One-step and Cost-effective Conversion of Polyimide to Graphene by Utilizing a Desktop Laser

Yıl 2023, , 1104 - 1110, 18.10.2023

Nihan Aydemir

https://doi.org/10.16984/saufenbilder.1201851

Öz

Herein a one-step, cost-effective, chemical-free, and versatile graphene fabrication by employing a CO2 laser is presented. A cost-effective desktop laser, compared to expensive and bulky lasers reported in the literature, is utilized for the conversion of polyimide films to graphene. Optimization of the fabrication is enabled by the examination of laser parameters such as laser power and scanning speed. Also, various 2D pattern drawings and in-situ fabrication were realized by the Laser Draw software. Furthermore, characterization experiments such as Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD), Raman Spectroscopy, and X-Ray Photon Spectroscopy (XPS) were performed to prove the successive graphene fabrication.

Anahtar Kelimeler

Graphene, laser scribed graphene, CO2 laser

Kaynakça

• A.K. Geim, K.S. Novoselov, The rise of graphene. Nature materials. vol. 6, no. 3, pp.183-91, 2007
• J. Du, H.M. Cheng. The fabrication, properties, and uses of graphene/polymer composites. Macromolecular Chemistry and Physics. vol. 213, no (10‐11), pp.1060-1077. 2012
• X. Jia, J. Campos-Delgado, M. Terrones, V. Meunier, M.S. Dresselhaus. Graphene edges: a review of their fabrication and characterization. Nanoscale. vol. 3, no. 1, pp. 86-95. 2011
• A. Velasco, Y.K Ryu, A. Boscá, A. Ladrón-de-Guevara, E. Hunt, J. Zuo, J. Pedrós, F. Calle, J. Martinez. Recent trends in graphene supercapacitors: from large area to micro supercapacitors. Sustainable Energy & Fuels. vol. 5, no. 5, pp.1235-54. 2021
• I.I. Gurten. Scalable activated carbon/ graphene-based supercapacitors with improved capacitance retention at high current densities. Turkish Journal of Chemistry. vol. 45, no. 3, pp.927-41. 2021.
• I. Prattis, E. Hui, P. Gubeljak, G.S. Schierle, A. Lombardo, L.G. Occhipinti. Graphene for biosensing applications in point-of-care testing. Trends in Biotechnology. vol. 39, no. 10, pp. 1065-1077. 2021
• H. Tian, Y. Shu, Y.L. Cui, W.T. Mi, Y. Yang, D. Xie, T.L. Ren. Scalable fabrication of high-performance and flexible graphene strain sensors. Nanoscale. vol. 6, no. 2, pp.699-705. 2014
• H. Aghamohammadi, N. Hassanzadeh, R. Eslami-Farsani. A review study on the recent advances in developing the heteroatom-doped graphene and porous graphene as superior anode materials for Li-ion batteries. Ceramics International. Vol. 47, no.16, pp. 22269-22301. 2021
• H. Kose, S. Dombaycioglu, H. Akbulut, A.O. Aydin. Reduced graphene oxide supported tin oxide-boron oxide flexible paper anodes for Li-ion batteries. Turkish Journal of Chemistry. vol. 43, no. 5, pp. 1244-1257. 2019
• P. Mandal, J. Debbarma, M. Saha. A review on the emergence of graphene in photovoltaics industry. Biointerface Research in Applied Chemistry. vol. 11, no.6, 15009-15036. 2021.
• B. Jmai, V. Silva, P.M. Mendes. 2D electronics based on graphene field effect transistors: Tutorial for modelling and simulation. Micromachines. vol.12, no.8, pp. 979-997. 2021
• F. Pasadas, P.C. Feijoo, N. Mavredakis, A. Pacheco‐Sanchez, F.A. Chaves, D. Jiménez. Compact modeling technology for the simulation of integrated circuits based on graphene field‐effect transistors. Advanced Materials. vol. 34, no.48 :2201691- 2201691. 2022
• K.S. Novoselov, A.K. Geim, S.V. Morozov, D.E. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, A.A. Firsov. Electric field effect in atomically thin carbon films. science. vol. 306, no. 5696, pp. 666-669. 2004.
• C.K. Chua, M. Pumera. Chemical reduction of graphene oxide: a synthetic chemistry viewpoint. Chemical Society Reviews. vol. 43. no. 1. pp. 291-312. 2014
• K.K. De Silva, H.H. Huang, R.K. Joshi, M. Yoshimura. Chemical reduction of graphene oxide using green reductants. Carbon. vol. 119, pp. 190-199. 2017.
• M.S. Eluyemi, M.A. Eleruja, A.V. Adedeji, B. Olofinjana, O. Fasakin, O.O. Akinwunmi, O.O. Ilori, A.T. Famojuro, S.A. Ayinde, E.O. Ajayi. Synthesis and characterization of graphene oxide and reduced graphene oxide thin films deposited by spray pyrolysis method. Graphene. vol. 5, no. 3, pp.143-54. 2016
• X. Xu, Z. Zhang, J. Dong, D. Yi, J. Niu, M. Wu, L. Lin, R. Yin, M. Li, J. Zhou, S. Wang. Ultrafast epitaxial growth of metre-sized single-crystal graphene on industrial Cu foil. Science bulletin. vol. 62, no. 15, pp.1074-1080. 2017.
• L.G. De Arco, Y. Zhang, A. Kumar, C. Zhou. Synthesis, transfer, and devices of single-and few-layer graphene by chemical vapor deposition. IEEE Transactions on Nanotechnology. vol. 8, no. 2, pp.135-138. 2009
• C.Y. Su, A.Y. Lu, Y. Xu, F.R. Chen, A.N. Khlobystov, L.J. Li. High-quality thin graphene films from fast electrochemical exfoliation. ACS Nano. vol.5, no.3, pp.2332-2339. 2011
• M.F. El-Kady, R.B. Kaner. Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage. Nature communications. vol. 4, no.1, pp.1-9. 2013.
• J. Lin, Z. Peng, Y. Liu, F. Ruiz-Zepeda, R. Ye, E.L. Samuel, M.J. Yacaman, B.I. Yakobson, J.M. Tour. Laser-induced porous graphene films from commercial polymers. Nature communications. vol. 5, no.1, pp.1-8. 2014
• V. Strong, S. Dubin, M.F. El-Kady, A. Lech, Y. Wang, B.H. Weiller, R.B. Kaner. Patterning and electronic tuning of laser scribed graphene for flexible all-carbon devices. ACS Nano. vol. 6, no.2, pp. 1395-1403. 2012.
• N. Kurra, Q. Jiang, P. Nayak, H.N. Alshareef. Laser-derived graphene: A three-dimensional printed graphene electrode and its emerging applications. Nano Today. vol.24, pp.81-102. 2019.
• Y. Lei, A.H. Alshareef, W. Zhao, S. Inal. Laser-scribed graphene electrodes derived from lignin for biochemical sensing. ACS Applied Nano Materials. vol. 3, no. 2, pp.1166-1174. 2019.
• W. Tian, W. Li, W. Yu, X. Liu. A review on lattice defects in graphene: types, generation, effects and regulation. Micromachines. vol. 8, no. 5, pp. 163-178. 2017.
• G. Yang, L. Li, W.B. Lee, M.C. Ng. Structure of graphene and its disorders: a review. Science and technology of advanced materials. vol. 19, no. 1, pp. 613-48. 2018