Theoretical Study of Thermal Conductivities of n- and p-type Doped Mg2Si1-xSnx Thermoelectric Solid Solutions

Yıl 2017, Cilt: 21 Sayı: 6, 1221 - 1228, 01.12.2017

Övgü Ceyda Yelgel

https://doi.org/10.16984/saufenbilder.292752

Öz

Mg₂Si_1-xSn_x
solid solutions are a promising class of thermoelectric materials due to
their high thermoelectric efficiencies at
intermediate temperature range from 500 K to 800 K. Present study presents a theoretical
work of the   thermal conductivities of both n- and
p-type doped Mg₂Si_1-xSn_x solid solutions. The
thermal conductivity contributions arising from carriers (electrons or holes),
electron-hole pairs, and phonons are taken into account separately by employing
the Wiedemann-Franz law, Price's theory, and Debye's isotropic continuum model,
respectively. All phonon scattering mechanisms originate from crystal
boundaries, mass-defects, deformation potentials, and anharmonicity are
investigated rigorously for all solid solutions. The lowest total thermal
conductivity values are obtained as 2.431 WK^-1m^-1 at 700
K for n-type doped Mg₂(Si_0.4Sn_0.6)_0.98Bi_0.02
solid solution and 1.843 WK^-1m^-1 at 600 K for
p-type doped Mg₂(Si_0.3Sn_0.7)_0.95Ga_0.05
solid solution which clearly suggest that p-type doped Mg₂Si_1-xSn_x
based solid solutions are better candidates for the thermoelectric
devices than their n-type doped solid solutions.

Anahtar Kelimeler

thermoelectric materials, thermal conductivity, phonon thermal conductivity

N- ve P-tip Katkılı Mg2Si1-xSnx Katı alaşımlarının termal iletkenliklerinin teorik calışması

Öz

Mg₂Si_1-xSn_x katı
alaşımları yüksek termoelektrik verimlilikleri sebebiyle 500 K’den 800 K’e
kadar olan orta sıcaklılık aralığı için umut vaadeden termoelektrik
materyallerdir. Bu çalışmada hem n- hem p-tip katkılı Mg₂Si_1-xSn_x
katı alaşımlarının termal iletkenlikleri teorik olarak detaylıca incelenmesi
sunulmuştur. Taşıyıcılardan (elektronlar yada holler), elektron-hole
çiftlerinden ve fononlardan kaynaklanan termal iletkenlik katkıları ayrı ayrı
göz önüne alınarak ve sırasıyla Wiedeman-Franz kanunu, Price’in teorisi, ve
Debye’nin izotropik sürekli modeli uygulanarak hesaplanmıştır. Bütün fonon
çarpışma mekanizmaları, kaynağı kristal sınırlarından, kütle bozukluklarından,
bozunum potansiyellerinden ve anharmoniklikten olan katı alaşımların hepsi için
eksiksiz bir şekilde incelenmiştir. En düşük toplam termal iletkenlik değerleri
n-tip katkılı Mg₂(Si_0.4Sn_0.6)_0.98Bi_0.02
katı alaşım için 700 K’de 2.431 WK^-1m^-1 olarak, p-tip
katkılı Mg₂(Si_0.3Sn_0.7)_0.95Ga_0.05
katı alaşım için 600 K’de 1.843 WK^-1m^-1 olarak
bulunmuştur buda açıkca öneriyor ki p-tip katkılı Mg₂Si_1-xSn_x
tabanlı katı alaşımlar n-tip katkılı katı alaşımlarından termoelektrik cihazlar
için daha iyi adaylardır.

Anahtar Kelimeler

termoelektrik materyaller, termal iletkenlik, fonon termal iletkenlik

Kaynakça

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