Araştırma Makalesi
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Bromlu fenstatin türevlerinin seryum (IV) amonyum nitrat/lityum bromür (CAN/LiBr) ile sentezi ve yoğunluk fonksiyonel teorisi (DFT) ile incelenmesi

Yıl 2017, Cilt: 21 Sayı: 3, 481 - 488, 01.06.2017

Yasin Çetinkaya

https://doi.org/10.16984/saufenbilder.270715
Cited By: 1

Öz

 Bu
çalışmada, Eaton reaktifi (CH3SO3H/P2O5)
kullanılarak fenstatin türevi olan (3,4-dimetoksifenil)(3,4,5-trimetoksifenil)metanon
(7) sentezlendi. Diarilmetanon 7’nin seryum (IV) amonyum nitrat (CAN/LiBr)
kullanılarak bromlanması ile  (2-brom-3,4,5-trimetoksifenil)(3,4-dimetoksifenil)metanon
(10) ve (2,6-dibrom-3,4,5-trimetoksifenil) (3,4-dimetoksifenil)metanon (11)
sentezlendi. Sentezlenen bileşiklerin yapıları IR, HRMS,  1H ve 13C NMR
spektroskopisi ile aydınlatıldı. Bileşiklerin geometrik parametreleri GAUSSIAN
09W paket programı kullanılarak, yoğunluk fonksiyonel teorisi (DFT)
B3LYP/6-311G(d,p) metodu ile optimize edildi ve yapısal parametreleri (bağ
açıları, bağ uzunlukları ve dihedral açıları) incelendi.

Anahtar Kelimeler

Fenstatin brominasyon seryum (IV) amonyum nitrat (CAN) Eaton reaktifi

Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT)

Yıl 2017, Cilt: 21 Sayı: 3, 481 - 488, 01.06.2017

Yasin Çetinkaya

https://doi.org/10.16984/saufenbilder.270715
Cited By: 1

Öz

In this study,
(3,4-dimethoxyphenyl) (3,4,5-trimethoxyphenyl) methanone (7) being phenstatin
derivation  was synthesized using Eaton's
reagent (CH3SO3H / P2O5). Novel
compound (2-bromo-3,4,5-trimethoxyphenyl) (3,4-dimethoxyphenyl) methanone (10)
and (2,6-dibromo-3,4,5-trimethoxyphenyl) (3,4-dimethoxyphenyl) methanone (11)
were   synthesized with the bromination of
diarylmethanone 7 with ceric (IV) ammonium nitrate (CAN/LiBr).  In order to determine the structures of the
compounds synthesized, IR, HRMS, 1H and 13C NMR
spectroscopic analysis were used. Geometrical
parameters of the products were optimized with the density functional theory
(DFT) B3LYP method using the 6-311G(d,p) basis set implemented Gaussian 09 and
analyzed their structural parameters (bond lenghts, bond angles, dihedral
angles).

Anahtar Kelimeler

Phenstatin bromination serium (IV) ammonium nitrate (CAN) Eaton’s reagent

Toplam 0 adet kaynakça vardır.

Ayrıntılar

Konular Mühendislik
Bölüm Araştırma Makalesi
Yazarlar

Yasin Çetinkaya

Yayımlanma Tarihi 1 Haziran 2017
Gönderilme Tarihi 1 Aralık 2016
Kabul Tarihi 21 Mart 2017
Yayımlandığı Sayı Yıl 2017 Cilt: 21 Sayı: 3

Kaynak Göster

APA Çetinkaya, Y. (2017). Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT). Sakarya University Journal of Science, 21(3), 481-488. https://doi.org/10.16984/saufenbilder.270715
AMA Çetinkaya Y. Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT). SAUJS. Haziran 2017;21(3):481-488. doi:10.16984/saufenbilder.270715
Chicago Çetinkaya, Yasin. “Synthesis of Brominated Phenstatin Derivatives via Cerium (IV) Ammonium Nitrate / Lithium Bromide (CAN/LiBr) and Investigation With the Density Functional Theory (DFT)”. Sakarya University Journal of Science 21, sy. 3 (Haziran 2017): 481-88. https://doi.org/10.16984/saufenbilder.270715.
EndNote Çetinkaya Y (01 Haziran 2017) Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT). Sakarya University Journal of Science 21 3 481–488.
IEEE Y. Çetinkaya, “Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT)”, SAUJS, c. 21, sy. 3, ss. 481–488, 2017, doi: 10.16984/saufenbilder.270715.
ISNAD Çetinkaya, Yasin. “Synthesis of Brominated Phenstatin Derivatives via Cerium (IV) Ammonium Nitrate / Lithium Bromide (CAN/LiBr) and Investigation With the Density Functional Theory (DFT)”. Sakarya University Journal of Science 21/3 (Haziran 2017), 481-488. https://doi.org/10.16984/saufenbilder.270715.
JAMA Çetinkaya Y. Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT). SAUJS. 2017;21:481–488.
MLA Çetinkaya, Yasin. “Synthesis of Brominated Phenstatin Derivatives via Cerium (IV) Ammonium Nitrate / Lithium Bromide (CAN/LiBr) and Investigation With the Density Functional Theory (DFT)”. Sakarya University Journal of Science, c. 21, sy. 3, 2017, ss. 481-8, doi:10.16984/saufenbilder.270715.
Vancouver Çetinkaya Y. Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT). SAUJS. 2017;21(3):481-8.

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