Investigation of hydrazine electrooxidation performance of carbon nanotube supported Pd monometallic direct hydrazine fuel cell anode catalysts

Ömer Er; Ali Cavak; Adnan Aldemir; Hilal Demir Kıvrak

doi:10.51354/mjen.801182

EN

Investigation of hydrazine electrooxidation performance of carbon nanotube supported Pd monometallic direct hydrazine fuel cell anode catalysts

Abstract

In this study, carbon nanotube (CNT) supported Pd catalysts at varying Pd molar ratios are prepared via NaBH4 reduction method. Catalysts prepared for hydrazine electrooxidation are characterized via N2 adsorption-desorption measurements (BET), X-ray photoelectron spectroscopy (XPS), and transmission electron microscope (TEM). Electrochemical measurements are performed using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques by CHI660E potentiostat in a three-electrode system. According to the characterization results, Pd/CNT catalysts are successfully synthesized. For 5% Pd/CNT catalyst, the average particle size and the surface area determined as 5.17 nm and 773.10 m2 g-1 via TEM and BET, respectively. Between the Pd containing (0.1-20 wt %) CNT supported catalysts prepared, 5% Pd / CNT catalyst shows the best current density as 6.81 mA cm-2 (1122.63 mA mg-1 Pd). Furthermore, 5% Pd/CNT catalyst shows littlest charge transfer resistance (Rct) compared to Pd/CNT catalysts.

Keywords

Pd, carbon nanotube, hydrazine, electrooxidation, direct liquid fuel cells, anode, characterization

References

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Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Ömer Er This is me
0000-0002-7179-726X
Türkiye

Ali Cavak This is me
0000-0003-1531-9623
Türkiye

Adnan Aldemir
0000-0001-9884-0961
Türkiye

Hilal Demir Kıvrak ^*
0000-0001-8001-7854
Türkiye

Publication Date

December 21, 2020

Submission Date

September 28, 2020

Acceptance Date

December 2, 2020

Published in Issue

Year 2020 Volume: 8 Number: 2

DOI

https://doi.org/10.51354/mjen.801182

IZ

https://izlik.org/JA89JB74SS

APA

Er, Ö., Cavak, A., Aldemir, A., & Demir Kıvrak, H. (2020). Investigation of hydrazine electrooxidation performance of carbon nanotube supported Pd monometallic direct hydrazine fuel cell anode catalysts. MANAS Journal of Engineering, 8(2), 90-98. https://doi.org/10.51354/mjen.801182

AMA

1.Er Ö, Cavak A, Aldemir A, Demir Kıvrak H. Investigation of hydrazine electrooxidation performance of carbon nanotube supported Pd monometallic direct hydrazine fuel cell anode catalysts. MJEN. 2020;8(2):90-98. doi:10.51354/mjen.801182

Chicago

Er, Ömer, Ali Cavak, Adnan Aldemir, and Hilal Demir Kıvrak. 2020. “Investigation of Hydrazine Electrooxidation Performance of Carbon Nanotube Supported Pd Monometallic Direct Hydrazine Fuel Cell Anode Catalysts”. MANAS Journal of Engineering 8 (2): 90-98. https://doi.org/10.51354/mjen.801182.

EndNote

Er Ö, Cavak A, Aldemir A, Demir Kıvrak H (December 1, 2020) Investigation of hydrazine electrooxidation performance of carbon nanotube supported Pd monometallic direct hydrazine fuel cell anode catalysts. MANAS Journal of Engineering 8 2 90–98.

IEEE

[1]Ö. Er, A. Cavak, A. Aldemir, and H. Demir Kıvrak, “Investigation of hydrazine electrooxidation performance of carbon nanotube supported Pd monometallic direct hydrazine fuel cell anode catalysts”, MJEN, vol. 8, no. 2, pp. 90–98, Dec. 2020, doi: 10.51354/mjen.801182.

ISNAD

Er, Ömer - Cavak, Ali - Aldemir, Adnan - Demir Kıvrak, Hilal. “Investigation of Hydrazine Electrooxidation Performance of Carbon Nanotube Supported Pd Monometallic Direct Hydrazine Fuel Cell Anode Catalysts”. MANAS Journal of Engineering 8/2 (December 1, 2020): 90-98. https://doi.org/10.51354/mjen.801182.

JAMA

1.Er Ö, Cavak A, Aldemir A, Demir Kıvrak H. Investigation of hydrazine electrooxidation performance of carbon nanotube supported Pd monometallic direct hydrazine fuel cell anode catalysts. MJEN. 2020;8:90–98.

MLA

Er, Ömer, et al. “Investigation of Hydrazine Electrooxidation Performance of Carbon Nanotube Supported Pd Monometallic Direct Hydrazine Fuel Cell Anode Catalysts”. MANAS Journal of Engineering, vol. 8, no. 2, Dec. 2020, pp. 90-98, doi:10.51354/mjen.801182.

Vancouver

1.Ömer Er, Ali Cavak, Adnan Aldemir, Hilal Demir Kıvrak. Investigation of hydrazine electrooxidation performance of carbon nanotube supported Pd monometallic direct hydrazine fuel cell anode catalysts. MJEN. 2020 Dec. 1;8(2):90-8. doi:10.51354/mjen.801182

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Investigation of hydrazine electrooxidation performance of carbon nanotube supported Pd monometallic direct hydrazine fuel cell anode catalysts

Abstract

Investigation of hydrazine electrooxidation performance of carbon nanotube supported Pd monometallic direct hydrazine fuel cell anode catalysts

Abstract

Keywords

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite

Cited By

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Superior formic acid electrooxidation activity on carbon nanotube‐supported binary Pd nanocatalysts prepared via sequential sodium borohydride reduction technique

Hydrazine electrooxidation activities of novel carbon nanotube supported Tin modified Palladium nanocatalysts

Production of a novel supercapacitor electrode material from Rheum ribes and its application

Superior and Novel Carbohydrate Antigen 125 Electrochemical Sensor Based on 4-(2-(Naphthalen-1-Yl)benzo[b]thiophen-3-Yl)benzaldehyde

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