Modelling of Remazol Black-B adsorption on chemically modified waste orange peel: pH shifting effect of acidic treatment

Yıl 2020, , 1135 - 1150, 01.10.2020

Ceren Karaman , Zümriye Aksu

https://doi.org/10.16984/saufenbilder.751491

Cited By: 7

Öz

The adsorption of Remazol Black-B (RBB) onto two different types of agricultural waste derived-adsorbents; dried-orange peel (DOP) and chemically modified orange peel (CMOP), was performed. The adsorption rate, capacity, and the dye removal efficiency were investigated in terms of initial pH ranged between 2.0 to 10.0 of the dispersion and the operating temperature of 25 °C, 35 °C, 45 °C . The Langmuir and Freundlich adsorption models were applied to the experimental data to model the adsorption equilibrium, and evaluated by regression analysis. The results indicated that the Langmuir model was more suitable to describe the adsorption equilibrium of RBB over CMOP. According to Langmuir model, while the highest RBB uptake capacity of DOP was determined as 62.4 mg.g-1 at pH 2.0 and 25°C, this value was figured out for CMOP as 84.4 mg.g-1 at pH 8.0 and 45°C. Furthermore, the adsorption kinetics followed both the pseudo-second order and the saturation type kinetic models for each adsorbent-dye system. The thermodynamic parameters of adsorption including the Gibbs free energy change (ΔGo), the enthalpy change (ΔHo), and the entropy change (ΔSo) were obtained by using thermodynamic equations. These parameters were calculated as -4.24 kJ.mol-1, 43.77 kJ.mol-1, 0.16 kJ mol-1.K-1 for CMOP respectively whereas for DOP -3.58 kJ.mol-1,-19.79 kJ.mol-1, -0.05 kJ mol-1.K-1 .

Anahtar Kelimeler

Adsorption, Orange Peel, Remazol Black-B, Acidic Treatment, Chemical Modification, pH shifting, Agricultural Waste

Destekleyen Kurum

none

Teşekkür

none

Kaynakça

• S.P. Kodal and Z. Aksu, "Cationic surfactant-modified biosorption of anionic dyes by dried Rhizopus arrhizus." Environmental technology, vol. 38, no. 20, pp. 2551-2561, 2017.
• Z. Aksu, “Application of biosorption for the removal of organic pollutants: a review.” Process Biochemistry, vol. 40, pp. 997−1026, 2005.
• E. Bayram and E. Ayranci, “Investigation of changes in properties of activated carbon cloth upon polarization and of electrosorption of the dye basic blue-7.” Carbon, vol. 48, pp. 1718–1730, 2010.
• S.P.D Monte Blanco, F.B. Scheufele, A.N. Modenes, F.R. Espinoza-Quinones, P. Marin, A.D. Kroumov and C.E. Borba, “Kinetic, equilibrium and thermodynamic phenomenological modeling of reactive dye adsorption onto polymeric adsorbent.” Chemical Engineering Journal, vol. 307, pp. 466-475, 2017.
• Z. Aksu and A. İsoglu, “Use of agricultural waste sugar beet pulp for the removal of Gemazol turquoise blue-G reactive dye from aqueous solution.” Journal of Hazardous Materials B, vol. 137, pp. 418-430, 2006.
• A.A. Attia, B.S. Girgis, and N.A. Fathy, “Removal of methylene blue by carbons derived from peach stones by H3PO4 activation: batch and column studies.” Dyes and Pigments, vol. 76, pp. 282–289, 2008.
• M, Olivares-Marín, C. Fernández-González A. Macías-García, and V. Gómez-Serrano, “Preparation of activated carbons from cherry stones by activation with potassium hydroxide.” Applied Surface Science, vol. 252,pp. 5980–5983, 2006.
• W. Li, K. Yang, J. Peng, L. Zhang, S. Guo, and H. Xia, “Effects of carbonization temperatures on characteristics of porosity in coconut shell chars and activated carbons derived from carbonized coconut shell chars.” Industrial Crops and Products, vol. 28, pp. 190–198, 2008.
• I.A.W. Tan, A.L. Ahmad, and B.H. Hameed, “Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: equilibrium, kinetic and thermodynamic studies.” Journal of Hazardous Materials, vol. 154, pp. 337–346, 2008.
• F.S. Vieira, A.R. Cestari, I.F. Gimenez, N.L.V. Carreño, and L.S. Barreto, “Kinetic and calorimetric study of the adsorption of dyes on mesoporous activated carbon prepared from coconut coir dust.”Journal of Colloid and Interface Science, vol. 298, pp. 515–522, 2006.
• M. Olivares-Marín, V. Del-Prete, E. Garcia-Moruno, C. Fernández-González, A. Macías-García, and V. Gómez-Serrano, “The development of 500 an activated carbon from cherry stones and its use in the removal of ochratoxin A from red wine.” Food Control. vol. 20, no. 3, pp. 298–303, 2009.
• J.M. Dias, M.C.M. Alvim-Ferraz, M.F. Almeida, J. Rivera-Utrilla, and M. Sánchez-Polo. “Waste materials for activated carbon preparation and its use in aqueous-phase treatment: a review.” Journal of Environmental Management, vol. 85, no. 4, pp. 833–846, 2007.
• S. Liang, X. Guo, N. Feng, and Q. Tian “Application of orange peel xanthate for the adsorption of Pb2+ from aqueous solutions.” Journal of Hazardous Materials, vol. 170, pp. 425-429, 2010.
• D.D. Lu, Q.L. Cao, X.M. Li, X. Cao, F. Luo, and W. Shao, “Kinetics and equilibrium of Cu(II) adsorption onto chemically modified orange peel cellulose biosorbents.” Hydrometallurgy, vol. 95, no. 1-2, pp. 145-152, 2009.
• P.D. Pathak, S.A. Mandavgane, and B.D. Kulkarni, “Characterizing fruit and vegetable peels as bioadsorbents.” Current Science, vol. 110, pp. 2114–2123, 2016.
• J.J.M Órfão, A.I.M. Silva, J.C.V. Pereira, S. A. Barata, I. M. Fonseca, P. C. C. Faria, and M. F. R. Pereira. “Adsorption of a reactive dye on chemically modified activated carbons–influence of pH.” Journal of Colloid and Interface Science, vol. 296, no. 2, pp. 480–489, 2006.
• N.H. Tran, S.J. You, and H.P. Chao, “Thermodynamic parameters of cadmium adsorption onto orange peel calculated from various methods: A comparison study.” Journal of Environmental Chemical Engineering, vol. 4, pp. 2671–2682, 2016.
• I. Langmuir, “The adsorption of gases on plane surfaces of glass, mica, and platinum.” Journal of the American Chemical Society, vol. 40, pp. 1361–140, 1918.
• Z. Aksu, A.I Tatlı, and Ö. Tunç, “A comparative adsorption/biosorption study of Acid Blue 161: Effect of temperature on equilibrium and kinetic parameters.” Chemical Engineering Journal, vol. 142, pp. 23-39, 2008.
• Q. Meng, Q. Kaiqiang, M. Liying, H. Chunnian, L. Enzuo, H. Fang, S. Chunsheng, L. Qunying, L. Jiajun, and Z. Naiqin, "N-doped porous carbon nanofibers/porous silver network hybrid for high-rate supercapacitor electrode." ACS applied materials & interfaces, vol. 9, no. 36, pp. 30832-30839, 2017.
• Karaman C., Bayram E., Karaman O., Aktaş Z., "Preparation of high surface area nitrogen doped graphene for the assessment of morphologic properties and nitrogen content impacts on supercapacitors", JOURNAL OF ELECTROANALYTICAL CHEMISTRY, vol.868, pp.114197-, 2020
• E. Errais, J. Duplay, M. Elhabiri, M. Khodja, R. Ocampo, R. Baltenweck-Guyot, and F. Darragi “Anionic RR120 dye adsorption onto raw clay: surface properties and adsorption mechanism.” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 403, 69–78, 2012.
• J. Huang, D. Liu, J. Lu, H. Wang, X.Wei, and J. Liu “Biosorption of reactive black 5 by modified Aspergillus versicolor biomass: kinetics, capacity and mechanism studies.” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 492, pp. 242–248, 2016.
• A. Srinivasan, and T. Viraraghavan, “Decolorization of dye wastewaters by biosorbents: a review.” Journal of Environmental Management, vol. 91, pp. 1915–1929, 2010.
• Y.S. Al-Degs, M.I. El-Barghouthi, A.H. El-Sheikh, and G.M. Walker, “Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon.” Dyes and Pigments, vol. 77, pp.16–23, 2008.
• A.R. Cestari, E.F.S. Vieira, A.G.P. Dos Santos, J.A. Mota, and V.P. De Almeida, “Adsorption of anionic dyes on chitosan beads. 1. The influence of the chemical structures of dyes and temperature on the adsorption kinetics.” Journal of Colloid and Interface Science, 280, 380–386, 2004.