Reactions of hexachlorocyclotriphosphazatriene,
N3P3Cl6 (1)
with 1-amino-2-propanol (2), in
(1:1:2, 1:2:4 and 1:3:6) mole ratios, in excess of NaH, in THF and acetonitril solutions
yield a total of 6 novel products:one
mono-open chain, N3P3Cl5[HN-CH2-CH(CH3)-OH]
(3); one monospiro, N3P3Cl4[O-CH(CH3)-CH2-NH]
(4); one trans bis-open chain, N3P3Cl4[HN-CH2CH(CH3)-OH]2
(5); one dispiro, N3P3Cl2[O-HC(CH3)-CH2-NH]2
(7); one tri-open chain, N3P3Cl3[HN-CH2CH(CH3)-OH]3
(6); and one tri-spiro, N3P3[O-HC(CH3)-CH2-NH]3(8) derivatives.These compounds have
interesting structural aspects as well as physical properties. Their structures
were established by elemental analysis, TL-MS, 31P and 1H
NMR spectral data. Stability constants were determined
using a simple potentiometric titration. For evaluation of melting behavior
and purity of derivatives (7) and (8), thermal transition peaks and their
corresponding enthalpies were determined via DSC technique. Spectroscopic
data, product types and relative
yields are compared with those of the previously investigated derivatives of N3P3Cl6
(1) with aliphatic difunctional reagents.
Hexachlorocyclotriphosphazene 1-amino-2-propanol spiro compounds open chain compounds
Birincil Dil | İngilizce |
---|---|
Konular | Kimya Mühendisliği |
Bölüm | Araştırma Makalesi |
Yazarlar | |
Yayımlanma Tarihi | 1 Haziran 2018 |
Gönderilme Tarihi | 26 Ocak 2018 |
Kabul Tarihi | 10 Mayıs 2018 |
Yayımlandığı Sayı | Yıl 2018 |
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.