Synthesis of Versatile s-Triazine Ligands and Investigation of Salen/Salophen Fe(III)/Cr(III) Metal Complexes

Abstract

In this study, cyanuric chloride was used as a starting material. Cyanuric chloride, given in the literature making use of methods in acetone end of the 5-hydroxyisophtalic acid chloride using 0 oC onedirectional (monopodal) 2,4-dichloro-6-(3,5-dicarboxyphenoxy)-1,3,5-triazine (MNCHIPA) and at room temperature bidirectional (dipodal) 2-chloro-4,6-(2,5-dicarboxyphenylphenoxy)-1,3,5-triazine (DPCHIPA) compounds were synthesized. Dissolved in ethanol 2,4,6-tris(3,5-dicarboxyphenoxy)-s-triazines ligands dissolved in ethanol ligand complexes [Fe(salen/saloph)]2O, [Cr(salen/saloph)]2O by the addition of double-oxygen-coordinated, synthesis of complexes with monopodal/dipodal was performed in conclusion, two different ligands and this ligands of salen/salophenFe(III)/Cr(III) complexes were isolated and their structures were characterized by FT-IR and 1H NMR spectra, elemental analysis and magnetic susceptibility.

Keywords

• s-Triazine
• Cyanuric chloride
• 5-Hydroxyisophtalic acid
• Salen
• Salophen
• Transition Metals

Çok Yönlü s-Triazin Ligandlarinin Sentezi ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi

Abstract

Bu çalışmada çıkış maddesi olarak siyanür klorür kullanıldı. Siyanür klorür, literatürde verilen metotlardan faydalanılarak asetonlu ortamda farklı klor uçlarından 5-hidroksiizoftalik asit kullanılarak 0 oC bir yönlü (monopodal) 2,4-dikloro-6-(3,5-dikarboksifenoksi)-1,3,5-triazin (MNCHIPA) ve oda sıcaklığında iki yönlü (dipodal) 2-kloro-4,6-(2,5-dikarboksifenilfenoksi)-1,3,5-triazin (DPCHIPA) bileşikleri sentezlendi. Etanollü ortamda çözülmüş, ligandlara ve yine etanolde çözülmüş ligand kompleksleri [Fe(salen/saloph)]2O, [Cr(salen/saloph)]2O ilave edilerek çift oksijenle koordine olmuş monopodal/dipodal komplekslerinin sentezi gerçekleştirildi. Sonuç olarak, monopodal/dipodal-s-triazin ligandı ve bu ligandın salen/salophFe(III)/Cr(III) kompleksleri izole edilerek, elementel analizleri, FT-IR, 1H-NMR spektrumları ve manyetik süssebtibilite ölçümleri alınarak yapıları aydınlatıldı..

Keywords

• s-triazine
• siyanür klorür
• 5-hidroksiizoftalik asit
• salen
• saloph
• geçiş metaller

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