Research Article

Usage of antimony trioxide, aluminum hydroxide and zinc borate in GRP composite production as fire-retardant additives: An experimental research

Volume: 13 Number: 1 January 18, 2021
EN

Usage of antimony trioxide, aluminum hydroxide and zinc borate in GRP composite production as fire-retardant additives: An experimental research

Abstract

In this study, it was aimed to investigate the usability of compounds in inorganic structure and the effect of these compounds used in composites on the mechanical properties of composites in order to give fire retardant properties to glass fiber reinforced polyester composites (CTP). Antimony trioxide (Sb2O3), aluminum hydroxide (Al(OH)3) and zinc borate (2ZnO3.BrO3.3H2O) were added by different proportions (5%, 10%, 15%, 20%, 25%, 30%) to resin blends to improve the non-flammability of the composites. In experimental study, the combustion behavior of the doped CTP composites produced using different inorganic compounds was determined by international combustion standards ASTM D-635, ASTM D-3801 and ASTM D-5048. In addition, thermogravimetric analysis (TGA) was applied in order to determine the thermal behavior of the produced GRP composites due to temperature increase and tensile test were applied according to ASTM 638-14.As a result, when the flame retardant additive ratio is 15% or more in the GRP composites, the hand lay production became difficult due to the increase in viscosity. According to ASTM D-3801, when 30% AH is used, non-combustible material in V1 class can be produced. All FRP composites containing flame retardants were included in the HB - slowly burning material class. Flame retardant use generally reduced the tensile strength of GRP composites, but it was found that 10% increase in AT-doped CTPs.

Keywords

Glass fiber, Fire retardant composites, Non-flammability, Tensile test

Project Number

2017-0705527

References

  1. Bar, M., Alagirusamy, R., Das, A. (2015). Flame retardant polymer composites. Fibers and Polymers. 16, 705-717.
  2. Bulut , Y., Erdoğan Ü. H. (2011). Usability of cellulose based natural fibers as reinforcement materials in composite manufacturing. Journal of Textiles and Engineer. 82, 26–35.
  3. Camino, G., Costa, L., Cortemiglia, L. (1991). Polymer degradation and stability. Journals & Books. 33(2), 131-154. doi:10.1016/0141-3910(91)90014-I
  4. Carpentier, F., Bourbigot, S., Le Bras., M. (2000). Charring of fire retarded ethylene vinyl acetate copolymer magnesium hydroxide/zinc borate formulations. Polymer Degradation and Stability. 69 (1), 83–92. doi:10.1016/S0141-3910(00)00044-6
  5. Cullis, C.F., Hirschler., M.M. (1981). The combustion of organic polymers. Clarendon Press, Oxford. Dittenber, B.D., Gangaroa, V.S.H. (2006). Composites part a: Applied science and manufacturing. Journals & Books 43 (8), 1419-1429. doi:10.1016/j.compositesa.2011.11.019
  6. Guan, F.L., Gui, C.X., Zhang, H.B. (2016). Enhanced thermal conductivity and satisfactory flame retardancy of epoxy/aluminacomposites by combination with graphene nanoplatelets and magnesium hydroxide. Compos Part B: Eng. 98 (1),134–140.doi:10.1016/j.compositesb.2016.04.062
  7. Hong, C.H., Lee, YB. (2005). Tensile properties and stress whiting of polypropylene/polyolefin elastomer/magnesium hydroxide flameretardant composites for cable insulating application. Journal of Applied Polymer Science 97 (6), 2311–2318. doi:10.1002/app.21776
  8. Hornsby, P.R. (1994). The application of magnesium hydroxide as fire retardant and smoke-suppressing additive for polymers. Fire and Materials. 18, 269–276. doi:10.1002/fam.810180502
  9. Kaya, A.İ. (2016). Composite Materials and Their Properties.Putech & Composites Magazine.
  10. Maira, B., Chammingkwan, P., Terano, M. (2015). New reactor granule technology for highly filled nanocomposites: effective flameretardation of polypropylene/magnesium hydroxide nanocomposites. Macromolecular Materials and Engineering. 300 (7),679–683.doi:10.1002/mame.201500012
APA
Beycioğlu, A., Doğan, E., Çetin, S., Gökçe, N., & Aruntaş, H. Y. (2021). Usage of antimony trioxide, aluminum hydroxide and zinc borate in GRP composite production as fire-retardant additives: An experimental research. International Journal of Engineering Research and Development, 13(1), 265-277. https://doi.org/10.29137/umagd.821003
AMA
1.Beycioğlu A, Doğan E, Çetin S, Gökçe N, Aruntaş HY. Usage of antimony trioxide, aluminum hydroxide and zinc borate in GRP composite production as fire-retardant additives: An experimental research. IJERAD. 2021;13(1):265-277. doi:10.29137/umagd.821003
Chicago
Beycioğlu, Ahmet, Eda Doğan, Suna Çetin, Neslihan Gökçe, and Hüseyin Yılmaz Aruntaş. 2021. “Usage of Antimony Trioxide, Aluminum Hydroxide and Zinc Borate in GRP Composite Production As Fire-Retardant Additives: An Experimental Research”. International Journal of Engineering Research and Development 13 (1): 265-77. https://doi.org/10.29137/umagd.821003.
EndNote
Beycioğlu A, Doğan E, Çetin S, Gökçe N, Aruntaş HY (January 1, 2021) Usage of antimony trioxide, aluminum hydroxide and zinc borate in GRP composite production as fire-retardant additives: An experimental research. International Journal of Engineering Research and Development 13 1 265–277.
IEEE
[1]A. Beycioğlu, E. Doğan, S. Çetin, N. Gökçe, and H. Y. Aruntaş, “Usage of antimony trioxide, aluminum hydroxide and zinc borate in GRP composite production as fire-retardant additives: An experimental research”, IJERAD, vol. 13, no. 1, pp. 265–277, Jan. 2021, doi: 10.29137/umagd.821003.
ISNAD
Beycioğlu, Ahmet - Doğan, Eda - Çetin, Suna - Gökçe, Neslihan - Aruntaş, Hüseyin Yılmaz. “Usage of Antimony Trioxide, Aluminum Hydroxide and Zinc Borate in GRP Composite Production As Fire-Retardant Additives: An Experimental Research”. International Journal of Engineering Research and Development 13/1 (January 1, 2021): 265-277. https://doi.org/10.29137/umagd.821003.
JAMA
1.Beycioğlu A, Doğan E, Çetin S, Gökçe N, Aruntaş HY. Usage of antimony trioxide, aluminum hydroxide and zinc borate in GRP composite production as fire-retardant additives: An experimental research. IJERAD. 2021;13:265–277.
MLA
Beycioğlu, Ahmet, et al. “Usage of Antimony Trioxide, Aluminum Hydroxide and Zinc Borate in GRP Composite Production As Fire-Retardant Additives: An Experimental Research”. International Journal of Engineering Research and Development, vol. 13, no. 1, Jan. 2021, pp. 265-77, doi:10.29137/umagd.821003.
Vancouver
1.Ahmet Beycioğlu, Eda Doğan, Suna Çetin, Neslihan Gökçe, Hüseyin Yılmaz Aruntaş. Usage of antimony trioxide, aluminum hydroxide and zinc borate in GRP composite production as fire-retardant additives: An experimental research. IJERAD. 2021 Jan. 1;13(1):265-77. doi:10.29137/umagd.821003