rGO/SnSbS Nanokompozitlerin Farklı Depolama Sıcaklığına Bağlı Elektriksel, Yapısal ve Yüzeysel Değerlendirmesi

Necmi Serkan Tezel; Afşin Kariper

doi:10.29137/umagd.1062439

EN TR

Electrical, Structural, Surface Evaluation Depends on the Different Deposition Temperature of rGO/SnSbS Nanocomposite

Abstract

In this study, reduced graphene oxide/sulfosalt (rGO/SnSbS) nanocomposite structures were produced at temperatures of 20 °C, 40 °C, 60 °C and 80°C with chemical bath deposition (CBD) method on commercial glass substrates. Structurally, it has an amorphous structure at low temperature values, but crystallizations of Sn2Sb2S5 have been observed at the temperature of 80 °C. It has been observed that nanocomposite structures with thickness of 125.22 nm, 126.27nm, 132.95 nm and 157.16 nm due to increased deposition temperatures have a more homogeneous and dense adhesive consistency. Their electrical resistance was calculated from I-V measurements depending on the film thickness using the four-point probe method, and it was observed that the electrical resistance decreased with increasing temperature. According to the obtained results, the effect of temperature and their usage applications have been discussed.

Keywords

Thin film; CBD, Sulfosalt, Electrical resistivity, Deposition Temperature

Project Number

KBÜBAP-21-DS-012

rGO/SnSbS Nanokompozitlerin Farklı Depolama Sıcaklığına Bağlı Elektriksel, Yapısal ve Yüzeysel Değerlendirmesi

Abstract

Bu çalışmada indirgenmiş grafen oksit/sülfosalt (rGO/SnSbS) nanokompozit yapıları ticari cam taban malzemeler üzerine kimyasal banyo depolama (CBD) metodu ile 20 °C, 40 °C, 60 °C ve 80 °C sıcaklıklarda üretilmiştir. Yapısal olarak düşük sıcaklık değerlerinde amorf yapıya sahiptir ancak 80 °C sıcaklıkta Sn2Sb2S5 kristallenmeleri gözlenmiştir. Artan depolama sıcaklığına bağlı 125,22 nm, 126,27nm, 132,95 nm ve 157,16 nm kalınlıklı nanokompozit yapıların daha homojen ve yoğun yapışkan kıvama geldiği görülmüştür. Elektriksel dirençleri ise four-point probe metodu ile film kalınlığına bağlı olarak I-V ölçümlerinden hesaplanmıştır ve sıcaklığın artması ile elektriksel dirençlerin düştüğü görülmüştür. Elde edilen verilere göre sıcaklığın etkisi ve kullanım alanları tartışılmıştır.

Keywords

İnce film, CBD, Sülfosalt, Elektrik direnci, Depolama sıcaklığı

Supporting Institution

Karabük Üniversitesi Bilimsel Araştırma Projeleri Birimi

Project Number

KBÜBAP-21-DS-012

Thanks

Bu çalışma Karabük Üniversitesi Bilimsel Araştırma Projeleri Birimi tarafından KBÜBAP-21-DS-012 nolu proje ile desteklenmiştir. Finansal desteklerinden dolayı KBU-BAP birimine teşekkür ederiz.

References

Abdelkader, D., ben Rabeh, M., Khemiri, N., & Kanzari, M. (2014). Investigation on optical properties of SnxSbyS z sulfosalts thin films. Materials Science in Semiconductor Processing, 21(1), 14–19. doi.org/10.1016/j.mssp.2014.01.027
Abdelkader, D., Chaffar Akkari, F., Khemiri, N., Gallas, B., Antoni, F., & Kanzari, M. (2015). Structural and spectroscopic ellipsometry studies on vacuum-evaporated Sn2m-4Sb4S2m+2 (m = 2.5, 3 and 4) thin films deposited on glass and Si substrates. Journal of Alloys and Compounds, 646, 1049–1057. doi.org/10.1016/j.jallcom.2015.06.114
Akram, M., Saleh, A. T., Ibrahim, W. A. W., Awan, A. S., & Hussain, R. (2016). Continuous microwave flow synthesis (CMFS) of nano-sized tin oxide: Effect of precursor concentration. Ceramics International, 42(7), 8613–8619. doi.org/10.1016/j.ceramint.2016.02.092
Antitomaso, P., Fraisse, B., Sougrati, M. T., Morato-Lallemand, F., Biscaglia, S., Aymé-Perrot, D., Girard, P., & Monconduit, L. (2016). Ultra-fast dry microwave preparation of SnSb used as negative electrode material for Li-ion batteries. Journal of Power Sources, 325, 346–350. doi.org/10.1016/j.jpowsour.2016.06.010
Chen, J., & Cheng, F. (2009). Combination of lightweight elements and nanostructured materials for batteries. Accounts of Chemical Research, 42(6), 713–723. doi.org/10.1021/ar800229g
Dittrich, H., Stadler, A., Topa, D., Schimper, H. J., & Basch, A. (2009). Progress in sulfosalt research. Physica Status Solidi (A) Applications and Materials Science, 206(5), 1034–1041. doi.org/10.1002/pssa.200881242
Dong, X., Liu, W., Chen, X., Yan, J., Li, N., Shi, S., Zhang, S., & Yang, X. (2018). Novel three dimensional hierarchical porous Sn-Ni alloys as anode for lithium ion batteries with long cycle life by pulse electrodeposition. Chemical Engineering Journal, 350, 791–798. doi.org/10.1016/j.cej.2018.06.031
Duan, J., Yu, J., Feng, S., & Su, L. (2016). A rapid microwave synthesis of nitrogen-sulfur co-doped carbon nanodots as highly sensitive and selective fluorescence probes for ascorbic acid. Talanta, 153, 332–339. doi.org/10.1016/j.talanta.2016.03.035
Fan, W., Liu, X., Wang, Z., Fei, P., Zhang, R., Wang, Y., Qin, C., Zhao, W., & Ding, Y. (2018). Synergetic enhancement of the electronic/ionic conductivity of a Li-ion battery by fabrication of a carbon-coated nanoporous SnO: XSb alloy anode. Nanoscale, 10(16), 7605–7611. doi.org/10.1039/c8nr00550h
Gassoumi, A., & Kanzari, M. (2011). Growth and post-annealing effect on the properties of the new sulfosalt SnSb2S4 thin films. Physica E: Low-Dimensional Systems and Nanostructures, 44(1), 71–74. doi.org/10.1016/j.physe.2011.07.007

Gutwirth, J., Wágner, T., Němec, P., Kasap, S. O., & Frumar, M. (2008). Thermal and optical properties of AgSbS2 thin films prepared by pulsed laser deposition (PLD). Journal of Non-Crystalline Solids, 354(2–9), 497–502. doi.org/10.1016/j.jnoncrysol.2007.08.083
He, M., Kravchyk, K., Walter, M., & Kovalenko, M. v. (2014). Monodisperse antimony nanocrystals for high-rate li-ion and na-ion battery anodes: Nano versus bulk. Nano Letters, 14(3), 1255–1262. doi.org/10.1021/nl404165c
He, M., Walter, M., Kravchyk, K. v., Erni, R., Widmer, R., & Kovalenko, M. v. (2015). Monodisperse SnSb nanocrystals for Li-ion and Na-ion battery anodes: Synergy and dissonance between Sn and Sb. Nanoscale, 7(2), 455–459. doi.org/10.1039/c4nr05604c
https://www.chemguide.co.uk/analysis/ir/interpret.html. (2019).
Huang, Z., Chen, Z., Ding, S., Chen, C., & Zhang, M. (2018). Multi-protection from nanochannels and graphene of SnSb-graphene carbon composites ensuring high properties for potassium-ion batteries. Solid State Ionics, 324, 267–275. doi.org/10.1016/j.ssi.2018.07.019
Ismail, B., Mushtaq, S., Khan, R. A., Khan, A. M., Zeb, A., & Khan, A. R. (2014). Enhanced grain growth and improved optical properties of the Sn doped thin films of Sb2S3 orthorhombic phase. Optik, 125(21), 6418–6421. doi.org/10.1016/j.ijleo.2014.06.138
Jena, S., Mitra, A., Patra, A., Sengupta, S., Das, K., Majumder, S. B., & Das, S. (2018). Sandwich architecture of Sn–SnSb alloy nanoparticles and N-doped reduced graphene oxide sheets as a high rate capability anode for lithium-ion batteries. Journal of Power Sources, 401, 165–174. doi.org/10.1016/j.jpowsour.2018.08.058
Khel, L. K., Khan, S., & Zaman, M. I. ,. (2005). SnS thin films fabricated by normal electrochemical deposition on aluminium plate. J. Chem. Soc. Pak., 27(1), 24–28. Lakshmi, D., Nalini, B., Sivaraj, P., & Jayapandi, S. (2017). Electro analytical studies on indium incorporated SnSb alloy anode for Li-ion batteries. Journal of Electroanalytical Chemistry, 801, 459–465. doi.org/10.1016/j.jelechem.2017.08.010
Li, Y., Huang, L., Zhang, P., Ren, X., & Deng, L. (2015). Synthesis of Si-Sb-ZnO Composites as High-Performance Anodes for Lithium-ion Batteries. Nanoscale Research Letters, 10(1). doi.org/10.1186/s11671-015-1128-4
M. Armand, & J.-M. Tarascon. (2008). Building Better Batteries. Nature , 451, 652–657.
Manolache, S., Duta, A., Isac, L., Nanu, M., Goossens, A., & Schoonman, J. (2007). The influence of the precursor concentration on CuSbS2 thin films deposited from aqueous solutions. Thin Solid Films, 515(15 SPEC. ISS.), 5957–5960. doi.org/10.1016/j.tsf.2006.12.046
Mariappan, R., Mahalingam, T., & Ponnuswamy, V. (2011). Preparation and characterization of electrodeposited SnS thin films. Optik, 122(24), 2216–2219. doi.org/10.1016/j.ijleo.2011.01.015
Mellouki, I., Mami, A., Bennaji, N., & Fadhli, Y. (2018). Study of doping and annealing effects on thermal properties of SnxSb2Sy (1≤ x≤ 3, 4≤ y≤ 6) sulfosalts thin films by electro-pyroelectric technique. Thermochimica Acta, 670, 123–127. doi.org/10.1016/j.tca.2018.10.021
Nasrollahzadeh, M., Jaleh, B., & Jabbari, A. (2014). Synthesis, characterization and catalytic activity of graphene oxide/ZnO nanocomposites. RSC Advances, 4(69), 36713–36720. doi.org/10.1039/c4ra05833j
Nithyadharseni, P., Reddy, M. v., Nalini, B., & Chowdari, B. V. R. (2015). Electrochemical investigation of SnSb nano particles for lithium-ion batteries. Materials Letters, 150, 24–27. doi.org/10.1016/j.matlet.2015.02.124
Sudesh, Kumar, N., Das, S., Bernhard, C., & Varma, G. D. (2013). Effect of graphene oxide doping on superconducting properties of bulk MgB2. Superconductor Science and Technology, 26(9). doi.org/10.1088/0953-2048/26/9/095008
Tesfaye, A. T., Yücel, Y. D., Barr, M. K. S., Santinacci, L., Vacandio, F., Dumur, F., Maria, S., Monconduit, L., & Djenizian, T. (2017). The Electrochemical Behavior of SnSb as an Anode for Li-ion Batteries Studied by Electrochemical Impedance Spectroscopy and Electron Microscopy. Electrochimica Acta, 256, 155–161. doi.org/10.1016/j.electacta.2017.10.031
Tezel, N. S., Tezel, F. M., & Kariper, I. A. (2019a). Surface and electro-optical properties of amorphous Sb 2 S 3 thin films. Applied Physics A: Materials Science and Processing, 125(3). doi.org/10.1007/s00339-019-2475-2
Tezel, N. S., Tezel, F. M., & Kariper, I. A. (2019b). The impact of pH on the structural, surface, electrical and optical properties of nanostructured PbSe thin films. Materials Research Express, 6(7). doi.org/10.1088/2053-1591/ab1675
Wagner, T., Krbal, M., Nemec, P., Frumar, M., Wagner, T., Vlcek, M., Perina, V., Mackova, A., Hnatovitz, V., & Kasap, S. O. (2004). AgAsS2 amorphous chalcogenide films prepared by pulsed laser deposition. Applied Physics A: Materials Science and Processing, 79(4–6), 1563–1565. doi.org/10.1007/s00339-004-2848-y
Wang, H., Wu, Q., Cao, D., Lu, X., Wang, J., Leung, M. K. H., Cheng, S., Lu, L., & Niu, C. (2016). Synthesis of SnSb-embedded carbon-silica fibers via electrospinning: Effect of TEOS on structural evolutions and electrochemical properties. Materials Today Energy, 1–2, 24–32. doi.org/10.1016/j.mtener.2016.11.003
Wu, H., Yu, G., Pan, L., Liu, N., McDowell, M. T., Bao, Z., & Cui, Y. (2013). Stable Li-ion battery anodes by in-situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles. Nature Communications, 4. doi.org/10.1038/ncomms2941
Xia, X., Li, Z., Xue, L., Qiu, Y., Zhang, C., & Zhang, X. (2017). The electrochemical performance of SnSb/C nanofibers with different morphologies and underlying mechanism. Journal of Materials Research, 32(6), 1184–1193. doi.org/10.1557/jmr.2016.508
Xia, X., Li, Z., Zhou, H., Qiu, Y., & Zhang, C. (2016). The effect of deep cryogenic treatment on SnSb/C nanofibers anodes for Li-ion battery. Electrochimica Acta, 222, 765–772. doi.org/10.1016/j.electacta.2016.11.034
Yi, Z., Han, Q., Geng, D., Wu, Y., Cheng, Y., & Wang, L. (2017). One-pot chemical route for morphology-controllable fabrication of Sn-Sb micro/nano-structures: Advanced anode materials for lithium and sodium storage. Journal of Power Sources, 342, 861–871. doi.org/10.1016/j.jpowsour.2017.01.016
Zhang, G., Zhu, J., Zeng, W., Hou, S., Gong, F., Li, F., Li, C. C., & Duan, H. (2014). Tin quantum dots embedded in nitrogen-doped carbon nanofibers as excellent anode for lithium-ion batteries. Nano Energy, 9, 61–70. doi.org/10.1016/j.nanoen.2014.06.030
Zhang, L., Lu, L., Zhang, D., Hu, W., Wang, N., Li, Y., & Zeng, H. (2016). Dual-buffered SnSe@CNFs as negative electrode with outstanding lithium storage performance. http://www.elsevier.com/open-access/userlicense/1.0/
Zou, Y., & Wang, Y. (2011). Sn@CNT nanostructures rooted in graphene with high and fast Li-storage capacities. ACS Nano, 5(10), 8108–8114. doi.org/10.1021/nn2027159

Details

Primary Language

Turkish

Subjects

Electrical Engineering

Journal Section

Research Article

Authors

Necmi Serkan Tezel ^*
0000-0002-9452-677X
Türkiye

Afşin Kariper
0000-0001-9127-301X
Türkiye

Publication Date

July 31, 2022

Submission Date

January 24, 2022

Acceptance Date

July 29, 2022

Published in Issue

Year 2022 Volume: 14 Number: 2

DOI

https://doi.org/10.29137/umagd.1062439

IZ

https://izlik.org/JA29NA42ZR

APA

Tezel, N. S., & Kariper, A. (2022). rGO/SnSbS Nanokompozitlerin Farklı Depolama Sıcaklığına Bağlı Elektriksel, Yapısal ve Yüzeysel Değerlendirmesi. International Journal of Engineering Research and Development, 14(2), 907-916. https://doi.org/10.29137/umagd.1062439

AMA

1.Tezel NS, Kariper A. rGO/SnSbS Nanokompozitlerin Farklı Depolama Sıcaklığına Bağlı Elektriksel, Yapısal ve Yüzeysel Değerlendirmesi. IJERAD. 2022;14(2):907-916. doi:10.29137/umagd.1062439

Chicago

Tezel, Necmi Serkan, and Afşin Kariper. 2022. “RGO/SnSbS/Nanokompozitlerin/Farklı/Depolama/Sıcaklığına/Bağlı/Elektriksel,/Yapısal/Ve/Yüzeysel/Değerlendirmesi”. International Journal of Engineering Research and Development 14 (2): 907-16. https://doi.org/10.29137/umagd.1062439.

EndNote

Tezel NS, Kariper A (July 1, 2022) rGO/SnSbS Nanokompozitlerin Farklı Depolama Sıcaklığına Bağlı Elektriksel, Yapısal ve Yüzeysel Değerlendirmesi. International Journal of Engineering Research and Development 14 2 907–916.

IEEE

[1]N. S. Tezel and A. Kariper, “rGO/SnSbS Nanokompozitlerin Farklı Depolama Sıcaklığına Bağlı Elektriksel, Yapısal ve Yüzeysel Değerlendirmesi”, IJERAD, vol. 14, no. 2, pp. 907–916, July 2022, doi: 10.29137/umagd.1062439.

ISNAD

Tezel, Necmi Serkan - Kariper, Afşin. “RGO/SnSbS/Nanokompozitlerin/Farklı/Depolama/Sıcaklığına/Bağlı/Elektriksel,/Yapısal/Ve/Yüzeysel/Değerlendirmesi”. International Journal of Engineering Research and Development 14/2 (July 1, 2022): 907-916. https://doi.org/10.29137/umagd.1062439.

JAMA

1.Tezel NS, Kariper A. rGO/SnSbS Nanokompozitlerin Farklı Depolama Sıcaklığına Bağlı Elektriksel, Yapısal ve Yüzeysel Değerlendirmesi. IJERAD. 2022;14:907–916.

MLA

Tezel, Necmi Serkan, and Afşin Kariper. “RGO/SnSbS/Nanokompozitlerin/Farklı/Depolama/Sıcaklığına/Bağlı/Elektriksel,/Yapısal/Ve/Yüzeysel/Değerlendirmesi”. International Journal of Engineering Research and Development, vol. 14, no. 2, July 2022, pp. 907-16, doi:10.29137/umagd.1062439.

Vancouver

1.Necmi Serkan Tezel, Afşin Kariper. rGO/SnSbS Nanokompozitlerin Farklı Depolama Sıcaklığına Bağlı Elektriksel, Yapısal ve Yüzeysel Değerlendirmesi. IJERAD. 2022 Jul. 1;14(2):907-16. doi:10.29137/umagd.1062439

Kırıkkale University, Faculty of Engineering and Natural Science, 71450 Yahşihan / Kırıkkale, Türkiye.

ijerad@kku.edu.tr

Electrical, Structural, Surface Evaluation Depends on the Different Deposition Temperature of rGO/SnSbS Nanocomposite

Abstract

Keywords

Project Number

rGO/SnSbS Nanokompozitlerin Farklı Depolama Sıcaklığına Bağlı Elektriksel, Yapısal ve Yüzeysel Değerlendirmesi

Abstract

Keywords

Supporting Institution

Project Number

Thanks

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite