Kil Esaslı Bütünüyle-Katı-Hal Kompozit Kurşun (II)-Seçici Potansiyometrik Elektrot

Yıl 2022, Cilt: 7 Sayı: 1, 8 - 21, 29.06.2022

Bilge Doğan , Bülent Çağlar , Cihan Topcu , Fatih Çoldur , Agah Özdemir , Eda Keleş Güner , Osman Çubuk , Volkan Özdokur

https://doi.org/10.33484/sinopfbd.1080403

Cited By: 1

Öz

Bentonit kili XRD, FTIR ve SEM-EDX teknikleriyle karakterize edildi. Karakterize edilen kil bütünüyle katı hal kompozit potansiyometrik elektrot yapımında iyonofor madde olarak kullanılmış ve kilin potansiyometrik uygulaması gerçekleştirilmiştir. Elektrodun Pb2+ iyonuna karşı, diğer yaygın inorganik katyonlarla karşılaştırıldığında oldukça duyarlı ve seçici potansiyometrik bir cevap sergilediği gözlemlenmiştir. Membran optimizasyon çalışmaları neticesinde en iyi potansiyometrik performans özellikleri sergileyen bileşimin kütlece % 65.0 grafit, % 5.0 çok duvarlı karbon nanotüp, %20.0 iyonofor (bentonit) ve %10.0 parafin yağı olduğu belirlenmiştir. Pb2+ seçici kompozit elektrodun 1.0×10-5 ˗ 1.0×10-1 M konsantrasyon aralığında doğrusal cevap sergilediği, doğrusal çalışma aralığında standart Pb2+ çözeltilerine karşı her 10 katlık konsantrasyon değişiminde ortalama 31 mV potansiyel fark sergilediği gözlenmiştir. Elektrodun tayin sınırı 9.0×10-6 M olarak hesaplanmıştır. Elektrodun cevap zamanının oldukça kısa olduğu (~5 s) potansiyometrik cevabın ve tekrarlanabilirliğinin de oldukça yüksek olduğu ortaya konmuştur.

Anahtar Kelimeler

Bentonit, XRD, kurşun, potansiyometrik elektrot

Destekleyen Kurum

Erzincan Binali Yıldırım Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğünün (BAP)

Proje Numarası

FBA-2020-687

All-Solid-State Composite Lead (II)-Selective Potentiometric Electrode Based on Clay

Öz

The bentonite clay was characterized by XRD, FTIR and SEM-EDX techniques. The characterized bentonite clay was used as an ionophore material in the production of solid state composite potentiometric electrodes and its potentiometric electrode application was carried out. It was observed that the electrode exhibited a highly sensitive and selective potentiometric response to Pb2+ ion compared to other common inorganic cations. Membrane optimization studies indicated that the composition exhibiting the best potentiometric performance properties was 65.0% graphite, 5.0% multi-walled carbon nanotube, 20.0% ionophore (bentonite) and 10.0% paraffin oil by mass. It was also observed that the Pb2+ selective composite electrode exhibited a linear response in the concentration range of 1.0×10-5 ˗ 1.0×10-1 M with an average potential difference of 31 mV for each 10-fold Pb2+concentration change in the linear operating range. The detection limit of the electrode was calculated as 9.0×10-6 M. It was also revealed that the response time of the electrode was quite short (~5 s) and the reproducibility of the potentiometric response was quite high.

Anahtar Kelimeler

Bentonite, XRD, lead, potentiometric electrode

Proje Numarası

FBA-2020-687

Kaynakça

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