Preparation of Silver Nanoparticle/Activated Carbon-Reinforced Fabric Composite

Yıl 2021, Cilt: 13 Sayı: 2, 645 - 652, 18.06.2021

Şule Ocak Araz Hüseyin Kaya

https://doi.org/10.29137/umagd.911364

Öz

Activated carbon is a materials with high capacity to adsorp organic and inorganic substances in liquid and gaseous phases thanks to its high surface area and pores. In the defense industry, activated carbon is used as protective clothing, in the production of explosives in the weapon industry and in the production of bombs to silence electronic systems, in the distillation and purification of gases and liquids and health sectors. In this study, it was aimed to expand the usage areas of active carbon (AC) by determining different methods and parametres of active carbon doped fabric with having antimicrobial properties of silver nanoparticles (AgNP) reinforcement.

AgNP’s formed colloidal in aqueous solution were obtained by chemical reduction of Silver Nitrate (AgNO3) with Sodium Borohydride (NaBH4). Structure and properties of synthesized AgNP’s were illuminated by UV-VIS spectrophotometer and Zeta Potential methods. Then, AC doped fabric with the obtained the AgNP’s were covered by using different methods such as ultrasonic bath, magnetic stirrer and soaking in solution and effective coating method was specified. Structure analysis of AgNP/AC composite and the amount of AgNP’s adsorbed to the surface were determined with Scanning Electron Microscope (SEM), and ICP-OES respectively. According to the obtained data, it was concluded that the AC fabric is covered with AgNP’s are the most approprite method by holding the AC fabric in the ultrasonic bath for 1 hour.

Anahtar Kelimeler

Silver Nanoparticle, Activated Carbon, Adsorption

Aktif Karbon Katkılı Kumaş/Gümüş Nanopartikül Kompozitin Hazırlanması

Öz

Aktif karbon (AC), yüksek yüzey alanı ve gözenekleri sayesinde sıvı ve gaz fazdaki organik ve inorganik maddeleri adsorplama kapasitesi yüksek bir malzemedir. Aktif karbon, savunma sanayinde koruyucu giysi yapımında, silah sanayisinde patlayıcı yapımında ve elektronik sistemleri susturmak için bomba yapımında, gazların ve sıvıların saflaştırılması, arıtılmasında ve sağlık sektörü gibi birçok alanda aktif karbon kullanılır. Bu çalışmada, aktif karbon katkılı kumaşa antimikrobiyal özelliğe sahip Gümüş nanopartiküllerin (AgNP) takviye edilmesi farklı yöntem ve parametrelerinin belirlenerek AC kullanım alanlarının daha da genişletilmesi amaçlanmıştır.

Sulu çözeltide kalloidal olarak oluşan AgNP, Gümüş Nitrat’ın (AgNO3) Sodyum Bor hidrür (NaBH4) ile kimyasal olarak indirgenmesiyle elde edildi. Sentezlenen AgNP’lerin yapı ve özellikleri UV-VIS spektrofotometresi ve Zeta Potansiyel yöntemleri ile aydınlatıldı. Daha sonra elde edilen AgNP ile Aktif Karbon (AC) katkılı kumaş ultrasonik banyo, manyetik karıştırıcı ve çözelti içinde bekletme gibi farklı yöntemler kullanılarak kumaş üzerine adsorpsiyon yöntemi ile takviye edilmesinde etkin yöntem belirlendi. AgNP/AC katkılı kumaş numunelerinin yüzey yapı analizi Taramalı Elektron Mikroskobu (SEM) ile, yüzeye adsorplanmış gümüş nanopartiküllerin miktarı ise ICP-OES ile belirlendi. Elde edilen verilere göre AC’li kumaşın ultrasonik banyo içerisinde 1 saat bekletilmesiyle AgNP adsorplanması en uygun yöntem olduğu belirlendi.

Anahtar Kelimeler

Gümüş nanopartikül, Aktif Karbon, Adsorplama

Kaynakça

• Abbas, F. S. (2017). Dyes removal from wastewater using agricultural waste. Adv. Environ. Biol. 7 (6), 1019–1026, 2013.
• Aksoy S., A., Çakar A., Korkmaz N. (2015). Korona Plazma ile Aktive Edilmiş Pamuklu Kumaşa Gümüş ve Çinko Oksit Nanopartikül Aplikasyonu, Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 19 (2), 78-85.
• Ali, H.H, Abdel-Satar, Amaal M. (2017). Removal of some heavy metals from aqueous solutions using natural wastes orange peel activated carbon. J. Appl. Sci. 3 (3), 13–30.
• Ali A., Saeed K., Mabood F. (2016). Removal of chromium (VI) from aqueous medium using chemically modified banana peels as efficient low-cost adsorbent. Alexandria Eng. J. 55 (3), 2933–2942.
• Amin N. K. (2008). Removal of reactive dye from aqueous solutions by adsorption onto activated carbons prepared from sugar- cane bagasse pith, Desalination 223, 152–161.
• Antony J. J., Nivedheetha M., Siva D., Pradeepha G., Kokilavani P., Kalaiselvi S., Sankarganesh A., Balasundaram A., Masilamani V., Achiraman S. (2013). Antimicrobial Activity of Leucas Aspera Engineered Silver Nanoparticles Against Aeromonas Hydrophila in İnfected Catla Catla. Colloids and Surfaces B: Biointerfaces, 109: 20-24.
• Bakar N. A., Othman N., Yunus Z. M., Altowayti W. A. H., Tahir M., Fitriani N., Mohd-Salleh S. N. A. (2021). An insight review of lignocellulosic materials as activated carbon precursor for textile wastewater treatment, Environmental Technology & Innovation 22, 101445.
• Bakirdere, S., Aydin, F., Bakirdere, E. G., Titretir, S. (2011). Akdeniz, İ., Aydin, I., Yildirim, E., Arslan, Y., From mg/kg to pg/kg levels: a story of trace element determination: a review. Applied Spectroscopy Reviews, 46: 38–66.
• Baytar., O. (2015). İğde Çekirdeği ve Kayın Ağacından Üretilen Aktif Karbonun Ağır Metal Ve Boyarmadde Gideriminde Kullanılması., Doktora Tezi., Selçuk Üniversitesi Fen Bilimleri Enstitüsü., Konya.
• Çakar A., Aksoy s. A., Korkmaz N. (2015). Korona Plazma ile Aktive Edilmiş Pamuklu Kumaşa Gümüş ve Çinko Oksit Nano Partikül Aplikasyonu, Suleyman Demirel University Journal of Natural and Applied Science, 19(2), 78-85.
• Çanayaz Y. (2016), Farklı İyonik Çevrelerde Membranların Yüzey İletkenliğinin Zeta Potansiyeli Üzerine Ektileri, Yüksek Lisans, Cumhuriyet Üniversitesi Fen Bilimleri Enstitüsü, Sivas.
• Çiftçi H. (2013). Aktif Karbonla Topraktan Tuz Adsorpsiyonu Yolu İle Tuzlanmış Tarım Arazilerinin Islah Edilebileceğinin Araştırılması, Yüksek Lisans, Harran Üniversitesi Fen Bilimleri Enstitüsü Şanlıurfa.
• Dilbilmez S. G. (2019). KBRN (Kimyasal, Biyolojik, Radyasyon, Nükleer) Tehditlere Karşı Koruyucu Malzemelerin Geliştirilmesi, Yüksek Lisans, Muğla Sıtkı Koçman Üniversitesi, Fen Bilimleri Enstitüsü, Muğla.
• El-Aassar A. H. M., Said M. M., Abdel-Gawad A. M., Shawky H. A. (2013). Using Silver Nanoparticles Coated on Activated Carbon Granules in Columns for Microbiological Pollutants Water Disinfection in Abu Rawash area, Great Cairo, Egypt, Australian Journal of Basic and Applied Sciences, 7(1): 422-432.
• Erkut, E. (2008). Aktif Karbon Adsorpsiyonu ile Boyarmadde Giderimi, Yüksek Lisans Tezi, Anadolu Üniversitesi, Fen Bilimleri Enstitüsü, Eskişehir, Türkiye, 39-71.
• Gerber C, Lang HP. (2006). How the doors to the nano-world were opened. Nature Nanotechnology, 1 (1): 3.
• Gupta, Vinod K., Jain, C.K., Ali, Imran, Chandra, S., Agarwal, S. (2002). Removal of lindane and malathion from wastewater using bagasse fly ash - A sugar industry waste. Water Res. 36 (10), 2483–2490.
• Hameed B.H., Din A.T.M., Ahmad A.L. (2007). Adsorption of meth- ylene blue onto bamboo-based activated carbon: Kinetics and equilibrium studies, J. Hazard. Mater. 141, 819–825.
• Karnib M., Holail H., Olama Z., Kabbani A., Hines M. (2013).The Antibacterial Activity of Activated Carbon, Silver, Silver Impregnated Activated Carbon and Silica Sand Nanoparticles against Pathogenic E. coli BL21, Int.J.Curr.Microbiol.App.Sci., 2(4): 20-30.
• Kim K. D., Han D. N. and Kim H. T. (2004). Chem. Engin. J., 104, 55.
• Küçükgül E. Y. (2004). Productıon Of The Commerıcal Actıvated Carbon And Determınatıon Of The Propertıes, Deü Mühendislik Fakültesi Fen Ve Mühendislik Dergisi, 6 (3), 41-56.
• Lee., B., S., Song., K., C., Lee.,S., M., Park., S., T. (2009). Preparation of colloidal silver nanoparticles by chemical reduction method, Korean J. Chem. Eng., 26 (1), 153-155.
• Lee J., Jeong S. (2005). Bacteriostasis and Skin Innoxiousness of Nanosize Silver Colloids on Textile Fabrics. Textile Research Journal, 75, 551-556.
• Lim S., H., Hudson, S., M. (2004). Application of a Fiber- Reactive Chitosan Derivative to Cotton Fabric as an Antimicrobial Textile Finish. Carbohydrate Polymers, 56, 227-234.
• Liu J., Lee J. B., Kim D. H., Kim Y. (2007). Colloids Surf. A, 302, 276.
• Ma B., Chaudhary J. P., Zhu J., Sun B., Chen C., Sun D. (2021). Construction of silver nanoparticles anchored in carbonized bacterial cellulose with enhanced antibacterial properties, Colloids and Surfaces A: Physicochemical and Engineering Aspects 611, 125845.
• Masoud, Mamdouh S., El-Saraf, Wagdi M., Abdel-Halim, Ahmed M., Ali, Alaa E., Mohamed, Essam A., Hasan, Hamad M.I. (2012). Rice husk and activated carbon for waste water treatment of El-Mex Bay, Alexandria Coast, Egypt. Arab. J. Chem. 1–8.
• Morgan I., Fink C. E. (1989). “Activated Carbon Production”, Chem. Ind. Eng. 2, 219 Norit (1983): “Activated Carbon” Main Grades of Norit Activated Carbon and their Applications, Amersfoort, The Netherlands.
• Omri A., Mourad Benzina M. (2012). Adsorption characteristics of silver ions onto activated carbon prepared from almond Shell, Desalination and Water Treatment, 5(10-12), 2317-2326.
• Prakash Kumar B.G., Shivakamy K., Miranda L. R., Velan M. (2006). Preparation of steam activated carbon from rubber- wood sawdust (Hevea brasiliensis) and its adsorption kinetics, J. Hazard. Mater. B136, 922–929.
• Radhika M., Palanivelu K. (2006). Adsorptive removal of chlorophe- nols from aqueous solution by low cost adsorbent-kinetics and isotherm analysis, J. Hazard. Mater. B138 116–124.
• Rajendran R., Balakumar C., Mohammed A. H. A., Jayakumar S., Vaideki K., Rajesh E., M. (2010). Use of Zinc Oxide Nano Particles For Production of Antimicrobial Textiles. International Journal of Engineering Science and Technology, 2(1), 202-208.
• Razi, Mohd Adib Mohammad, Al-Gheethi, Adel, Izzatul Ashikin, Z.A. (2018). Removal of heavy metals from textile wastewater using sugarcane bagasse activated carbon. Int. J. Eng. Technol. 7 (4.30), 112–115.
• Selvam S., Sundrarajan M. (2012). Functionalization of Cotton Fabric with PVP/ZnO Nanoparticles for Improved Reactive Dyeability and Antibacterial Activity. Carbohydrate Polymers, 87,1419-1424.
• Šıleıkaıtė A., Puıšo J, Prosyčevas I., Tamulevıčıus S. (2009). Investigation Of Silver Nanoparticles Formation Kinetics During Reduction Of Silver Nitrate With Sodium Citrate, Materıals Scıence (Medžıagotyra). Vol. 15, No. 1.
• Yahya, M.A., Al-Qodah, Z., Ngah, C.Z. (2015). Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: A review. Renew. Sustain. Energy Rev. 46, 218–235.
• Zahran M.K., Ahmed H.B.; El-Rafie M. H. (2014). Carbohydrate Polymers, 108, 145-152.
• Wang S.L., Tzou Y.M., Lu Y.H., Sheng G. (2007). Removal of 3-chlo- rophenol from water using rice-straw-based carbon, J. Haz- ard. Mater. 147 313–318.