Calix[4]arene-based Langmuir-Blodgett (LB) Thin Film for Volatile Organic Compounds Detection

Yıl 2021, Cilt: 47 Sayı: 1, 110 - 117, 30.04.2021

Yaser Açıkbaş Nursel Zeybek

Öz

In this study, the sensing ability of the calix[4]arene-based Langmuir-Blodgett (LB) thin films were investigated by using Surface Plasmon Resonance (SPR) technique. Dichloromethane, acetone and benzene vapors were selected as a harmful Volatile Organic Compounds (VOCs) to examine the kinetic responses of the calix[4]arene-based LB thin films against to these organic vapors at room temperature. Two calix[4]arene-based chemical sensors were prepared at different thickness values (4 and 8 LB thin film layers) to examine the effect on sensitivity of chemical sensor. The calix[4]arene-based chemical sensor prepared with 4 LB layers was found to be higher sensitive than prepared with 8 LB layers with fast response and recovery times. All kinetic measurements represented that the calix[4]arene molecule used in this study is a promising material for the development of chemical sensor devices at the room temperature with sensitivities between 0.66 and 1.41 percent response ppm−1.

Anahtar Kelimeler

Volatile Organic Compounds, Calix[4]arene, Optical sensor, Langmuir-Blodgett thin film

Proje Numarası

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Uçucu Organik Bileşiklerin Dedeksiyonu için Kaliks[4]aren Tabanlı Langmuir-Blodgett (LB) İnce Filmler

Öz

Bu çalışmada, Yüzey Plazmon Rezonans (YPR) tekniği kullanılarak kaliks[4]aren tabanlı Langmuir-Blodgett (LB) ince filmlerin hassasiyet yetenekleri araştırıldı. Kaliks[4]aren tabanlı Langmuir-Blodgett (LB) ince filmlerin zararlı Uçucu Organik Bileşikler (UOB)olarak seçilen diklorometan, aseton ve benzene buharlarına karşı kinetik tepkisi oda sıcaklığında incelendi. Kalınlığın kimyasal sensörün hassasiyeti üzerinde etkisini incelemek için iki kaliks[4]aren tabanlı kimyasal sensör farklı kalınlık değerlerinde (4 ve 8 LB ince film tabakaları) hazırlandı. 4 tabaka LB ince film kaplanarak hazırlanan kaliks[4]aren tabanlı kimyasal sensörün hızlı tepki ve kendini yenileme süresi ile 8 tabaka LB ince film kaplanarak hazırlanan kaliks[4]aren tabanlı kimyasal sensörden daha fazla hassasiyet göstermiştir. Bütün kinetik ölçümler, bu çalışmada kullanılan kaliks[4]aren molekülü 0.66 and 1.41 %. ppm−1 hassasiyet değer aralığı ile oda sıcaklığında kimyasal sensör cihazlarının geliştirilmesi için umut verici bir malzeme olabileceğini göstermiştir.

Anahtar Kelimeler

Uçucu Organik Bileşikler, Kaliks[4]aren, Optiksel sensör, Langmuir-Blodgett ince film

Destekleyen Kurum

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Proje Numarası

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Teşekkür

We thank Prof. Dr. Rifat Çapan, Prof. Dr. Matem Erdoğan, Prof. Dr. Abdulkadir Sırıt, Doç. Dr. Selahattin Bozkurt and Cansu Özkaya for their helpful discussions.

Kaynakça

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