Research Article
BibTex RIS Cite

Synthesis and characterization of Y-doped AlZn2O4 spinels

Year 2021, Volume: 4 Issue: 1, 8 - 12, 02.08.2021

Hanifi Kebiroglu , Ala Hssaın , Bahroz Kareem Mahmood Omer Kaygili

Abstract

Zinc aluminum oxide (ZnAl2O4) type spinel samples doped with Y at various amounts of 0, 5, 10, and 15 at.% were produced and characterized for this study. Both X-ray diffraction (XRD) and Fourier transform infrared (FTIR) analyses confirmed the formation of the ZnAl2O4 phase for all the samples. For the spinels doped with Y at the amounts of 10 and 15 at.%, the formation of the secondary phase of Y2O3 was detected. The average crystallite size, lattice constant, unit cell volume, and crystallinity were affected by Y content, as well as the morphology.

Keywords

Spinel Crystal structure Morphology

References

  • D. Dwibedi, C. Murugesan, M. Leskes and P. Barpanda, Role of annealing temperature on cation ordering in hydrothermally prepared zinc aluminate (ZnAl2O4) spinel, Mater. Res. Bull., 2018, 98, 219–224.
  • M. Kumar and S.K. Gupta, An insight into optical spectroscopy of intense green emitting ZnAl2O4: Tb3+ nanoparticles: photo, thermally stimulated luminescence and EPR study, J. Lumin, 2015, 168, 151–157.
  • P. Kumari, Y. Dwivedi and A. Bahadur, Analysis of bright red-orange emitting Mn2+: ZnAl2O4 spinel nanophosphor, Optik, 2018, 154, 126–132.
  • A. Belyaev, L. Basyrova, V. Sysoev, M. Lelet, S. Balabanov, V. Kalganov, V. Mikhailovski, M. Baranov, E. Stepanidenko, V. Vitkin, O. Dymshits and P. Loiko, Microstructure, doping and optical properties of Co2+: ZnAl2O4 transparent ceramics for saturable absorbers: Effect of the ZnF2 sintering additive, J. Alloys Compd, 2020, 829, 154514.
  • M. Mohapatra, M. Kumar and R.M. Kadam, Trap level spectroscopic investigations of U: ZnAl2O4: Role of defect centres in the TSL process, J Phys Chem Solids, 2018, 114, 83–87.
  • S.F. Wang, Y.T. Tsai and J.P.Chu, Resistive switching characteristics of a spinel ZnAl2O4 thin film prepared by radio frequency sputtering, Ceram. Int., 2016, 42, 17673–17679.
  • A. Movasati, S.M. Alavi and G. Mazloom, Dry reforming of methane over CeO2-ZnAl2O4 supported Ni and Ni-Co nanocatalysts, Fuel, 2019, 236, 1254–1262.
  • R. Yang, A. Han, M. Ye, X. Chen and L. Yuan, The influence of Mn/N-codoping on the thermal performance of ZnAl2O4 as high near-infrared reflective inorganic pigment, J. Alloys Compd., 2017, 696, 1329-1341.
  • T.K. Parya, R.K. Bhattacharyya, S. Banerjee and U.B. Adhikari, Co-precipitated ZnAl2O4 spinel precursor as potential sintering aid for pure alumina system, Ceram. Int., 2010, 36, 1211–1215.
  • R. Ianoş, R. Băbuţă, C. Păcurariu, R. Lazău, R. Istratie and C. Butaciu, Combustion synthesis of ZnAl2O4 powders with tuned surface area, Ceram. Int., 2017, 43, 8975–8981.
  • Q. Pan, S. Ye, D. Yang, J. Qiu and G. Dong, Multifunctional magnetic-fluorescent Ni-doped ZnAl2O4 nanoparticles with second biological NIR window fluorescence, Mater. Res. Bull., 2017, 93, 310–317.
  • D. Zhang, Y. Yin, Y. Liu, W. Chao and Y. Zhai, The photoluminescence and magnetic properties of ZnAl2O4: Mn nanocrystals, J Phys Chem Solids, 2013, 74, 1131–1135.
  • N. Peillon, F. Zuo, C. Meunier, S. Saunier, S. Marinel and D. Goeuriot, In-situ studies on preparation of ZnAl2O4 spinel using microwave reactive sintering technique, Mater. Lett., 2016, 167, 77–80.
  • A.D. Ballarini, S.A. Bocanegra, A.A. Castro, S.R. de Miguel and O.A. Scelza, Characterization of ZnAl2O4 obtained by different methods and used as catalytic support of Pt., Catal. Lett., 2009, 129, 293–302.
  • A.V. Belyaev, M.I. Lelet, N.I. Kirillova, N.M. Khamaletdinova, M.S. Boldin, A.A. Murashov and S.S. Balabanov, Sol-gel synthesis and characterization of ZnAl2O4 powders for transparent ceramics, Ceram. Int., 2019, 45, 4835–4839.
  • O. Kaygili, N. Bulut, T. Ates, I. Ercan, S. Koytepe, T. Seckin, C. Tatar, B. Gunduz and H. Kebiroglu, Structural and thermal properties of Zn-containing magnesium aluminate spinels obtained by wet chemical method, Mater. Sci.-Poland, 2019, 37, 238-243.
  • O. Kaygili, Synthesis and characterization of Na2O–CaO–SiO2 glass–ceramic, J. Therm. Anal. Calorim, 2014, 117, 223–227.
  • P.K. Haldar, S. Dey, S. Mukhopadhyay and T.K. Parya, Structural and optical properties of Ti4+ doped sintered ZnAl2O4 ceramics, Interceram. - Int. Ceram. Rev., 2014, 63, 382–385.
  • T.S. Nirmala, N. Iyandurai, S. Yuvaraj and M. Sundararajan, Effect of Cu2+ ions on structural, morphological, optical and magnetic behaviors of ZnAl2O4 spinel, Mater. Res. Express, 2020, 7, 046104.
  • M.K. Habibi, S.M. Rafiaei, A. Alhaji and M. Zare, ZnAl2O4: Ce3+ phosphors: Study of crystal structure, microstructure, photoluminescence properties and efficient adsorption of Congo red dye, J. Mol. Struct., 2021, 1228, 129769.
  • W. Mekprasart, K. Boonyarattanakalin, W. Pecharapa and K.N. Ishihara, Optical characteristics of samarium doped ZnAl2O4 nanomaterials synthesized by vibrational milling process, Mater. Today-Proc., 2018, 5, 14126–14130.
  • W. Staszak, M. Zawadzki and J. Okal, Solvothermal synthesis and characterization of nanosized zinc aluminate spinel used in iso-butane combustion, J. Alloys Compd., 2010, 492, 500–507.

Year 2021, Volume: 4 Issue: 1, 8 - 12, 02.08.2021

Hanifi Kebiroglu , Ala Hssaın , Bahroz Kareem Mahmood Omer Kaygili

Abstract

References

  • D. Dwibedi, C. Murugesan, M. Leskes and P. Barpanda, Role of annealing temperature on cation ordering in hydrothermally prepared zinc aluminate (ZnAl2O4) spinel, Mater. Res. Bull., 2018, 98, 219–224.
  • M. Kumar and S.K. Gupta, An insight into optical spectroscopy of intense green emitting ZnAl2O4: Tb3+ nanoparticles: photo, thermally stimulated luminescence and EPR study, J. Lumin, 2015, 168, 151–157.
  • P. Kumari, Y. Dwivedi and A. Bahadur, Analysis of bright red-orange emitting Mn2+: ZnAl2O4 spinel nanophosphor, Optik, 2018, 154, 126–132.
  • A. Belyaev, L. Basyrova, V. Sysoev, M. Lelet, S. Balabanov, V. Kalganov, V. Mikhailovski, M. Baranov, E. Stepanidenko, V. Vitkin, O. Dymshits and P. Loiko, Microstructure, doping and optical properties of Co2+: ZnAl2O4 transparent ceramics for saturable absorbers: Effect of the ZnF2 sintering additive, J. Alloys Compd, 2020, 829, 154514.
  • M. Mohapatra, M. Kumar and R.M. Kadam, Trap level spectroscopic investigations of U: ZnAl2O4: Role of defect centres in the TSL process, J Phys Chem Solids, 2018, 114, 83–87.
  • S.F. Wang, Y.T. Tsai and J.P.Chu, Resistive switching characteristics of a spinel ZnAl2O4 thin film prepared by radio frequency sputtering, Ceram. Int., 2016, 42, 17673–17679.
  • A. Movasati, S.M. Alavi and G. Mazloom, Dry reforming of methane over CeO2-ZnAl2O4 supported Ni and Ni-Co nanocatalysts, Fuel, 2019, 236, 1254–1262.
  • R. Yang, A. Han, M. Ye, X. Chen and L. Yuan, The influence of Mn/N-codoping on the thermal performance of ZnAl2O4 as high near-infrared reflective inorganic pigment, J. Alloys Compd., 2017, 696, 1329-1341.
  • T.K. Parya, R.K. Bhattacharyya, S. Banerjee and U.B. Adhikari, Co-precipitated ZnAl2O4 spinel precursor as potential sintering aid for pure alumina system, Ceram. Int., 2010, 36, 1211–1215.
  • R. Ianoş, R. Băbuţă, C. Păcurariu, R. Lazău, R. Istratie and C. Butaciu, Combustion synthesis of ZnAl2O4 powders with tuned surface area, Ceram. Int., 2017, 43, 8975–8981.
  • Q. Pan, S. Ye, D. Yang, J. Qiu and G. Dong, Multifunctional magnetic-fluorescent Ni-doped ZnAl2O4 nanoparticles with second biological NIR window fluorescence, Mater. Res. Bull., 2017, 93, 310–317.
  • D. Zhang, Y. Yin, Y. Liu, W. Chao and Y. Zhai, The photoluminescence and magnetic properties of ZnAl2O4: Mn nanocrystals, J Phys Chem Solids, 2013, 74, 1131–1135.
  • N. Peillon, F. Zuo, C. Meunier, S. Saunier, S. Marinel and D. Goeuriot, In-situ studies on preparation of ZnAl2O4 spinel using microwave reactive sintering technique, Mater. Lett., 2016, 167, 77–80.
  • A.D. Ballarini, S.A. Bocanegra, A.A. Castro, S.R. de Miguel and O.A. Scelza, Characterization of ZnAl2O4 obtained by different methods and used as catalytic support of Pt., Catal. Lett., 2009, 129, 293–302.
  • A.V. Belyaev, M.I. Lelet, N.I. Kirillova, N.M. Khamaletdinova, M.S. Boldin, A.A. Murashov and S.S. Balabanov, Sol-gel synthesis and characterization of ZnAl2O4 powders for transparent ceramics, Ceram. Int., 2019, 45, 4835–4839.
  • O. Kaygili, N. Bulut, T. Ates, I. Ercan, S. Koytepe, T. Seckin, C. Tatar, B. Gunduz and H. Kebiroglu, Structural and thermal properties of Zn-containing magnesium aluminate spinels obtained by wet chemical method, Mater. Sci.-Poland, 2019, 37, 238-243.
  • O. Kaygili, Synthesis and characterization of Na2O–CaO–SiO2 glass–ceramic, J. Therm. Anal. Calorim, 2014, 117, 223–227.
  • P.K. Haldar, S. Dey, S. Mukhopadhyay and T.K. Parya, Structural and optical properties of Ti4+ doped sintered ZnAl2O4 ceramics, Interceram. - Int. Ceram. Rev., 2014, 63, 382–385.
  • T.S. Nirmala, N. Iyandurai, S. Yuvaraj and M. Sundararajan, Effect of Cu2+ ions on structural, morphological, optical and magnetic behaviors of ZnAl2O4 spinel, Mater. Res. Express, 2020, 7, 046104.
  • M.K. Habibi, S.M. Rafiaei, A. Alhaji and M. Zare, ZnAl2O4: Ce3+ phosphors: Study of crystal structure, microstructure, photoluminescence properties and efficient adsorption of Congo red dye, J. Mol. Struct., 2021, 1228, 129769.
  • W. Mekprasart, K. Boonyarattanakalin, W. Pecharapa and K.N. Ishihara, Optical characteristics of samarium doped ZnAl2O4 nanomaterials synthesized by vibrational milling process, Mater. Today-Proc., 2018, 5, 14126–14130.
  • W. Staszak, M. Zawadzki and J. Okal, Solvothermal synthesis and characterization of nanosized zinc aluminate spinel used in iso-butane combustion, J. Alloys Compd., 2010, 492, 500–507.
There are 22 citations in total.

Details

Primary Language English
Subjects Metrology, Applied and Industrial Physics
Journal Section Articles
Authors

Hanifi Kebiroglu 0000-0002-6764-3364

Ala Hssaın 0000-0001-9774-0555

Bahroz Kareem Mahmood This is me 0000-0003-3579-3955

Omer Kaygili 0000-0002-2321-1455

Publication Date August 2, 2021
Submission Date April 18, 2021
Acceptance Date May 3, 2021
Published in Issue Year 2021 Volume: 4 Issue: 1

Cite

APA Kebiroglu, H., Hssaın, A., Kareem Mahmood, B., Kaygili, O. (2021). Synthesis and characterization of Y-doped AlZn2O4 spinels. Journal of Physical Chemistry and Functional Materials, 4(1), 8-12.
AMA Kebiroglu H, Hssaın A, Kareem Mahmood B, Kaygili O. Synthesis and characterization of Y-doped AlZn2O4 spinels. Journal of Physical Chemistry and Functional Materials. August 2021;4(1):8-12.
Chicago Kebiroglu, Hanifi, Ala Hssaın, Bahroz Kareem Mahmood, and Omer Kaygili. “Synthesis and Characterization of Y-Doped AlZn2O4 Spinels”. Journal of Physical Chemistry and Functional Materials 4, no. 1 (August 2021): 8-12.
EndNote Kebiroglu H, Hssaın A, Kareem Mahmood B, Kaygili O (August 1, 2021) Synthesis and characterization of Y-doped AlZn2O4 spinels. Journal of Physical Chemistry and Functional Materials 4 1 8–12.
IEEE H. Kebiroglu, A. Hssaın, B. Kareem Mahmood, and O. Kaygili, “Synthesis and characterization of Y-doped AlZn2O4 spinels”, Journal of Physical Chemistry and Functional Materials, vol. 4, no. 1, pp. 8–12, 2021.
ISNAD Kebiroglu, Hanifi et al. “Synthesis and Characterization of Y-Doped AlZn2O4 Spinels”. Journal of Physical Chemistry and Functional Materials 4/1 (August 2021), 8-12.
JAMA Kebiroglu H, Hssaın A, Kareem Mahmood B, Kaygili O. Synthesis and characterization of Y-doped AlZn2O4 spinels. Journal of Physical Chemistry and Functional Materials. 2021;4:8–12.
MLA Kebiroglu, Hanifi et al. “Synthesis and Characterization of Y-Doped AlZn2O4 Spinels”. Journal of Physical Chemistry and Functional Materials, vol. 4, no. 1, 2021, pp. 8-12.
Vancouver Kebiroglu H, Hssaın A, Kareem Mahmood B, Kaygili O. Synthesis and characterization of Y-doped AlZn2O4 spinels. Journal of Physical Chemistry and Functional Materials. 2021;4(1):8-12.