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Mersin Kuvars Kumunun X-Işınları ile Termoluminesans Özelliklerinin Çalışılması

Yıl 2014, Cilt: 9 Sayı: 2, 71 - 78, 31.12.2014

Öz

Özet: Mersin Yeşilovacık Kuvars yataklarından alınan kuvars kumu örneklerinin Termolüminesansı (TL), oda sıcaklığından 400oC'ye kadar X-ışınları ile ışınlandıktan sonra çalışılmıştır. Termoluminesans tuzak parametreleri Çeşitli Isıtma Hızı Oranı Yöntemi ile hesaplanmıştır. Isıtma hızları 0.5oC/s, 1oC/s, 2oC/s, 5oC/s ve 10oC/s olarak seçilmiştir. TL eğrilerindeki 90oC, 210oC ve 320oC maksimum sıcaklıklarına karşılık gelen tepe değerlerindeki kaymalar farklı ısıtma hızlarına göre tespit edilmiştir. Tepe sıcaklıklarındaki kaymalardan farklı ısıtma yöntemi ile tuzak parametreleri; aktivasyon enerjisi (E), frekans faktörü (s) hesaplanmıştır. Hesaplanan aktivasyon enerjileri ve frekans faktörü sırasıyla 0.84eV, 2.84x1010 s-1, 1.13eV, 2.34x1013 s-1 ve 1.78eV, 1.59x1018s-1 olarak bulunmuştur.

Anahtar kelimeler: Kuvars, termoluminesans, tuzak parametreleri

Studies of Thermoluminescence Properties of Mersin's Quartz Sand with X-ray Irradiation

Abstract: The quartz samples collected from quartz sand deposits from Yeşilovacık Mersin region were studied Thermoluminescence (TL) from room temperature to 400oC after irradiated by X-ray source. Thermoluminescence trap parameters were calculated via Various Heating Rate (VHR) method. Heating rates were selected as 0.5oC/s, 1oC/s, 2oC/s, 5oC/s, 10oC/s. The peak maximum temperature shift values from TL glow curve at 90oC, 210oC and 320oC were monitored by VHR method. The temperature shift along to heating rates were used to calculate the trap parameters as Activation Energy (E) and Frequency Factor (s). The activation and frequency factor values were obtained as 0.84eV, 2.84x1010 s-1, 1.13eV, 2.34x1013 s-1 and 1.78eV, 1.59x1018s-1 at selected peaks.

Key words: Quartz, thermoluminescence, trap parameters

Kaynakça

  • Demange M., 2012. Mineralogy for Petrologists, Taylor & Francis Group, LLC.
  • Heany P.J, Prewitt C.T, Gibbs, G.V., 1994. Silica-physical behaviour, geochemistry and materials application, Reviews in Mineralogy, vol 29. Mineralogical Society of America, Washington, p 606
  • Yokota, R., 1953. Thermoluminescence of Quartz and Fused Quartz Colored by X-Ray Irradiation, Physical Reviews, 91: 1013.
  • Daniels F., Boyd C.A., Saunders D.F., 1953. Thermoluminescence as a research Tool, Science, 117: 343- 349.
  • Fleming SJ., 1970. Thermoluminesans dating refinement of quartz inclusion method, Archaeometry, 12: 135-145.
  • Huntley D.J., Short M.A., Dunphy K., 1996. Deep traps in quartz and their use for optical dating, Canadian Journal of Physics, 74: 81-91.
  • Aitken M.J., 1985. Thermoluminescence Dating, Academic Press, London, p 359.
  • Göksu H.Y., Fremlin J. H., 1972. Thermoluminescence from unirradiated flints: regeneration thermoluminescence, Archaeometry, 14(1): 127–132.
  • [ 9] McKeever, S. W. S., 1985. Thermoluminescence of Solids, Cambridge University Press, Cambridge, UK., p.376.
  • Krbetschek M.R., Goetze J., Dietrich A., Trautmann T., 1997. Spectral information from minerals relevant for luminescence dating, Radiation Measurements, 27(5-6): 695-748.
  • Bİtter-Jensen L., Andersen C. E., Duller G.A.T., Murray A.S., 2003a. Developments in radiation, stimulation and observation facilities in luminescence measurements, Radiation Measurements, 37: 535-541.
  • Gartia R. K., Singh L.L., 2011. Evaluation of trapping parameter of quartz by deconvolution of the glow curves, Radiation Measurements, 46: 664-668.
  • Wintle V., 1975. Thermal quenching of thermoluminescence in Quartz, Geophysical Journal of the Royal Astronomical Society, 41: 107-113.
  • Demars, C., Pagel M., Deloule E., Blanc P., 1996. Cathodoluminescence of Quartz From Sandstones: Interpretation of The Uv Range by Determination of Trace Element Distributions and Fluid- Inclusion P-T-X Properties in Authigenic Quartz, American Mineralogist, 81: 891-901.
  • Huntley D. J., Godfrey-Smith, D. I., Haskell, E. H., 1991. Light-induced emission spectra from some quartz and feldspars, International Journal of Radiation Applications and Instrumentation, 18: 127- 131.
  • Smith B. W., Rhodes E. J., Stokes S., Spooner N.A., 1990. The optical dating of sediments using quartz, Radiation Protection Dosimetry, 34: 75-78.
  • Topaksu M., Dogan T., Yüksel M., Kurt K., Topak Y., Yegingil Z., 2014. Comparative study of the thermoluminescence properties of natural metamorphic quartz belonging to Turkey and Spain, Radiation Physics and Chemistry, 96: 223–228.
  • Bohum A., 1954. Emission aus nichtmetallischen kristallen, Czechoslovak Journal of Physics, 4:91-99.
  • Hoogenstraaten W., 1958. Electron traps in zinc-sulphide phosphors, Philiphs Research Reports, 13: 515- 693.
  • Kitis G., Tuyn J. W. N., 1999. Correction for temperature lag and thermal gradient effects arising during thermoluminescence readout, Radiation Protection Dosimetry, 84(1-4): 371-374.
  • Pagonis V., Tatsis E., Kitis G., Drupieski C., 2002. Search for common characteristics in the glow curves of quartz of various origins, Radiation Protection Dosimetry, 100(1-4): 373-376.
  • Yazici A. N., Topaksu M. 2003. The analysis of thermoluminescence glow peaks of unannealed synthetic quartz, Journal of Physics D: Applied Physics, 36: 620–627.
  • Petrov S. A., Bailiff I. K., 1995. The 110°C TL Peak in synthetic quartz, Radiation Measurements, 24(4): 519-523.
  • İlbilge Özsu e-posta: ilbilgeozsu@gmail.com

Mersin Kuvars Kumunun X-Işınları ile Termoluminesans Özelliklerinin Çalışılması

Yıl 2014, Cilt: 9 Sayı: 2, 71 - 78, 31.12.2014

Öz

The quartz samples collected from quartz sand deposits from Yeşilovacık Mersin region were studied Thermoluminescence (TL) from room temperature to 400oC after irradiated by X-ray source. Thermoluminescence trap parameters were calculated via Various Heating Rate (VHR) method. Heating rates were selected as 0.5oC/s, 1oC/s, 2oC/s, 5oC/s, 10oC/s. The peak maximum temperature shift values from TL glow curve at 90oC, 210oC and 320oC were monitored by VHR method. The temperature shift along to heating rates were used to calculate the trap parameters as Activation Energy (E) and Frequency Factor (s). The activation and frequency factor values were obtained as 0.84eV, 2.84x1010 s-1, 1.13eV, 2.34x1013 s-1 and 1.78eV, 1.59x1018s-1 at selected peaks

Kaynakça

  • Demange M., 2012. Mineralogy for Petrologists, Taylor & Francis Group, LLC.
  • Heany P.J, Prewitt C.T, Gibbs, G.V., 1994. Silica-physical behaviour, geochemistry and materials application, Reviews in Mineralogy, vol 29. Mineralogical Society of America, Washington, p 606
  • Yokota, R., 1953. Thermoluminescence of Quartz and Fused Quartz Colored by X-Ray Irradiation, Physical Reviews, 91: 1013.
  • Daniels F., Boyd C.A., Saunders D.F., 1953. Thermoluminescence as a research Tool, Science, 117: 343- 349.
  • Fleming SJ., 1970. Thermoluminesans dating refinement of quartz inclusion method, Archaeometry, 12: 135-145.
  • Huntley D.J., Short M.A., Dunphy K., 1996. Deep traps in quartz and their use for optical dating, Canadian Journal of Physics, 74: 81-91.
  • Aitken M.J., 1985. Thermoluminescence Dating, Academic Press, London, p 359.
  • Göksu H.Y., Fremlin J. H., 1972. Thermoluminescence from unirradiated flints: regeneration thermoluminescence, Archaeometry, 14(1): 127–132.
  • [ 9] McKeever, S. W. S., 1985. Thermoluminescence of Solids, Cambridge University Press, Cambridge, UK., p.376.
  • Krbetschek M.R., Goetze J., Dietrich A., Trautmann T., 1997. Spectral information from minerals relevant for luminescence dating, Radiation Measurements, 27(5-6): 695-748.
  • Bİtter-Jensen L., Andersen C. E., Duller G.A.T., Murray A.S., 2003a. Developments in radiation, stimulation and observation facilities in luminescence measurements, Radiation Measurements, 37: 535-541.
  • Gartia R. K., Singh L.L., 2011. Evaluation of trapping parameter of quartz by deconvolution of the glow curves, Radiation Measurements, 46: 664-668.
  • Wintle V., 1975. Thermal quenching of thermoluminescence in Quartz, Geophysical Journal of the Royal Astronomical Society, 41: 107-113.
  • Demars, C., Pagel M., Deloule E., Blanc P., 1996. Cathodoluminescence of Quartz From Sandstones: Interpretation of The Uv Range by Determination of Trace Element Distributions and Fluid- Inclusion P-T-X Properties in Authigenic Quartz, American Mineralogist, 81: 891-901.
  • Huntley D. J., Godfrey-Smith, D. I., Haskell, E. H., 1991. Light-induced emission spectra from some quartz and feldspars, International Journal of Radiation Applications and Instrumentation, 18: 127- 131.
  • Smith B. W., Rhodes E. J., Stokes S., Spooner N.A., 1990. The optical dating of sediments using quartz, Radiation Protection Dosimetry, 34: 75-78.
  • Topaksu M., Dogan T., Yüksel M., Kurt K., Topak Y., Yegingil Z., 2014. Comparative study of the thermoluminescence properties of natural metamorphic quartz belonging to Turkey and Spain, Radiation Physics and Chemistry, 96: 223–228.
  • Bohum A., 1954. Emission aus nichtmetallischen kristallen, Czechoslovak Journal of Physics, 4:91-99.
  • Hoogenstraaten W., 1958. Electron traps in zinc-sulphide phosphors, Philiphs Research Reports, 13: 515- 693.
  • Kitis G., Tuyn J. W. N., 1999. Correction for temperature lag and thermal gradient effects arising during thermoluminescence readout, Radiation Protection Dosimetry, 84(1-4): 371-374.
  • Pagonis V., Tatsis E., Kitis G., Drupieski C., 2002. Search for common characteristics in the glow curves of quartz of various origins, Radiation Protection Dosimetry, 100(1-4): 373-376.
  • Yazici A. N., Topaksu M. 2003. The analysis of thermoluminescence glow peaks of unannealed synthetic quartz, Journal of Physics D: Applied Physics, 36: 620–627.
  • Petrov S. A., Bailiff I. K., 1995. The 110°C TL Peak in synthetic quartz, Radiation Measurements, 24(4): 519-523.
  • İlbilge Özsu e-posta: ilbilgeozsu@gmail.com
Toplam 24 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Metroloji,Uygulamalı ve Endüstriyel Fizik
Bölüm Makaleler
Yazarlar

İlbilge Özsu

Kasım Kurt

Yayımlanma Tarihi 31 Aralık 2014
Yayımlandığı Sayı Yıl 2014 Cilt: 9 Sayı: 2

Kaynak Göster

IEEE İ. Özsu ve K. Kurt, “Mersin Kuvars Kumunun X-Işınları ile Termoluminesans Özelliklerinin Çalışılması”, Süleyman Demirel University Faculty of Arts and Science Journal of Science, c. 9, sy. 2, ss. 71–78, 2014.