Yıl 2021, Cilt 8 , Sayı 1, Sayfalar 23 - 29 2021-01-23

Adsorption of Malachite Green by An Agricultural Waste: Rice Husk
Tarımsal bir Atık Tarafından Malaşit Yeşilinin Adsorpsiyonu: Pirinç Kavuzu

Nagihan METİN [1] , Serpil SAVCI [2]


The main objective of this research was to investigate the adsorption of malachite green as a cationic dye on rice husk as an agricultural waste. Effect of initial dye concentration, pH and time was evaluated. The adsorption data were calculated Langmuir, Freundlich isotherm model and kinetics. Langmuir isotherm (Qmax=8.688 mg/g) is more fitted than Freundlich isotherm. Scanning electron microscope (SEM) results described that characterization of rice husk. Pseudo second order kinetic model fitted well for removal of malachite green. Thus, rice husk was using no-cost and effective adsorbent for adsorption of cationic dyes.
Bu çalışmanın temel amacı, tarımsal bir atık olarak pirinç kavuzu üzerine katyonik bir boya olarak malaşit yeşilinin adsorpsiyonunun araştırılmasıdır. Başlangıç boya konsantrasyonu, pH ve zamanın etkisi araştırılmıştır. Adsorpsiyondan elde edilen verilerle Langmuir, Freundlich izoterm modelleri ve kinetikler hesaplanmıştır. Langmuir izotermi (Qmax=8.688 mg/g) Freundlich izoterminden daha iyi uyum sağlamıştır. Pirinç kavuzunun karakterizasyonu taramalı elektron mikroskopu (SEM) ile tespit edilmiştir. Yalancı ikinci derece kinetic model malaşit yeşilinin gideriminde uyum sağlamıştır. Sonuç olarak pirinç kavuzu katonik boyaların adsorpsiyonunda etkili ve maliyetsiz bir adsorban olarak kullanılabilmiştir.
  • Abbas, M., Hussain, T., Arshad, M., Ansari, A. R., Irshad, A., Nisar, J., Hussain, F., Masood, N., Nazir, A., Iqbal, M., 2019. Wound healing potential of curcumin cross-linked chitosan/polyvinyl alcohol, Int. J. Biol. Macromol. 140:871–876.
  • Chowdhury, S., Mishra, R., Saha, P., Kushwaha, P., 2011. Adsorption thermodynamics, kinetics and isosteric heat of adsorption of malachitegreen onto chemically modified rice husk. Desalination, 265:159-168.
  • Ghourbanpour, J., Sabzi, M., Shafagh, N., 2019. Effective dye adsorption behavior of poly (vinyl alcohol)/chitin nanofiber/Fe(III) complex, Int. J. Biol. Macromol. 137:296–306.
  • Gosavi V. D., Sharma, S., 2013. A General Review on Various Treatment Methods for Textile Wastewater. Journal of Environmental Science, Computer Science and Engineering & Technology; 3: 029-039.
  • Guo, Y., Yang, S., Fu, W., Qi, J., Li, R., Wang, Z., Xu, H., 2003. Adsorption of malachite green on micro- and mesoporous rice husk-based active carbon. Dyes and Pigments 56:219–229.
  • Hameed, B. H., Mahmoud, D. K., Ahmad, A. L., 2008. Equilibrium modeling and kineticstudies on the adsorption of basic dye by a low-cost adsorbent: coconut(Cocos nucifera) bunch waste, J. Hazard. Mater. 158:65–72.
  • Hameed, B. H., 2008. Equilibrium and kinetic studies of methyl violet sorption byagricultural waste, J. Hazard. Mater. 154:204–212.
  • Ho, Y. S., McKay, G., 1998. Sorption of dye from aqueous solution by peat, Chem. Eng. J. 70: 115–124.
  • Ishtiaq, F., Bhatti, H. N., Khan, A., Iqbal, M., Kausar, A., 2020. Polypyrole, polyaniline and sodium alginate biocomposites and adsorption-desorption efficiency for imidacloprid insecticide, Int. J. Biol. Macromol. 147: 217–232.
  • Johar, N., Ahmad, I., Dufresne, A., 2012. Extraction, preparation and characterization of cellulose fibres and nanocrystals from rice husk, Ind. Crop. Prod. 37:93–99.
  • Kalita, E., Nath, B. K., Deb, P., Agan, M. R. Islam, Saikia, K., 2015. High quality fluorescent cellulose nanofibers from endemic rice husk: isolation and characterization, Carbohydr. Polym. 122:308–313.
  • Leung, A.C.W., Lam, E., Chong,J., Hrapovic, S., Luong, J.H.T., 2013. Reinforced plastics and aerogels by nanocrystalline cellulose, J. Nanopart. Res. 15:1636.
  • Leng, L., Yuan, X., Zeng, G., Shao, J., Chen, X., Wu, Z., Wang, H., Peng, X., 2015. Surface characterization of rice husk bio-char produced by liquefaction and application for cationic dye (Malachite green) adsorption. Fuel, 155:77-85.
  • Li, J., Li, H., Yuan, Z., Fang, J., Chang, L., Zhang, H., Li, C., 2019. Role of sulfonation in lignin-based material for adsorption removal of cationic dyes, Int. J. Biol. Macromol. 135:1171–1181.
  • Lou, T., Yan, X., Wang, X., 2019. Chitosan coated polyacrylonitrile nanofibrous mat for dye adsorption, Int. J. Biol. Macromol. 135:919–925.
  • Moon, R. J., Martini, A., Nairn, J., Simonsen, J., Youngblood, J., 2011. Cellulose nanomaterials review: structure, properties and nanocomposites, Chem. Soc. Rev. 40: 3941–3994.
  • Noreen, S., Bhatti, H. B., Iqbal, H., Hussain, F., Sarim, F. M., 2020. Chitosan, starch, polyaniline and polypyrrole biocomposite with sugarcane bagasse for the efficient removal of Acid Black dye, Int. J. Biol. Macromol. 147:439–452.
  • Santos, M. S. F., Schaule, G., Alves, A., Madeira, L. M., 2013. Adsorption of paraquat herbicide on deposits from drinking water Networks. Chem. Eng. J., 229:324-333.
  • Sharma, R. K., Kumar, R., 2019. Functionalized cellulose with hydroxyethyl methacrylate and glycidyl methacrylate for metal ions and dye adsorption applications, Int. J. Biol. Macromol. 134:704–721.
  • Saroj, S., Singh, S. W., Mohan, D., 2015. Removal of Colour (Direct Blue 199) from Carpet Industry Wastewater Using Different Biosorbents (Maize Cob, Citrus Peel and Rice Husk). Arab J Sci Eng, 40:1553–1564.
  • Uma R., Lakshmi, Srivastava, V. C., 2009. Indra Deo Mall, Dilip H. Lataye, Rice husk ash as an effective adsorbent: Evaluation of adsorptive characteristics for Indigo Carmine dye. Journal of Environmental Management 90:710-720.
  • Venkat S. Mane1, Indra Deo Mall_, Vimal Chandra Srivastava, 2007. Kinetic and equilibrium isotherm studies for the adsorptive removal of Brilliant Green dye from aqueous solution by rice husk ash. Journal of Environmental Management 84:390–400.
  • Weber W. J., Morris, J. C., Sanit. J., 1963. Eng. Div. Am. Soc. Civil Engineer, 89, 31.
Birincil Dil en
Konular Fen
Bölüm Araştırma Makaleleri
Yazarlar

Orcid: 0000-0000-0000-0000
Yazar: Nagihan METİN
Kurum: Yozgat Bozok University
Ülke: Turkey


Orcid: 0000-0003-2015-2223
Yazar: Serpil SAVCI (Sorumlu Yazar)
Kurum: YOZGAT BOZOK ÜNİVERSİTESİ
Ülke: Turkey


Tarihler

Yayımlanma Tarihi : 23 Ocak 2021

Bibtex @araştırma makalesi { turkjans749218, journal = {Türk Tarım ve Doğa Bilimleri Dergisi}, issn = {2148-3647}, address = {}, publisher = {Mevlüt AKÇURA}, year = {2021}, volume = {8}, pages = {23 - 29}, doi = {10.30910/turkjans.749218}, title = {Adsorption of Malachite Green by An Agricultural Waste: Rice Husk}, key = {cite}, author = {Metin, Nagihan and Savcı, Serpil} }
APA Metin, N , Savcı, S . (2021). Adsorption of Malachite Green by An Agricultural Waste: Rice Husk . Türk Tarım ve Doğa Bilimleri Dergisi , 8 (1) , 23-29 . DOI: 10.30910/turkjans.749218
MLA Metin, N , Savcı, S . "Adsorption of Malachite Green by An Agricultural Waste: Rice Husk" . Türk Tarım ve Doğa Bilimleri Dergisi 8 (2021 ): 23-29 <https://dergipark.org.tr/tr/pub/turkjans/issue/60017/749218>
Chicago Metin, N , Savcı, S . "Adsorption of Malachite Green by An Agricultural Waste: Rice Husk". Türk Tarım ve Doğa Bilimleri Dergisi 8 (2021 ): 23-29
RIS TY - JOUR T1 - Adsorption of Malachite Green by An Agricultural Waste: Rice Husk AU - Nagihan Metin , Serpil Savcı Y1 - 2021 PY - 2021 N1 - doi: 10.30910/turkjans.749218 DO - 10.30910/turkjans.749218 T2 - Türk Tarım ve Doğa Bilimleri Dergisi JF - Journal JO - JOR SP - 23 EP - 29 VL - 8 IS - 1 SN - 2148-3647- M3 - doi: 10.30910/turkjans.749218 UR - https://doi.org/10.30910/turkjans.749218 Y2 - 2020 ER -
EndNote %0 Türk Tarım ve Doğa Bilimleri Dergisi Adsorption of Malachite Green by An Agricultural Waste: Rice Husk %A Nagihan Metin , Serpil Savcı %T Adsorption of Malachite Green by An Agricultural Waste: Rice Husk %D 2021 %J Türk Tarım ve Doğa Bilimleri Dergisi %P 2148-3647- %V 8 %N 1 %R doi: 10.30910/turkjans.749218 %U 10.30910/turkjans.749218
ISNAD Metin, Nagihan , Savcı, Serpil . "Adsorption of Malachite Green by An Agricultural Waste: Rice Husk". Türk Tarım ve Doğa Bilimleri Dergisi 8 / 1 (Ocak 2021): 23-29 . https://doi.org/10.30910/turkjans.749218
AMA Metin N , Savcı S . Adsorption of Malachite Green by An Agricultural Waste: Rice Husk. TTDBD. 2021; 8(1): 23-29.
Vancouver Metin N , Savcı S . Adsorption of Malachite Green by An Agricultural Waste: Rice Husk. Türk Tarım ve Doğa Bilimleri Dergisi. 2021; 8(1): 23-29.
IEEE N. Metin ve S. Savcı , "Adsorption of Malachite Green by An Agricultural Waste: Rice Husk", Türk Tarım ve Doğa Bilimleri Dergisi, c. 8, sayı. 1, ss. 23-29, Oca. 2021, doi:10.30910/turkjans.749218