Araştırma Makalesi
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(NH4)2CO3 Kullanılarak Sölestinin Yaş Mekanokimyasal İşlenmesi

Yıl 2017, Cilt: 21 Sayı: 3, 278 - 284, 01.06.2017

Deniz Bingöl Salih Aydoğan Seda Karayünlü Bozbaş

https://doi.org/10.16984/saufenbilder.283291
Cited By: 1

Öz

Bu çalışmada, yaş mekanokimyasal işlem bir planetary bilyalı değirmende sölestin (SrSO4)-(NH4)2CO3-H2O
karışımından SrCO3 ve (NH4)2SO4 elde etmek için geleneksel (tekli) yöntemle uygulandı. X-ışını kırınımı, Fourier
dönüşümlü kızılötesi spektroskopi, taramalı elektron mikroskobu ve kimyasal analiz yaş öğütme sırasında oluşan
ürünleri analiz etmek için kullanıldı. Hidrometalurjik işlem, bir planeter değirmende öğütme süresi, bilya ile öğütülmüş
malzeme kütle oranı, (NH4)2CO3 ile SrSO4 mol oranı ve değirmen dönme hızını incelemek için gerçekleştirildi.
Optimum koşullar altında, SrCO3’ın %100’e yaklaşan bir dönüşümü elde edildi.  

Anahtar Kelimeler

Amonyum Sülfat Sölestin Stronsiyum Karbonat Yaş Mekanokimyasal Dönüşüm

Kaynakça

  • [1] B. A. Kennedy. (1990). Surface Mining, (2nd ed), [Online]. Available: https://app.knovel.com
  • [2] M. Erdemoğlu, M. Canbazoğlu. “The effect of oxygen on the precipitation of strontium carbonate from aqueous carbon dioxide solutions”, in: Proc.7th Balkan Conference on Mineral Processing, Vatra Dornei, Romania, 1997, pp. 108–112.
  • [3] M. Erdemoğlu, M. Canbazoğlu. (1998, February). The leaching of SrS with water and the precipitation of SrCO3 from leach solution by different carbonating agents, Hydrometallurgy. [Online]. 49, pp. 135–150. Available: https://www.deepdyve.com
  • [4] M. Erdemoğlu, M. Canbazoğlu, H. Yalçın. (1998). Carbothermic reduction of high grade celestite ore to manufacture strontium carbonate, Mineral Process, Ext. Metall. (Trans. IMM. Sec C), 107, pp. 65–70.
  • [5] G. Owusu, J. E. Litz. (2000, August). Water leaching of SrS and precipitation of SrCO3 using carbon dioxide as precipitating agent, Hydrometallurgy. [Online]. 57, pp. 23–29. Available: http://www.sciencedirect.com/science/article/pii/S0304386X00000918
  • [6] M. Beg, A. Arshad, S. A. Khan, N. Hasan. (1986, June). Production of strontium carbonate from celestite, Pakistan J. Sci. Ind. Res. [Online]. 29, pp. 217–221. Available: http://www.pjsir.org/documents/journals
  • [7] M. Iwai, J. M. Toguri. (1989, June). The leaching of celestite in sodium carbonate solution, Hydrometallurgy, [Online]. 22, pp. 87–100. Avalilable: http://www.sciencedirect.com/science/article/pii/0304386X89900431
  • [8] A. H. Castillejos, F. P. dela Cruz, A. (1996, January). Uribe. The direct conversion of celestite to strontium carbonate in sodium carbonate aqueous media, Hydrometallurgy. [Online]. 40, pp. 207–222. Available: http://www.sciencedirect.com/science/article/pii/0304386X9400060G
  • [9] D. Bingol, S. Aydogan, S. S. Gultekin. (2010, December) Neural model for the leaching of celestite in sodium carbonate solution, Chem. Eng. J. [Online]. 165, pp. 617–624. Available: http://www.sciencedirect.com/science/article/pii/S1385894710009149
  • [10] Method for recovery and conversion of strontium sulphate to strontium carbonate from low and medium grade celestite ores, F. De Buda. (1987, February 3). Patent 4.666.668. [Online]. Available:
  • http://www.google.com/patents/US4666688
  • [11] Z. Cheng, T. Jiang. (1992). Production of SrCO3 by NH4HCO3 method without removing barium, Huadong Huagong Xueyuan Xueba, 18, pp. 723–728.
  • [12] H. Di, Y. Wang, Y. Zhang. “Preparation of high purity strontium carbonate from Celestine”, Chine HC Patent 1.078.706. 1993.
  • [13] Continuous production of fertilizing salts with derivatives of strontium and gypsum, P. A. Piedrafita. (1991, July 3), EP0495937, [Online]. Available: http://www.google.se/patents/EP0495937A1?cl=sv
  • [14] Production of strontium carbonate from celestite, S. Kocakuşak, R. Tolun, H. Doğan, M. Koral, K. Akçay, H. J. Köroğlu. (2001, October 18). WIPO Patent WO/2001/077021S. [Online]. Available: http://www.google.com/patents/WO2001077021A1?cl=en
  • [15] B. Kacar, A. V. Katkat. ”Gübreler ve Gübreleme Tekniği,” Fen ve Biyoloji Yay. Diz.,vol. 34, no. 849, Nobel ISBN: 978–9944–77–159–7, 2007.
  • [16] P. G. McCormick, F. H. Froes. (1998, November). The fundamentals of mechanochemical processing, JOM. [Online]. pp.61-65. Available: http://download.springer.com/static/pdf/562
  • [17] Q. Zhang, F. Saito. (1997, January ) Mechanochemical processing of celestite, Chem. Eng. J. [Online]. 66. pp. 79–82. Available: http://www.sciencedirect.com/science/article/pii/S1385894796031816
  • [18] A. Obut, P. Balaz, I. Girgin. (2006, August). Direct mechanochemical conversion of celestite to SrCO3, Miner. Eng. [Online]. 19. pp. 1185–1190. Available: http://www.sciencedirect.com/science/article/pii/S0892687505004140
  • [19] M. Erdemoğlu, S. Aydoğan, M. Canbazoğlu. (2007, April). A kinetic study on the conversion of celestite (SrSO4) to SrCO3 by mechanochemical processing, Hydrometallurgy. [Online]. 86. pp. 1–5. Available: http://www.sciencedirect.com/science/article/pii/S0304386X06002544
  • [20] N. Setoudeh, N. J. Welham, S. M. Azami. (2010, March). Dry mechanochemical conversion of SrSO4 to SrCO3, J. Alloy. Comp. [Online]. 492, pp. 389–391. Available: http://www.sciencedirect.com/science/article/pii/S0925838809024396
  • [21] D. Bingöl, S. Aydoğan, S. Karayünlü Bozbaş. (2012, March ) Production of SrCO3 and (NH4)2SO4 by the dry mechanochemical processing of celestite, JIEC. [Online]. 18, pp. 834–838. Available: http://www.sciencedirect.com/science/article/pii/S1226086X11003583
  • [22] D. Bingol, S. Aydogan, S. Karayunlu Bozbas. (2012). Optimization of dry mechanochemical conversion conditions of SrSO4 to SrCO3, Essays on Environmental Studies, 25th section, Athens Institute for Education and Research, Athens, Greece, pp. 265-273.
  • [23] D. Bingöl, S. Aydoğan, S. Karayünlü Bozbaş. (2012, October). Optimization of the wet mechanochemical process conditions of SrSO4 to SrCO3 and (NH4)2SO4 by using response surface methodology, Met. Trans. B. [Online]. 43, pp. 1214–1219. Available: https://www.researchgate.net/publication/257708868
  • [24] D.R. Lide. (1997). Handbook of Chemistry and Physics, 78th ed. CRC Press.
  • [25] A. López–Valdivieso, A. Robledo–Cabrera, A. Uribe–Salas. (2000, September). Flotation of celestite with the anionic collector sodium dodecyl sulfate: Effect of carbonate ions, Int. J. Miner. Process. [Online]. 60, pp. 79– 90. Available: http://www.sciencedirect.com/science/article/pii/S0301751600000041
  • [26] R. Suárez–Orduña, J.C. Rendón–Angeles, L. López–Cuevas, K. Yanagisawa. (2004, July). The conversion of mineral celestite to strontianite under alkaline hydrothermal conditions, J. Phys. Condens. Matter. [Online]. 16 pp. 1331–1344. Available: http://www.sciencedirect.com/science/article/pii/S0301751607000701
  • [27] R. Suárez–Orduña, J. C. Rendón–Angeles, K. Yanagisawa. (2007 March). Kinetic study of the conversion of mineral celestite to strontianite under alkaline hydrothermal conditions, Int. J. Miner. Process. [Online]. 83, pp. 12–18. Available: https://www.researchgate.net/publication/229308904
  • [28] X. Zhu, M. Elomaa, F. Sundholm, C. H. Lochmüller. (1998, December). Infrared and thermogravimetric studies of thermal degradation of polystyrene in the presence of ammonium sulfate, Poly. Deg. &.Stab. [Online]. 62, pp. 487–494. Available: http://www.sciencedirect.com/science/article/pii/S0141391098000329
  • [29] W. Zhou, T. Fukushima, M. Ito. (2006, October). Overlayer adsorbates of NH4 + and SO4
  • 2- on a Pt(111) surface studied by in situ IR spectroscopy, Sci. Technol. Adv. Mater. [Online]. 7, pp. 216–218. Available: http://www.readcube.com/articles/10.1016%2Fj.stam.2005.10.006

Wet Mechanochemical Processing of Celestine using (NH4)2CO3

Yıl 2017, Cilt: 21 Sayı: 3, 278 - 284, 01.06.2017

Deniz Bingöl Salih Aydoğan Seda Karayünlü Bozbaş

https://doi.org/10.16984/saufenbilder.283291
Cited By: 1

Öz

In this study, traditional (univariate) method of processing to the wet mechanochemical treatment were applied to
obtain both SrCO3 and (NH4)2SO4 from celestite (SrSO4)-(NH4)2CO3-H2O mixtures in a planetary ball mill. X-ray
diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and chemical analysis were used
to analyze products formed during wet milling. A hydrometallurgical process was carried out to examine milling time,
ball to grinding material mass ratio, (NH4)2CO3 to SrSO4 mole ratio and rotational speed of the mill in a planetary mill.
Under optimum conditions, a conversion approaching 100% of SrCO3 was obtained.  

Anahtar Kelimeler

Ammonium Sulfate Celestine Strontium Carbonate Wet Mechanochemical Conversion

Kaynakça

  • [1] B. A. Kennedy. (1990). Surface Mining, (2nd ed), [Online]. Available: https://app.knovel.com
  • [2] M. Erdemoğlu, M. Canbazoğlu. “The effect of oxygen on the precipitation of strontium carbonate from aqueous carbon dioxide solutions”, in: Proc.7th Balkan Conference on Mineral Processing, Vatra Dornei, Romania, 1997, pp. 108–112.
  • [3] M. Erdemoğlu, M. Canbazoğlu. (1998, February). The leaching of SrS with water and the precipitation of SrCO3 from leach solution by different carbonating agents, Hydrometallurgy. [Online]. 49, pp. 135–150. Available: https://www.deepdyve.com
  • [4] M. Erdemoğlu, M. Canbazoğlu, H. Yalçın. (1998). Carbothermic reduction of high grade celestite ore to manufacture strontium carbonate, Mineral Process, Ext. Metall. (Trans. IMM. Sec C), 107, pp. 65–70.
  • [5] G. Owusu, J. E. Litz. (2000, August). Water leaching of SrS and precipitation of SrCO3 using carbon dioxide as precipitating agent, Hydrometallurgy. [Online]. 57, pp. 23–29. Available: http://www.sciencedirect.com/science/article/pii/S0304386X00000918
  • [6] M. Beg, A. Arshad, S. A. Khan, N. Hasan. (1986, June). Production of strontium carbonate from celestite, Pakistan J. Sci. Ind. Res. [Online]. 29, pp. 217–221. Available: http://www.pjsir.org/documents/journals
  • [7] M. Iwai, J. M. Toguri. (1989, June). The leaching of celestite in sodium carbonate solution, Hydrometallurgy, [Online]. 22, pp. 87–100. Avalilable: http://www.sciencedirect.com/science/article/pii/0304386X89900431
  • [8] A. H. Castillejos, F. P. dela Cruz, A. (1996, January). Uribe. The direct conversion of celestite to strontium carbonate in sodium carbonate aqueous media, Hydrometallurgy. [Online]. 40, pp. 207–222. Available: http://www.sciencedirect.com/science/article/pii/0304386X9400060G
  • [9] D. Bingol, S. Aydogan, S. S. Gultekin. (2010, December) Neural model for the leaching of celestite in sodium carbonate solution, Chem. Eng. J. [Online]. 165, pp. 617–624. Available: http://www.sciencedirect.com/science/article/pii/S1385894710009149
  • [10] Method for recovery and conversion of strontium sulphate to strontium carbonate from low and medium grade celestite ores, F. De Buda. (1987, February 3). Patent 4.666.668. [Online]. Available:
  • http://www.google.com/patents/US4666688
  • [11] Z. Cheng, T. Jiang. (1992). Production of SrCO3 by NH4HCO3 method without removing barium, Huadong Huagong Xueyuan Xueba, 18, pp. 723–728.
  • [12] H. Di, Y. Wang, Y. Zhang. “Preparation of high purity strontium carbonate from Celestine”, Chine HC Patent 1.078.706. 1993.
  • [13] Continuous production of fertilizing salts with derivatives of strontium and gypsum, P. A. Piedrafita. (1991, July 3), EP0495937, [Online]. Available: http://www.google.se/patents/EP0495937A1?cl=sv
  • [14] Production of strontium carbonate from celestite, S. Kocakuşak, R. Tolun, H. Doğan, M. Koral, K. Akçay, H. J. Köroğlu. (2001, October 18). WIPO Patent WO/2001/077021S. [Online]. Available: http://www.google.com/patents/WO2001077021A1?cl=en
  • [15] B. Kacar, A. V. Katkat. ”Gübreler ve Gübreleme Tekniği,” Fen ve Biyoloji Yay. Diz.,vol. 34, no. 849, Nobel ISBN: 978–9944–77–159–7, 2007.
  • [16] P. G. McCormick, F. H. Froes. (1998, November). The fundamentals of mechanochemical processing, JOM. [Online]. pp.61-65. Available: http://download.springer.com/static/pdf/562
  • [17] Q. Zhang, F. Saito. (1997, January ) Mechanochemical processing of celestite, Chem. Eng. J. [Online]. 66. pp. 79–82. Available: http://www.sciencedirect.com/science/article/pii/S1385894796031816
  • [18] A. Obut, P. Balaz, I. Girgin. (2006, August). Direct mechanochemical conversion of celestite to SrCO3, Miner. Eng. [Online]. 19. pp. 1185–1190. Available: http://www.sciencedirect.com/science/article/pii/S0892687505004140
  • [19] M. Erdemoğlu, S. Aydoğan, M. Canbazoğlu. (2007, April). A kinetic study on the conversion of celestite (SrSO4) to SrCO3 by mechanochemical processing, Hydrometallurgy. [Online]. 86. pp. 1–5. Available: http://www.sciencedirect.com/science/article/pii/S0304386X06002544
  • [20] N. Setoudeh, N. J. Welham, S. M. Azami. (2010, March). Dry mechanochemical conversion of SrSO4 to SrCO3, J. Alloy. Comp. [Online]. 492, pp. 389–391. Available: http://www.sciencedirect.com/science/article/pii/S0925838809024396
  • [21] D. Bingöl, S. Aydoğan, S. Karayünlü Bozbaş. (2012, March ) Production of SrCO3 and (NH4)2SO4 by the dry mechanochemical processing of celestite, JIEC. [Online]. 18, pp. 834–838. Available: http://www.sciencedirect.com/science/article/pii/S1226086X11003583
  • [22] D. Bingol, S. Aydogan, S. Karayunlu Bozbas. (2012). Optimization of dry mechanochemical conversion conditions of SrSO4 to SrCO3, Essays on Environmental Studies, 25th section, Athens Institute for Education and Research, Athens, Greece, pp. 265-273.
  • [23] D. Bingöl, S. Aydoğan, S. Karayünlü Bozbaş. (2012, October). Optimization of the wet mechanochemical process conditions of SrSO4 to SrCO3 and (NH4)2SO4 by using response surface methodology, Met. Trans. B. [Online]. 43, pp. 1214–1219. Available: https://www.researchgate.net/publication/257708868
  • [24] D.R. Lide. (1997). Handbook of Chemistry and Physics, 78th ed. CRC Press.
  • [25] A. López–Valdivieso, A. Robledo–Cabrera, A. Uribe–Salas. (2000, September). Flotation of celestite with the anionic collector sodium dodecyl sulfate: Effect of carbonate ions, Int. J. Miner. Process. [Online]. 60, pp. 79– 90. Available: http://www.sciencedirect.com/science/article/pii/S0301751600000041
  • [26] R. Suárez–Orduña, J.C. Rendón–Angeles, L. López–Cuevas, K. Yanagisawa. (2004, July). The conversion of mineral celestite to strontianite under alkaline hydrothermal conditions, J. Phys. Condens. Matter. [Online]. 16 pp. 1331–1344. Available: http://www.sciencedirect.com/science/article/pii/S0301751607000701
  • [27] R. Suárez–Orduña, J. C. Rendón–Angeles, K. Yanagisawa. (2007 March). Kinetic study of the conversion of mineral celestite to strontianite under alkaline hydrothermal conditions, Int. J. Miner. Process. [Online]. 83, pp. 12–18. Available: https://www.researchgate.net/publication/229308904
  • [28] X. Zhu, M. Elomaa, F. Sundholm, C. H. Lochmüller. (1998, December). Infrared and thermogravimetric studies of thermal degradation of polystyrene in the presence of ammonium sulfate, Poly. Deg. &.Stab. [Online]. 62, pp. 487–494. Available: http://www.sciencedirect.com/science/article/pii/S0141391098000329
  • [29] W. Zhou, T. Fukushima, M. Ito. (2006, October). Overlayer adsorbates of NH4 + and SO4
  • 2- on a Pt(111) surface studied by in situ IR spectroscopy, Sci. Technol. Adv. Mater. [Online]. 7, pp. 216–218. Available: http://www.readcube.com/articles/10.1016%2Fj.stam.2005.10.006
Toplam 31 adet kaynakça vardır.

Ayrıntılar

Konular Kimya Mühendisliği
Bölüm Araştırma Makalesi
Yazarlar

Deniz Bingöl Bu kişi benim

Salih Aydoğan Bu kişi benim

Seda Karayünlü Bozbaş Bu kişi benim

Yayımlanma Tarihi 1 Haziran 2017
Gönderilme Tarihi 27 Ocak 2016
Kabul Tarihi 26 Ağustos 2016
Yayımlandığı Sayı Yıl 2017 Cilt: 21 Sayı: 3

Kaynak Göster

APA Bingöl, D., Aydoğan, S., & Karayünlü Bozbaş, S. (2017). Wet Mechanochemical Processing of Celestine using (NH4)2CO3. Sakarya University Journal of Science, 21(3), 278-284. https://doi.org/10.16984/saufenbilder.283291
AMA Bingöl D, Aydoğan S, Karayünlü Bozbaş S. Wet Mechanochemical Processing of Celestine using (NH4)2CO3. SAUJS. Haziran 2017;21(3):278-284. doi:10.16984/saufenbilder.283291
Chicago Bingöl, Deniz, Salih Aydoğan, ve Seda Karayünlü Bozbaş. “Wet Mechanochemical Processing of Celestine Using (NH4)2CO3”. Sakarya University Journal of Science 21, sy. 3 (Haziran 2017): 278-84. https://doi.org/10.16984/saufenbilder.283291.
EndNote Bingöl D, Aydoğan S, Karayünlü Bozbaş S (01 Haziran 2017) Wet Mechanochemical Processing of Celestine using (NH4)2CO3. Sakarya University Journal of Science 21 3 278–284.
IEEE D. Bingöl, S. Aydoğan, ve S. Karayünlü Bozbaş, “Wet Mechanochemical Processing of Celestine using (NH4)2CO3”, SAUJS, c. 21, sy. 3, ss. 278–284, 2017, doi: 10.16984/saufenbilder.283291.
ISNAD Bingöl, Deniz vd. “Wet Mechanochemical Processing of Celestine Using (NH4)2CO3”. Sakarya University Journal of Science 21/3 (Haziran 2017), 278-284. https://doi.org/10.16984/saufenbilder.283291.
JAMA Bingöl D, Aydoğan S, Karayünlü Bozbaş S. Wet Mechanochemical Processing of Celestine using (NH4)2CO3. SAUJS. 2017;21:278–284.
MLA Bingöl, Deniz vd. “Wet Mechanochemical Processing of Celestine Using (NH4)2CO3”. Sakarya University Journal of Science, c. 21, sy. 3, 2017, ss. 278-84, doi:10.16984/saufenbilder.283291.
Vancouver Bingöl D, Aydoğan S, Karayünlü Bozbaş S. Wet Mechanochemical Processing of Celestine using (NH4)2CO3. SAUJS. 2017;21(3):278-84.

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30930 This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.