Zn(II) iyonlarının piromellitik dianhidrit ile modifiye edilmiş poliamin poliüre polimeri ile adsorpsiyonu

Yıl 2016, , 635 - 644, 11.10.2016

Çiğdem Özer Eda Ergin Füsun Boysan , Mustafa İmamoğlu

https://doi.org/10.16984/saufenbilder.00606

Cited By: 1

Öz

Bu çalışmada sulu çözeltilerden Zn(II) iyonlarının piromellitik dianhidrit ile modifiye edilmiş poliamin- poliüre polimeri (PMPPP) üzerine adsorpsiyonu incelenmiştir. Adsorpsiyon çalışmasına etkisi incelenen parametreler; pH, temas süresi, PMPPP dozu, Zn(II) başlangıç konsantrasyonudur. Langmuir ve Freundlich izoterm modelleri kullanılarak analiz edilen Zn(II) adsorpsiyonunun deneysel verileri, tek tabakalı adsorpsiyonu ifade eden Langmuir izotermi ile daha yüksek uyum göstermiştir. Langmuir izotermine göre Zn(II) iyonları için PMPPP’nin maksimum adsorpsiyon kapasitesi 119.1 mg g^-1 olarak hesaplanmıştır. PMPPP ile Zn(II) iyonlarının adsorpsiyon kinetiği pseudo ikinci derece modeli ile uyumlu bulunmuştur. Zn(II) adsorpsiyonu için termodinamik hesaplar prosesin ekzotermik ve kendiliğinden gerçekleşme eğiliminde olduğunu göstermiştir.

Anahtar Kelimeler

: Zn(II), Adsorpsiyon, Arıtma, Poliamin-poliüre polimeri

Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride

Öz

In this study, adsorption of Zn(II) ions from aqueous solutions was investigated using polyamine polyurea polymer modified with pyromellitic dianhydride (PMPPP). The parameters on the adsorption studies such as pH, contact time, PMPPP dose and initial concentration of Zn(II) were studied. The experimental data analyzed using Langmuir and Freundlich isotherm models were showed a higher compliance with the Langmuir isotherm representing the monolayer adsorption. Maximum adsorption capacity of PMPPP for Zn (II) ions was calculated to be 119.1 mg g^-1 according to Langmuir isotherm. Adsorption kinetics of Zn(II) ions on PMPPP were found to consistent with second order model. Thermodynamic calculations showed that the process is exothermic and occurs spontaneously.

Anahtar Kelimeler

Zn(II), Adsorption, Removal, Polyamine polyurea polymer

Kaynakça

• A. Abdolali, H. H. Ngo, W. Guo, S. Lu, S.-S. Chen, N. C. Nguyen, X. Zhang, J. Wang, and Y. Wu. (2016 Jan.). A breakthrough biosorbent in removing heavy metals: Equilibrium, kinetic, thermodynamic and mechanism analyses in a lab-scale study. Sci. Total Environ. [Online]. 542, pp. 603–11. Available: http://www.sciencedirect.com/science/article/pii/S0048969715309116
• K. A. Krishnan, K. G. Sreejalekshmi, V. Vimexen, and V. Dev. (2016 Feb.). Evaluation of adsorption properties of sulphurised activated carbon for the effective and economically viable removal of Zn(II) from aqueous solutions. Ecotoxicol. Environ. Saf. [Online]. 124, pp. 418–25. Available: http://www.sciencedirect.com/science/article/pii/S0147651315301652
• A. Abbas, A. M. Al-Amer, T. Laoui, M. Almarri, M. Nasser, M. Khraisheh, and M. A. Atieh. (2015 Nov.). Heavy metal removal from aqueous solution by advanced carbon nanotubes: critical review of adsorption applications, Sep. Purif. Technol. [Online] 157, pp. 141–161. Available: http://www.sciencedirect.com/science/article/pii/S1383586615303622
• T. K. Sen and D. Gomez (2011). Adsorption of zinc (Zn2+) from aqueous solution on natural bentonite, Desalination. [Online] 267, pp. 286–294. Available: http://dx.doi.org/10.1016/j.desal.2010.09.041
• J. Nriagu (2007). Zinc Toxicity in Humans, Elsevier Sci. ExtraNet [Online]. Available: http://www.extranet.elsevier.com/homepage_about/mrwd/nvrn/Zinc Toxicity in Humans.pdf
• Y. Huang, D. Wu, X. Wang, W. Huang, D. Lawless, and X. Feng. (2016 Jan.). Removal of heavy metals from water using polyvinylamine by polymer-enhanced ultrafiltration and flocculation, Sep. Purif. Technol. [Online]. 158, pp. 124–136. Available: http://www.sciencedirect.com/science/article/pii/S1383586615303774
• Z. Wan, L. Xu, and J. Wang (2016 Jan.). Treatment of spent radioactive anionic exchange resins using Fenton-like oxidation process, Chem. Eng. J. [Online]. 284, pp. 733–740. Available: http://www.sciencedirect.com/science/article/pii/S1385894715012413
• R. S. Hebbar, A. M. Isloor, K. Ananda, and A. F. Ismail (2015 Nov.). Fabrication of polydopamine functionalized halloysite nanotube/polyetherimide membranes for heavy metal removal, J. Mater. Chem. A. [Online]. 4, pp. 764-774. Available: http://pubs.rsc.org/en/Content/ArticleLanding/2015/TA/C5TA09281Gnhttp://xlink.rsc.org/?DOI=C5TA09281G
• S. Sivrikaya, S. Albayrak, M. Imamoglu, A. Gundogdu, C. Duran, and H. Yildiz. (2012 Dec.). Dehydrated hazelnut husk carbon: a novel sorbent for removal of Ni(II) ions from aqueous solution, Desalin. Water Treat. [Online]. 50, pp. 2–13. Available: http://www.tandfonline.com/doi/abs/10.1080/19443994.2012.708234
• C. Ozer, F. Boysan, and M. Imamoglu (2015 May.). Adsorption of Cu(II), Ni(II) and Pb(II) ions onto polyamine-polyurea polymer modified with pyromellitic dianhydride: kinetic, isotherm and thermodynamic studies, Desalin. Water Treat. [Online]. 57(24), 11173-11183. Available: http://www.tandfonline.com/doi/full/10.1080/19443994.2015.1043653
• Z. Wang, G. Huang, C. An, L. Chen, and J. Liu (2016 Jan.). Removal of copper, zinc and cadmium ions through adsorption on water-quenched blast furnace slag. Desalin. Water Treat. [Online]. pp. 1–14. Available: http://www.tandfonline.com/doi/abs/10.1080/19443994.2015.1135084
• F. Ge, M.-M. Li, H. Ye, and B.-X. Zhao. (2012 Apr.). Effective removal of heavy metal ions Cd2+, Zn2+, Pb2+, Cu2+ from aqueous solution by polymer-modified magnetic nanoparticles. J. Hazard. Mater. [Online]. 211–212, pp. 366–72. Available: http://www.ncbi.nlm.nih.gov/pubmed/22209322
• M. Monier. (2012 Apr.). Adsorption of Hg2+, Cu2+ and Zn2+ ions from aqueous solution using formaldehyde cross-linked modified chitosan-thioglyceraldehyde Schiff’s base. Int. J. Biol. Macromol. [Online]. 50(3), pp. 773–81. Available: http://www.sciencedirect.com/science/article/pii/S0141813011004430
• S. R. Shukla, R. S. Pai, and A. D. Shendarkar. (2006 Jan.). Adsorption of Ni(II), Zn(II) and Fe(II) on modified coir fibres, Sep. Purif. Technol. [Online]. 47(3), pp. 141–147. Available: http://www.sciencedirect.com/science/article/pii/S1383586605002066
• P. Senthilkumar, S. Ramalingam, R. V. Abhinaya, S. D. Kirupha, T. Vidhyadevi, and S. Sivanesan (2012). Adsorption equilibrium, thermodynamics, kinetics, mechanism and process design of zinc(II) ions onto cashew nut shell, Can. J. Chem. Eng. 90(4), pp. 973–982
• M. Revathi, M. Saravanan, A. B. Chiya, and M. Velan. (2012). Removal of copper, nickel, and zinc ions from electroplating rinse Water, Clean - Soil, Air, Water. 40(1), pp. 66–79
• A.H. Chen, S.C. Liu, C.Y. Chen, and C.Y. Chen. (2008 Jun.). Comparative adsorption of Cu(II), Zn(II), and Pb(II) ions in aqueous solution on the crosslinked chitosan with epichlorohydrin. J. Hazard. Mater. [Online]. 154, pp. 184–91. Available: http://www.sciencedirect.com/science/article/pii/S0304389407014240
• P. Z. Ray and H. J. Shipley. (2015). Inorganic nano-adsorbents for the removal of heavy metals and arsenic: a review, RSC Adv. [Online]. 5(38), pp. 29885–29907. Available: http://xlink.rsc.org/?DOI=C5RA02714D
• K. G. Bhattacharyya and S. Sen Gupta. (2008). Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: A review, Adv. Colloid Interface Sci. 140(2), pp. 114–131
• F. Fu and Q. Wang. (2011). Removal of heavy metal ions from wastewaters: A review, J. Environ. Manage. [Online]. 92(3), pp. 407–418. Available: http://dx.doi.org/10.1016/j.jenvman.2010.11.011
• S. Lapwanit, T. Trakulsujaritchok, and P. Na Nongkhai. (2015 Dec.). Chelating magnetic copolymer composite modified by click reaction for removal of heavy metal ions from aqueous solution, Chem. Eng. J. [Online]. 289, pp. 286–295. Available: http://www.sciencedirect.com/science/article/pii/S1385894715017453
• C. Ozer, F. Boysan, M. Imamoglu, and S. Z. Yildiz. (2014 Nov.). Adsorption of Cd(II) ions onto polyamine-polyurea polymer modified with pyromellitic dianhydride, Desalin. Water Treat. [Online]. 57(6), pp. 2787-2798. Available: http://www.tandfonline.com/doi/abs/10.1080/19443994.2014.983176
• Z. A. AL-Othman, R. Ali, and M. Naushad. (2012). Hexavalent chromium removal from aqueous medium by activated carbon prepared from peanut shell: Adsorption kinetics, equilibrium and thermodynamic studies, Chem. Eng. J. [Online]. 184, pp. 238–247. Available: http://dx.doi.org/10.1016/j.cej.2012.01.048
• G. Z. Kyzas, P. I. Siafaka, E. G. Pavlidou, K. J. Chrissafis, and D. N. Bikiaris. (2015 Jan.). Synthesis and adsorption application of succinyl-grafted chitosan for the simultaneous removal of zinc and cationic dye from binary hazardous mixtures, Chem. Eng. J. [Online]. 259, pp. 438–448. Available: http://www.sciencedirect.com/science/article/pii/S1385894714010730
• G. Rao, C. Lu, and F. Su. (2007 Dec.). Sorption of divalent metal ions from aqueous solution by carbon nanotubes: A review, Sep. Purif. Technol. [Online]. 58(1) pp. 224–231. Available: http://www.sciencedirect.com/science/article/pii/S1383586606004163
• R. Hasanzadeh, P. N. Moghadam, N. Samadi, and S. Asri-Rezaei. (2013 Feb.). Removal of heavy-metal ions from aqueous solution with nanochelating resins based on poly(styrene- alt -maleic anhydride), J. Appl. Polym. Sci. [Online]. 127(4) pp. 2875–2883. Available: http://doi.wiley.com/10.1002/app.36793
• Y. Wang, L. Zhu, H. Jiang, F. Hu, and X. Shen. (2016 Jan.). Application of longan shell as non-conventional low-cost adsorbent for the removal of cationic dye from aqueous solution, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. [Online]. Available: http://www.sciencedirect.com/science/article/pii/S1386142516300427
• L. Lin, Y. Lin, C. Li, D. Wu, and H. Kong. (2016 Jan.). Synthesis of zeolite/hydrous metal oxide composites from coal fly ash as efficient adsorbents for removal of methylene blue from water, Int. J. Miner. Process. [Online]. 148, pp. 32–40. Available: http://www.sciencedirect.com/science/article/pii/S0301751616300096
• Ihsanullah, F. A. Al-Khaldi, B. Abusharkh, M. Khaled, M. A. Atieh, M. S. Nasser, T. Laoui, T. A. Saleh, S. Agarwal, I. Tyagi, and V. K. Gupta. (2015). Adsorptive removal of cadmium(II) ions from liquid phase using acid modified carbon-based adsorbents, J. Mol. Liq. [Online]. 204, pp. 255–263. Available: http://linkinghub.elsevier.com/retrieve/pii/S0167732215000446
• K. Tekin, M. K. Akalin, L. Uzun, S. Karagöz, S. Bektaş, and A. Denizli. (2015). Adsorption of Pb(II) and Cd(II) Ions onto Dye-Attached Sawdust, CLEAN - Soil, Air, Water [Online]. 43(9999), pp. 1-6. Available: http://doi.wiley.com/10.1002/clen.201500222
• A. Duran, M. Soylak, and S. A. Tuncel. (2008 Jun.). Poly(vinyl pyridine-poly ethylene glycol methacrylate-ethylene glycol dimethacrylate) beads for heavy metal removal. J. Hazard. Mater. [Online]. 155, pp. 114–20. Available: http://www.sciencedirect.com/science/article/pii/S0304389407016652
• I. Langmuir (1918).The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum, J. Am. Chem. Soc. 40, pp. 1361–403
• H. M. F. Freundlich. (1906). Über Die Adsorption in Lösungen, Zeitschrift für Phys. Chemie, 57, no. A, pp. 385–470
• S. Lagergren. (1898). About the theory of so-called adsorption of soluble substances, K. Sven. Vetenskapsakad. Hand, 24(4) pp. 1–39
• Y. Ho and G. McKay. (1999 Jul.). Pseudo-second order model for sorption processes, Process Biochem. [Online]. 34(5), pp. 451–465. Available: http://linkinghub.elsevier.com/retrieve/pii/S0032959298001125
• K. C. Bedin, A. C. Martins, A. L. Cazetta, O. Pezoti, and V. C. Almeida. (2016 Feb.). KOH-activated carbon prepared from sucrose spherical carbon: Adsorption equilibrium, kinetic and thermodynamic studies for Methylene Blue removal, Chem. Eng. J. [Online]. 286, pp. 476–484. Available: http://www.sciencedirect.com/science/article/pii/S1385894715015120
• M. Peydayesh and A. Rahbar-Kelishami. (2015 Jan.). Adsorption of methylene blue onto Platanus orientalis leaf powder: Kinetic, equilibrium and thermodynamic studies, J. Ind. Eng. Chem. [Online]. 21, pp. 1014–1019. Available: http://www.sciencedirect.com/science/article/pii/S1226086X14002597