2,4,6-Trinitrofenol ve Trinitrotoluen ile 1-Bromopiren Arasında Oluşan Yeni Enerjik Ko-kristalin Karakterizasyonu ve Enerjik Performans Özellikleri

Year 2019, Volume: 14 Issue: 1, 136 - 149, 31.05.2019

Nilgün Şen , Sinecan İrem Bozkuş

https://doi.org/10.29233/sdufeffd.537748

Cited By: 2

Abstract

Ko-kristallendirme, 1:1
molar oranda Pikrik asit ile 1-Bromopiren ve TNT ile 1-Bromopiren arasında
çözücü buharlaştırma yöntemiyle hazırlandı ve ko-kristallerin yapısı tek
kristal ve toz X ışını kırınımı, Kütle spektrometresi, Kızılötesi
spektroskopisi ile karekterize edildi. Kırınım verileri analizi,
ko-kristallerin öncelikle donor-alıcı (elektron verici-elekton alıcı) π…π
istifleme etkileşimlerinden oluştuğunu ortaya koydu. Darbe hassasiyeti testleri
sonucu yapılan ölçümler ile TNT: 1-Bromopiren ve Pikrik Asit: 1-Bromopiren
ko-kristalleri, saf TNT, Picric Acid'e kıyasla önemli ölçüde azaltılmış darbe
duyarlılığını göstermiştir. Elde edilen yeni enerjik ko-kristaller detaylı calışması
ile  yoğunluk, oksijen dengesi, erime
noktası, ayrışma sıcaklığı, patlama performansı (hız, basınç) gibi önemli
fiziksel ve kimyasal özelliklerin değiştiğini ortaya koymaktadır.
Ko-kristalizasyon calişmasi ile  yeni
keşfedilen alternatif enerjik maddelerin iyileştirilmiş özelliğe sahip olduğunu
ve mevcut enerjik materyalin fiziksel ve kimyasal özelliklerini değiştirmenin
etkili bir yöntem olduğunu vurgulamaktadır.

Keywords

Enerjik madde, 246-Trinitrofenol, Trinitrotoluen, Ko-kristallenme, Patlayıcı Hassasiyeti, Patlayıcı Performansı

Characterization and Energetic Performance Properties of New Energetic Co-crystals formed between 2, 4, 6-Trinitrophenol, Trinitrotoluene and 1-Bromopyrene

Abstract

A 1:1 co-crystals of Picric
Acid with 1-Bromopyrene and TNT with 1-Bromopyrene were prepared by a solvent
evaporation method, and the structure of the co-crystals were determined by
single-crystal and powder X-ray diffraction, Mass spectrometry, Infrared
spectroscopy techniques. The diffraction data analysis revealed that the
co-crystals are primarily formed through donor-acceptor π…π stacking
interactions. The TNT:1-Bromopyrene and Picric Acid:1-Bromopyrene co-crystals
indicates significantly reduced impact sensitivity relative to pure TNT, Picric
Acid. A detailed study of the cocrystals formed reveals a modification of
crucial properties including density, oxygen balance, melting point,
decomposition temperature detonation performance (velocity, pressure). The acquired
results highlight that co-crystallization provides the newly discovered
energetic material with attractive properties, and is an effective way to alter
existing energetic material. 

Keywords

Energetic material, 246-Trinitrophenol, Trinitrotoluene, Co-crystallisation, Explosive sensitivity, Explosive performance

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