Smart Dimethylacrylamide/Gelatin–Rosa Hydrogels for Application in Food Packaging Materials
Abstract
A multifunctional bio-based hydrogel, p(Gelatin-co- N,N-dimethylacrylamide) Citric acid-Rosa Extract (p(Gelatin-co-DMAAm)/CA-RE), was developed as a smart food packaging material. Synthesized via redox polymerization of N,N-dimethylacrylamide, gelatin, citric acid, and Rosa extract (RE), the hydrogel formed robust films with enhanced mechanical strength and water resistance through crosslinking with citric acid and MBA. Entrapped RE imparted antioxidant, antimicrobial, and pH-responsive colorimetric properties, enabling real-time monitoring of food freshness. Characterization by Thermo-gravimetric, Fourier transform infrared spectroscopy, Dynamic mechanical analysis and Scanning Electron Microscopy (DMA, TGA, FT-IR, and SEM) confirmed network formation, thermal stability up to 527°C, and molecular interactions between polymer components and RE. The hydrogel exhibited effective antimicrobial activity against Escherichia coli, Bacillus subtilis, and Staphylococcus aureus, while rapid and visible color changes under varying pH highlighted its sensing capability. Application to pasteurized milk and cheese demonstrated simultaneous microbial inhibition and spoilage detection. The combination of mechanical robustness, bioactivity, and intelligent colorimetric response positions p(Gelatin-co-DMAAm)/CA-RE as a sustainable, multifunctional smart packaging platform with potential extensions to biomedical and other functional material applications.
Keywords
References
- Abou-Arab, A. A., Abu-Salem, F. M., & Abou-Arab, E. A. (2011). Physico-chemical properties of natural pigments (anthocyanin) extracted from Roselle calyces (Hibiscus subdariffa). Journal of American Science, 7(7), 445–456.
- Alpaslan, D. (2019). Use of colorimetric hydrogel as an indicator for food packaging applications. Bulletin of Materials Science, 42(5), 247. https://doi.org/10.1007/s12034-019-1908-z
- Alpaslan, D., Sahiner, M., Yuceer, Y., Akcali, A., Aktas, N., & Sahiner, N. (2016). Milk hydrogels as nutrient media and survival rate enhancer under cryogenic conditions for different microorganisms. Polymer Bulletin, 73(12), 3351–3370. https://doi.org/10.1007/s00289-016-1660-0
- Angelov, G., Boyadzhieva, S., & Georgieva, S. (2014). Rosehip extraction: Process optimization and antioxidant capacity of extracts. Open Chemistry, 12(4), 502–508. https://doi.org/10.2478/s11532-013-0395-0 Baranac, J. M., Petranović, N. A., & Dimitrić-Marković, J. M. (1996). Spectrophotometric Study of Anthocyan Copigmentation Reactions. Journal of Agricultural and Food Chemistry, 44(5), 1333–1336. https://doi.org/10.1021/jf950420l
- Biji, K. B., Ravishankar, C. N., Mohan, C. O., & Srinivasa Gopal, T. K. (2015). Smart packaging systems for food applications: A review. Journal of Food Science and Technology, 52(10), 6125–6135. https://doi.org/10.1007/s13197-015-1766-7
- Bobelyn, E., Hertog, M. L. A. T. M., & Nicolaï, B. M. (2006). Applicability of an enzymatic time temperature integrator as a quality indicator for mushrooms in the distribution chain. Postharvest Biology and Technology, 42(1), 104–114. https://doi.org/10.1016/j.postharvbio.2006.05.011
- Bondre, S., Patil, P., Kulkarni, A., & Pillai, M. (2012). Study on isolation and purification of anthocyanins and its application as pH indicator. International Journal of Advanced Biotechnology and Research, 3(3), 698–702.
- Bot, A., Van Amerongen, I. A., Groot, R. D., Hoekstra, N. L., & Agterof, W. G. M. (1996). Large deformation rheology of gelatin gels. Polymer Gels and Networks, 4(3), 189–227. https://doi.org/10.1016/0966-7822(96)00011-1
Details
Primary Language
English
Subjects
Polymer Science and Technologies
Journal Section
Research Article
Authors
Duygu Alpaslan
*
0000-0002-6007-3397
Türkiye
Publication Date
May 16, 2026
Submission Date
October 27, 2025
Acceptance Date
January 30, 2026
Published in Issue
Year 2026 Volume: 2026
