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REMOVAL OF HEXAVALENT CHROMIUM FROM WATER BY USING NATURAL BROWN CLAY

Yıl 2017, Özel Sayı 2, 43 - 52, 23.11.2017

Öz

The present study investigates the removal of chromium from aqueous solution, by natural Algerian brown clay, in batch mode, at different temperatures. Kinetic experiment showed that the adsorption process can be simulated by pseudo-second order model. In order to determine the best-fit-isotherm, the experimental data were analyzed by the Freundlich, Langmuir, Temkin and Dubinin-Radushkevich equation, at different temperatures of 20, 30, 40 and 50°C. The mean deviation obtained from the four models revealed that Freundlich is the most suitable one. The results showed that natural brown clay is effective to remove chromium (VI) about 90% at 20°C.



Kaynakça

  • Alonso, A.I., Galán, B., González, M., Ortiz, I., 1999. Experimental and theoretical analysis of a nondispersive solvent extraction pilot plant for the removal of Cr(VI) from a galvanic process wastewaters, Ind. Eng. Chem. Res., 38, 1666.
  • Arfaouia, S., Frini-Srasraa, N., Srasra, E., 2008. Modelling of the adsorption of the chromium ion by modified clays, Desalination, 222, 474.
  • Barkat, M., Chegrouche, S., Mellah, A., Bensmain, B., Nibou, D., Boufatit, M., 2014. Application of algerian bentonite in the removal of cadmium (II) and chromium (VI) from aqueous solutions, J. Surf. Eng. Mater. Adv. Technol., 4, 210.
  • El-Taweel, Y.A., Nassef, E.M., Elkheriany, I., Sayed, D., 2015. Removal of Cr(VI) ions from waste water by electrocoagulation using iron electrode, Egyptian Journal of Petroleum, 24(2), 183.
  • Hafez, A., El-Manharawy, S., 2004. Design and performance of the two-stage/two-pass RO membrane system for chromium removal from tannery wastewater. Part 3, Desalination, 165, 141.
  • Ho, Y.S., McKay, G., 1999. Pseudo-scond order model for sorption process, Process Biochem, 34, 451.
  • Hsu, L.C., Wang, S.L., Lin, Y.C., Wang, M.K., Chiang, P.N., Liu, J.C., Kuan, W.H., Chen, C.C., Tzou, Y.M., 2010. Cr(VI) removal on fungal biomass of neurospora crassa: the importance of dissolved organic carbons derived from the biomass to Cr(VI) reduction, Environ. Sci. Technol. 44, 6202.
  • Kashif Uddin, M., 2017. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade, J. Chem. Eng., 308, 438.
  • Lagergren, S., 1898. Zur theorie Der sogenanntenadsorption gel ster stoffe. Kung-liga Svenska Vetenakapsakademiens Handlingar, 24, 1.
  • Rengaraj, S., Kyeong-Ho Yeon, Seung-Hyeon Moon, 2001. Removal of chromium from water and wastewater by ion exchange resins, J. Hazard.Mater., 87(1-3), 273.
  • Wanees, S. A., Ahmed, A.M., Adam, M.S., Mohamed, M.A., 2013. Adsorption Studies on the Removal of Hexavalent Chromium-Contaminated Wastewater, Asian Journal of Chemistry, 25(15), 8245.
  • Yuan, P., Liu, D., Fan., M., Yang, D., Zhu, R., Ge, F., Zhu, J., He, H., 2010. Removal of Hexavalent Chromium [Cr(VI)] from Aqueous Solutions by the Diatomite-Supported/Unsupported Magnetite Nanoparticles, J. Hazard. Mater., 173, 614.
  • Zhan, Y.B., Shukla, A., Shukls, S., Dorris, K.L., 2000.The removal of heavy metal from aqueous solutions by sawdust adsorption - removal of copper, J. Hazard. Mater., 80, 33.
Yıl 2017, Özel Sayı 2, 43 - 52, 23.11.2017

Öz

Kaynakça

  • Alonso, A.I., Galán, B., González, M., Ortiz, I., 1999. Experimental and theoretical analysis of a nondispersive solvent extraction pilot plant for the removal of Cr(VI) from a galvanic process wastewaters, Ind. Eng. Chem. Res., 38, 1666.
  • Arfaouia, S., Frini-Srasraa, N., Srasra, E., 2008. Modelling of the adsorption of the chromium ion by modified clays, Desalination, 222, 474.
  • Barkat, M., Chegrouche, S., Mellah, A., Bensmain, B., Nibou, D., Boufatit, M., 2014. Application of algerian bentonite in the removal of cadmium (II) and chromium (VI) from aqueous solutions, J. Surf. Eng. Mater. Adv. Technol., 4, 210.
  • El-Taweel, Y.A., Nassef, E.M., Elkheriany, I., Sayed, D., 2015. Removal of Cr(VI) ions from waste water by electrocoagulation using iron electrode, Egyptian Journal of Petroleum, 24(2), 183.
  • Hafez, A., El-Manharawy, S., 2004. Design and performance of the two-stage/two-pass RO membrane system for chromium removal from tannery wastewater. Part 3, Desalination, 165, 141.
  • Ho, Y.S., McKay, G., 1999. Pseudo-scond order model for sorption process, Process Biochem, 34, 451.
  • Hsu, L.C., Wang, S.L., Lin, Y.C., Wang, M.K., Chiang, P.N., Liu, J.C., Kuan, W.H., Chen, C.C., Tzou, Y.M., 2010. Cr(VI) removal on fungal biomass of neurospora crassa: the importance of dissolved organic carbons derived from the biomass to Cr(VI) reduction, Environ. Sci. Technol. 44, 6202.
  • Kashif Uddin, M., 2017. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade, J. Chem. Eng., 308, 438.
  • Lagergren, S., 1898. Zur theorie Der sogenanntenadsorption gel ster stoffe. Kung-liga Svenska Vetenakapsakademiens Handlingar, 24, 1.
  • Rengaraj, S., Kyeong-Ho Yeon, Seung-Hyeon Moon, 2001. Removal of chromium from water and wastewater by ion exchange resins, J. Hazard.Mater., 87(1-3), 273.
  • Wanees, S. A., Ahmed, A.M., Adam, M.S., Mohamed, M.A., 2013. Adsorption Studies on the Removal of Hexavalent Chromium-Contaminated Wastewater, Asian Journal of Chemistry, 25(15), 8245.
  • Yuan, P., Liu, D., Fan., M., Yang, D., Zhu, R., Ge, F., Zhu, J., He, H., 2010. Removal of Hexavalent Chromium [Cr(VI)] from Aqueous Solutions by the Diatomite-Supported/Unsupported Magnetite Nanoparticles, J. Hazard. Mater., 173, 614.
  • Zhan, Y.B., Shukla, A., Shukls, S., Dorris, K.L., 2000.The removal of heavy metal from aqueous solutions by sawdust adsorption - removal of copper, J. Hazard. Mater., 80, 33.
Toplam 13 adet kaynakça vardır.

Ayrıntılar

Konular Mühendislik
Bölüm Makaleler
Yazarlar

Latifa Bentchikou Bu kişi benim

Fatma-zohra Mechelouf Bu kişi benim

Feyza Neggaz Bu kişi benim

Abdelhamid Mellah Bu kişi benim

Yayımlanma Tarihi 23 Kasım 2017
Gönderilme Tarihi 12 Aralık 2017
Kabul Tarihi 21 Aralık 2017
Yayımlandığı Sayı Yıl 2017 Özel Sayı 2

Kaynak Göster

APA Bentchikou, L., Mechelouf, F.-z., Neggaz, F., Mellah, A. (2017). REMOVAL OF HEXAVALENT CHROMIUM FROM WATER BY USING NATURAL BROWN CLAY. Journal of the Turkish Chemical Society Section B: Chemical Engineering, 1(Sp. is. 2), 43-52.

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This piece of scholarly information is licensed under Creative Commons Atıf-GayriTicari-AynıLisanslaPaylaş 4.0 Uluslararası Lisansı.

J. Turk. Chem. Soc., Sect. B: Chem. Eng. (JOTCSB)