Research Article

Correlation Between Surface, Thermal, Mechanical and Morphological Properties of Polylactic Acid/Polypropylene and Polylactic Acid/Polyamide 6 Blends

Volume: 14 Number: 1 January 31, 2022
EN

Correlation Between Surface, Thermal, Mechanical and Morphological Properties of Polylactic Acid/Polypropylene and Polylactic Acid/Polyamide 6 Blends

Abstract

In the automotive sector, which is one of the sectors where polymers are mostly used, their behaviour and compatibility in secondary processes such as painting and coating applications are important in the preference of polymers according to their usage areas as well as mechanical and thermal properties. In this context, it is known that surface wettability of a polymer material is of great importance for different application areas and it can be stated that wetting and non-wetting behaviours play an important role in the selection of polymers and their industrial applications. In this study, the contact angle properties of polypropylene (PP) and polyamide 6 (PA6), which are the most used polymers in the automotive sector and their polymer blends prepared by using polylactic acid (PLA) were examined. When PLA/PP and PLA/PA6 mixtures were compared, it was observed that there were significant differences in contact angle measurements and these properties detected in water contact angle measurements were attributed to changes in chemical structures, functional groups and morphology of related polymers. Surface analysis were supported by thermal, mechanical and morphological analysis and differences in static contact angle measurement results were explained.

Keywords

Bio-based polymer blends, Wettability, Thermal properties, Mechanical properties, Morphological properties

Supporting Institution

Scientific Research Projects Unit of Bursa Technical University

Project Number

190D001

Thanks

The authors gratefully acknowledge the Scientific Research Projects Unit of Bursa Technical University (under the contract number of 190D001) and Bursa Technical University Central Research Laboratory for providing facilities for this research.

References

  1. Auras, R. A., Harte, B., Selke, S., & Hernandez, R. (2003). Mechanical, physical, and barrier properties of poly (lactide) films. Journal of Plastic Film & Sheeting, 19(2), 123-135. doi:10.1177/8756087903039702
  2. Bhasney, S. M., Kumar, A., & Katiyar, V. (2020). Microcrystalline cellulose, polylactic acid and polypropylene biocomposites and its morphological, mechanical, thermal and rheological properties. Composites Part B: Engineering, 184, 107717. doi:10.1016/j.compositesb.2019.107717
  3. Di, Y., Iannace, S., Di Maio, E., & Nicolais, L. (2005). Reactively modified poly (lactic acid): properties and foam processing,” Macromolecular Materials and Engineering., 290(11), 1083-1090. doi:10.1002/mame.200500115
  4. Ebadi-Dehaghani, H., Khonakdar, H. A., Barikani, M., & Jafari, S. H. (2015). Experimental and theoretical analyses of mechanical properties of PP/PLA/clay nanocomposites. Composites Part B: Engineering, 69, 133-144. doi:10.1016/j.compositesb.2014.09.006
  5. Feng, F., & Ye, L. (2010). Structure and property of polylactide/polyamide blends. Journal of Macromolecular Science, Part B Physics, 49(6), 1117-1127. doi:10.1080/00222341003609179
  6. Grundke, K., Pöschel, K., Synytska, A., Frenzel, R., Drechsler, A., Nitschke, M., Cordeiro, A. L., Uhlmann, P., & Welzel, P. B. (2015). Experimental studies of contact angle hysteresis phenomena on polymer surfaces-Toward the understanding and control of wettability for different applications. Advances in Colloid and Interface Science, 222, 350-376. doi:10.1016/j.cis.2014.10.012
  7. Hamad, K., Kaseem, M., Ayyoob, M., Joo, J., & Deri, F. (2018). Polylactic acid blends: The future of green, light and tough. Progress in Polymer Science, 85, 83-127. doi:10.1016/j.progpolymsci.2018.07.001
  8. He, Y., Xu, Y., Wei, J., Fan, Z., & Li, S. (2008). Unique crystallization behavior of poly (L-lactide)/poly (D-lactide) stereocomplex depending on initial melt states. Polymer, 49(26), 5670-5675. doi:10.1016/j.polymer.2008.10.028
  9. Karimpour-Motlagh, N., Khonakdar, H. A., Jafari, S. M. A., Mahjub, A., Panahi-Sarmad, M., Kasbi, S. F., Shojaei, S., Goodarzi, V., & Arjmand, M. (2020). Influence of polypropylene and nanoclay on thermal and thermo-oxidative degradation of poly (lactide acid): TG-FTIR, TG-DSC studies and kinetic analysis. Thermochimica Acta, 691, 178709. doi:10.1016/j.tca.2020.178709
  10. Kawashima, N., Ogawa, S., Obuchi, S., Matsuo, M., & Yagi, T. (2005). Polylactic acid ‘LACEA’. Biopolymer Online, 4. doi:10.1002/3527600035.bpol4009
APA
Tuna, S., & Akkoyun, M. (2022). Correlation Between Surface, Thermal, Mechanical and Morphological Properties of Polylactic Acid/Polypropylene and Polylactic Acid/Polyamide 6 Blends. International Journal of Engineering Research and Development, 14(1), 84-94. https://doi.org/10.29137/umagd.950070
AMA
1.Tuna S, Akkoyun M. Correlation Between Surface, Thermal, Mechanical and Morphological Properties of Polylactic Acid/Polypropylene and Polylactic Acid/Polyamide 6 Blends. IJERAD. 2022;14(1):84-94. doi:10.29137/umagd.950070
Chicago
Tuna, Sibel, and Meral Akkoyun. 2022. “Correlation Between Surface, Thermal, Mechanical and Morphological Properties of Polylactic Acid Polypropylene and Polylactic Acid Polyamide 6 Blends”. International Journal of Engineering Research and Development 14 (1): 84-94. https://doi.org/10.29137/umagd.950070.
EndNote
Tuna S, Akkoyun M (January 1, 2022) Correlation Between Surface, Thermal, Mechanical and Morphological Properties of Polylactic Acid/Polypropylene and Polylactic Acid/Polyamide 6 Blends. International Journal of Engineering Research and Development 14 1 84–94.
IEEE
[1]S. Tuna and M. Akkoyun, “Correlation Between Surface, Thermal, Mechanical and Morphological Properties of Polylactic Acid/Polypropylene and Polylactic Acid/Polyamide 6 Blends”, IJERAD, vol. 14, no. 1, pp. 84–94, Jan. 2022, doi: 10.29137/umagd.950070.
ISNAD
Tuna, Sibel - Akkoyun, Meral. “Correlation Between Surface, Thermal, Mechanical and Morphological Properties of Polylactic Acid Polypropylene and Polylactic Acid Polyamide 6 Blends”. International Journal of Engineering Research and Development 14/1 (January 1, 2022): 84-94. https://doi.org/10.29137/umagd.950070.
JAMA
1.Tuna S, Akkoyun M. Correlation Between Surface, Thermal, Mechanical and Morphological Properties of Polylactic Acid/Polypropylene and Polylactic Acid/Polyamide 6 Blends. IJERAD. 2022;14:84–94.
MLA
Tuna, Sibel, and Meral Akkoyun. “Correlation Between Surface, Thermal, Mechanical and Morphological Properties of Polylactic Acid Polypropylene and Polylactic Acid Polyamide 6 Blends”. International Journal of Engineering Research and Development, vol. 14, no. 1, Jan. 2022, pp. 84-94, doi:10.29137/umagd.950070.
Vancouver
1.Sibel Tuna, Meral Akkoyun. Correlation Between Surface, Thermal, Mechanical and Morphological Properties of Polylactic Acid/Polypropylene and Polylactic Acid/Polyamide 6 Blends. IJERAD. 2022 Jan. 1;14(1):84-9. doi:10.29137/umagd.950070