Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama

Semih Ağca

doi:10.29137/umagd.1368646

EN TR

New Studies on Chalcopyrite Thin Film Solar Cells: Silver Alloying

Abstract

In this study, after giving general information about chalcopyrite solar cells, different production methods, development methods applied to solar cell layers and the status of research conducted around the world are examined. It has been shown that chalcopyrite solar cells can compete with different types of solar cells with an efficiency of 26%. It has been determined that the traditional chalcopyrite structure has been replaced by silver alloyed chalcopyrite structure in recent years. Silver alloying research has shown that the silver alloyed chalcopyrite structure exhibits better grain growth at the same production temperatures compared to the traditional chalcopyrite structure. This has enabled the crystal quality to increase. Additionally, widening the bandgap by silver alloying has contributed to multilayer tandem solar cell studies. The biggest contribution of silver alloying to wide bandgap studies is the ability to control the distribution of gallium in the chalcopyrite structure. Moreover, better efficiency results were obtained because silver alloying reduced recombination and increased the open circuit voltage. It is also very important that transparent and flexible solar cells can be designed with this technology. It is predicted that the future of studies on chalcopyrite solar cells will be shaped by silver alloying. The fact that both flexible and transparent solar cells can be used in areas such as wearable solar cells, building applications and agrivoltaics that can be used in agricultural lands increases the importance of the subject.

Keywords

Silver alloying, Chalcopyrite, Thin film, Solar cell

Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama

Abstract

Bu çalışmada, kalkopirit güneş hücreleri ile ilgili genel bilgiler verildikten sonra farklı üretim yöntemleri, güneş hücresi tabakalarına uygulanan geliştirme yöntemleri ve dünya genelinde yapılan araştırmaların durumu incelenmiştir. Kalkopirit güneş hücrelerinin %26 verim ile farklı tipteki güneş hücreleri ile yarışabilir pozisyonda olduğu gösterilmiştir. Geleneksel kalkopirit yapının son yıllarda yerini gümüş alaşımlanmış kalkopirit yapıya bıraktığı tespit edilmiştir. Gümüş alaşımlama araştırmaları gümüş alaşımlanmış kalkopirit yapının geleneksel kalkopirit yapıya kıyasla aynı üretim sıcaklıklarında daha iyi tane büyümesi sergilediğini göstermiştir. Bu durum da kristal kalitesinin artmasını sağlamıştır. Ayrıca, gümüş alaşımlama ile yasak bant aralığının genişletilebilmesi çok katlı tandem güneş hücresi çalışmalarına katkıda bulunmuştur. Geniş yasak bant aralığı çalışmalarına yapmış olduğu en büyük katkı kalkopirit yapıdaki galyumun dağılımının kontrol edilebilmesini sağlamasıdır. Bununla birlikte, gümüş alaşımlama rekombinasyonu azaltıp açık devre voltajını artırdığı için daha iyi verim sonuçları alınmıştır. Bu teknoloji ile şeffaf ve esnek güneş hücresi tasarlanabiliyor olması da çok önemlidir. Kalkopirit güneş hücreleri ile ilgili çalışmaların geleceğinin gümüş alaşımlama ile şekilleneceği öngörülmektedir. Hem esnek hem de şeffaf güneş hücrelerinin giyilebilir güneş hücresi, bina uygulamaları ve tarım arazilerinde kullanılabilen agrivoltaik gibi alanlarda kullanılabileceği gerçeği konunun önemini artırmaktadır.

Keywords

Gümüş alaşımlama, Kalkopirit, İnce film, Güneş hücresi

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Yang, S-C., Sastre, J., Krause, M., Sun, X., Hertwig, R., Ochoa, M., Tiwari, A. N., & Carron, R. (2021). Silver-promoted high-performance (Ag,Cu)(In,Ga)Se2 thin-film solar cells grown at very low temperature. Solar RRL, 5(5), 2100108. doi:10.1002/solr.202100108
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Details

Primary Language

Turkish

Subjects

Compound Semiconductors, Electronic, Optics and Magnetic Materials

Journal Section

Review

Authors

Semih Ağca ^*
0000-0002-4834-5337
Türkiye

Publication Date

January 31, 2024

Submission Date

September 29, 2023

Acceptance Date

November 24, 2023

Published in Issue

Year 2024 Volume: 16 Number: 1

DOI

https://doi.org/10.29137/umagd.1368646

IZ

https://izlik.org/JA53WT77SW

APA

Ağca, S. (2024). Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama. International Journal of Engineering Research and Development, 16(1), 106-116. https://doi.org/10.29137/umagd.1368646

AMA

1.Ağca S. Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama. IJERAD. 2024;16(1):106-116. doi:10.29137/umagd.1368646

Chicago

Ağca, Semih. 2024. “Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama”. International Journal of Engineering Research and Development 16 (1): 106-16. https://doi.org/10.29137/umagd.1368646.

EndNote

Ağca S (January 1, 2024) Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama. International Journal of Engineering Research and Development 16 1 106–116.

IEEE

[1]S. Ağca, “Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama”, IJERAD, vol. 16, no. 1, pp. 106–116, Jan. 2024, doi: 10.29137/umagd.1368646.

ISNAD

Ağca, Semih. “Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama”. International Journal of Engineering Research and Development 16/1 (January 1, 2024): 106-116. https://doi.org/10.29137/umagd.1368646.

JAMA

1.Ağca S. Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama. IJERAD. 2024;16:106–116.

MLA

Ağca, Semih. “Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama”. International Journal of Engineering Research and Development, vol. 16, no. 1, Jan. 2024, pp. 106-1, doi:10.29137/umagd.1368646.

Vancouver

1.Semih Ağca. Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama. IJERAD. 2024 Jan. 1;16(1):106-1. doi:10.29137/umagd.1368646

Kırıkkale University, Faculty of Engineering and Natural Science, 71450 Yahşihan / Kırıkkale, Türkiye.

ijerad@kku.edu.tr

New Studies on Chalcopyrite Thin Film Solar Cells: Silver Alloying

Abstract

Keywords

Kalkopirit İnce Film Güneş Hücrelerinde Yeni Çalışmalar: Gümüş Alaşımlama

Abstract

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