyloxy)-2-[[[4-(dodecyloxy)phenyl] imino]-methyl]phenol by inverse gas chromato-graphy. J Mol Liq [Internet]. 2016 Nov 1;223:861–7. Available from: <URL>.
• 16. Uhlmann P, Schneider S. Acid–base and surface energy characterization of grafted polyethylene using inverse gas chromatography. J Chromatogr A [Internet]. 2002 Sep 6;969(1–2):73–80. Available from: <URL>.
• 17. Król P, Król B. Determination of free surface energy values for ceramic materials and polyurethane surface-modifying aqueous emulsions. J Eur Ceram Soc [Internet]. 2006 Jan 1;26(12): 2241–8. Available from: <URL>.
• 18. Ugraskan V, Isik B, Yazici O, Cakar F. Surface characterization and synthesis of boron carbide and silicon carbide. Solid State Sci [Internet]. 2021 Aug 1;118:106636. Available from: <URL>.
• 19. Faria PC., Órfão JJ., Pereira MF. Adsorption of anionic and cationic dyes on activated carbons with different surface chemistries. Water Res [Internet]. 2004 Apr 1;38(8):2043–52. Available from: <URL>.
• 20. Nassar NN, Hassan A, Pereira-Almao P. Effect of surface acidity and basicity of aluminas on asphaltene adsorption and oxidation. J Colloid Interface Sci [Internet]. 2011 Aug 1;360(1):233–8. Available from: <URL>.
• 21. Isik B, Cakar F, Cankurtaran O. A comparative study of surface properties of Urtica dioica (nettle) leaves, roots, and seeds and examination of their ability to separate xylene isomers. Phytochem Anal [Internet]. 2022 Aug 29;33(6):886–94. Available from: <URL>.
• 22. Gamelas JAF. The surface properties of cellulose and lignocellulosic materials assessed by inverse gas chromatography: a review. Cellulose [Internet]. 2013 Dec 1;20(6):2675–93. Available from: <URL>.
• 23. Isik B, Avci S, Cakar F, Cankurtaran O. Adsorptive removal of hazardous dye (crystal violet) using bay leaves (Laurus nobilis L.): surface characterization, batch adsorption studies, and statistical analysis. Environ Sci Pollut Res [Internet]. 2023 Jan 2;30(1):1333–56. Available from: <URL>.
• 24. Grosso C, Vinholes J, Silva LR, Pinho PG de, Gonçalves RF, Valentão P, et al. Chemical composition and biological screening of Capsella bursa-pastoris. Rev Bras Farmacogn [Internet]. 2011 Aug;21(4):635–43. Available from: <URL>.
• 25. Al-Snafi AE. The chemical constituents and pharmacological effects of capsella bursa-pastoris-a review. Int J Pharmacol Toxicol [Internet]. 2015;5(2):76–81. Available from: <URL>.
• 26. Al-Douri NA, Al-Essa LY. A survey of plants used in Iraqi traditional medicine. Jordan J Pharm Sci [Internet]. 2010 Jul 12;3(2):100–18. Available from: <URL>.
• 27. Alizadeh H, Club YR, Branch A, Jafari B, Babae T. The Study of Antibacterial Effect of Capsella Bursa-Pastoris on Some of Gram Positive and Gram Negative Bacteria. J Basic Appl Sci Res [Internet]. 2012;2(7):6940–5. Available from: <URL>.
• 28. Ali NS, Jabbar NM, Alardhi SM, Majdi HS, Albayati TM. Adsorption of methyl violet dye onto a prepared bio-adsorbent from date seeds: isotherm, kinetics, and thermodynamic studies. Heliyon [Internet]. 2022 Aug 1;8(8):e10276. Available from: <URL>.
• 29. Işık B, Çakar F, Cankurtaran H, Cankurtaran Ö. Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation. Turkish J Chem [Internet]. 2021 Jun 30;45(3):845–57. Available from: <URL>.
• 30. Erol I, Cakar F, Ocak H, Cankurtaran H, Cankurtaran Ö, Bilgin-Eran B, et al. Thermodynamic and surface characterisation of 4-[4-((S)-citronel-lyloxy)benzoyloxy]benzoic acid thermotropic liquid crystal. Liq Cryst [Internet]. 2016 Jan 2;43(1):142–51. Available from: <URL>.
• 31. Mukhopadhyay P, Schreiber HP. Aspects of acid-base interactions and use of inverse gas chromatography. Colloids Surfaces A Physicochem Eng Asp [Internet]. 1995 Jul 25;100:47–71. Available from: <URL>.
• 32. Isik B, Cakar F, Cankurtaran O, Cankurtaran H. Liquid crystal entrapped porous films for ammonia sensing and determination of surface properties of liquid crystal molecule. ChemistrySelect [Internet]. 2021 Jul 13;6(26):6740–7. Available from: <URL>.
• 33. Ugraskan V, Isik B, Yazici O, Cakar F. Comparative physicochemical characterization of ULTEM/SWCNT nanocomposites: Surface, thermal and electrical conductivity analyses. J Polym Res [Internet]. 2022 Jul 2;29(7):254. Available from: <URL>.
• 34. Ugraskan V, Isik B, Yazici O, Cakar F. Removal of Safranine T by a highly efficient adsorbent (Cotinus Coggygria leaves): Isotherms, kinetics, thermodynamics, and surface properties. Surfaces and Interfaces [Internet]. 2022 Feb 1;28:101615. Available from: <URL>.
• 35. Dorris GM, Gray DG. Adsorption of n-alkanes at zero surface coverage on cellulose paper and wood fibers. J Colloid Interface Sci [Internet]. 1980 Oct 1;77(2):353–62. Available from: <URL>.
• 36. Donnet J-B, Park S-J. Surface characteristics of pitch-based carbon fibers by inverse gas chromatography method. Carbon N Y [Internet]. 1991 Jan 1;29(7):955–61. Available from: <URL>.
• 37. Donnet JB, Park SJ, Balard H. Evaluation of specific interactions of solid surfaces by inverse gas chromatography. Chromatographia [Internet]. 1991 May;31(9–10):434–40. Available from: <URL>.
• 38. Donnet JB, Park SJ, Brendle M. The effect of microwave plasma treatment on the surface energy of graphite as measured by inverse gas chromatography. Carbon N Y [Internet]. 1992 Jan 1;30(2):263–8. Available from: <URL>.
• 39. Schultz J, Lavielle L, Martin C. The Role of the interface in carbon fibre-epoxy composites. J Adhes [Internet]. 1987 Sep 3;23(1):45–60. Available from: <URL>.
• 40. Pérez-Mendoza M, Almazán-Almazán MC, Méndez-Liñán L, Domingo-García M, López-Garzón FJ. Evaluation of the dispersive component of the surface energy of active carbons as determined by inverse gas chromatography at zero surface coverage. J Chromatogr A [Internet]. 2008 Dec 19;1214(1–2):121–7. Available from: <URL>.
• 41. Sreekanth TVM, Basivi PK, Nagajyothi PC, Dillip GR, Shim J, Ko TJ, et al. Determination of surface properties and Gutmann’s Lewis acidity–basicity parameters of thiourea and melamine polymerized graphitic carbon nitride sheets by inverse gas chromatography. J Chromatogr A [Internet]. 2018 Dec 14;1580:134–41. Available from: <URL>.
• 42. Papadopoulou SK, Papaiconomou N, Baup S, Iojoiu C, Svecova L, Thivel P-X. Surface characterization of 1-butyl-1-ethylpiperidinium bro-mide by inverse gas chromatography. J Mol Liq [Internet]. 2019 Aug 1;287:110945. Available from: <URL>.
• 43. Wang Q, Wang Q. Evaluation of the surface properties of poly(ionic liquid) materials by inverse gas chromatography. Eur Polym J [Internet]. 2020 Jan 15;123:109451. Available from: <URL>.
• 44. Isik B, Cakar F, Cankurtaran O. The study on cholesteryl chloroformate liquid crystal for separation of isomers and determination of its surface properties. Sep Sci Technol [Internet]. 2022 Nov 22;57(17):2843–51. Available from: <URL>.
• 45. Santos JMRCA, Guthrie JT. Study of a core-shell type impact modifier by inverse gas chromatography. J Chromatogr A [Internet]. 2005 Apr 8;1070(1–2):147–54. Available from: <URL>.
• 46. Santos JMRCA, Guthrie JT. Analysis of interactions in multicomponent polymeric systems: The key-role of inverse gas chromatography. Mater Sci Eng R Reports [Internet]. 2005 Oct 31;50(3):79–107. Available from: <URL>.
• 47. Santos JMRCA, Fagelman K, Guthrie J. Characterisation of the surface Lewis acid–base properties of poly(butylene terephthalate) by inverse gas chromatography. J Chromatogr A [Internet]. 2002 Sep 6;969(1–2):111–8. Available from: <URL>.
• 48. Gutmann V. The donor-acceptor approach to molecular interactions [Internet]. Springer New York, NY; 1978. 279 p. Available from: <URL>.
• 49. Bauer F, Meyer R, Czihal S, Bertmer M, Decker U, Naumov S, et al. Functionalization of porous siliceous materials, Part 2: Surface characterization by inverse gas chromatography. J Chromatogr A [Internet]. 2019 Oct 11;1603:297–310. Available from: <URL>.