Research Article
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Year 2024, Volume: 52 Issue: 1, 41 - 54, 04.01.2024
https://doi.org/10.15671/hjbc.1359536

Abstract

Project Number

2013/6-4YLS

References

  • C.H. Walker, R.M. Sibly, S.P. Hopkin, D. B. Peakall, Principles of Ecotoxicology; Group, T. And F., Ed.; 4th Edition, CRC Press, 2012.
  • D. Türkmen, M. Bakhshpour, S. Akgönüllü, S. Aşır, & A. Denizli, Heavy metal ions removal from wastewater using cryogels: A review. Frontiers in Sustainability. 3 (2022) 765592.
  • H. Wu, G. Lin, C. Liu, S. Chu, C. Mo, & X. Liu, Progress and challenges in molecularly imprinted polymers for adsorption of heavy metal ions from wastewater. Trends in Environmental Analytical Chemistry. 36 (2022) e00178.
  • S. Nam, & P.G. Tratnyek, Reduction of azo dyes with zero-valent iron. Water Research. 34 (2000) 1837-1845.
  • A.R. Bagheri, N. Aramesh, A.A. Khan, I. Gul, S. Ghotekar, & M. Bilal, Molecularly imprinted polymers-based adsorption and photocatalytic approaches for mitigation of environmentally-hazardous pollutants─ A review. Journal of Environmental Chemical Engineering. 9 (2021) 104879.
  • L. Duan, Y. Zhang, M. He, R. Deng, H. Yi, Q. Wei, & A. Uddin, Burn-in degradation mechanism identified for small molecular acceptor-based high-efficiency nonfullerene organic solar cells. ACS applied materials & interfaces. 12 (2020) 27433-27442.
  • Y. Gao, N. Yan, C. Jiang, C. Xu, S. Yu, P. Liang, & X. Huang, Filtration-enhanced highly efficient photocatalytic degradation with a novel electrospun rGO@ TiO2 nanofibrous membrane: Implication for improving photocatalytic efficiency. Applied Catalysis B: Environmental. 268 (2020) 118737.
  • F. Fu, Q. Wang, Removal of heavy metal ions from wastewaters: A review. Journal of Environmental Management. 92 (2011) 407-418.
  • P. Häyrynen, J. Landaburu-Aguirre, E. Pongrácz, R.L. Keiski, Study of permeate flux in micellar-enhanced ultrafiltration on a semi-pilot scale: Simultaneous removal of heavy metals from phosphorous rich real wastewaters. Separation and Purification Technology. 93 (2012) 59-66.
  • M. Adrees, S. Ali, M. Rizwan, M. Zia-Ur-Rehman, M. Ibrahim, F. Abbas, M. Farid, M. F. Qayyum, M. K. Irshad, Mechanisms of silicon-mediated alleviation of heavy metal toxicity in plants: A review. Ecotoxicology and Environmental Safety, 119 (2015) 186-197.
  • M. Singh, J. Kumar, S. Singh, V.P. Singh, S.M. Prasad, M. Singh, Adaptation strategies of plants against heavy metal toxicity: A short review. Biochemistry and Pharmacology (Los Angeles). 4 (2015) 501-2167.
  • C. K. Yap, M. Saleem, W. S. Tan, W. M. Syazwan, N. Azrizal-Wahid, R. Nulit, L. S. Wong, Ecological–Health Risk Assessments of Copper in the Sediments: A Review and Synthesis. Pollutants, 2 (2022) 269-288.
  • R. N. Khalef, A. I. Hassan, H. M. Saleh, (2022) Metal’s Environmental Impact. In: Environmental Impact and Remediation of Heavy Metals. IntechOpen.
  • Panel on Micronutrients, & Nutrition Board. (2002). Dietary Reference Intakes for vitamin A, vitamin K, arsenic, boron, chromium, copper, iodine, iron, manganese, molybdenum, nickel, silicon, vanadium, and zinc. Dietary Reference Intakes.
  • L.M. Gaetke, & C.K. Chow, Copper toxicity, oxidative stress, and antioxidant nutrients. Toxicology. 189 (2003) 147-163.
  • C.F. Carolin, P.S. Kumar, A. Saravanan, G.J. Joshiba, & M. Naushad, Efficient techniques for the removal of toxic heavy metals from aquatic environment: A review. Journal of environmental chemical engineering. 5 (2017) 2782-2799.
  • R. Chakraborty, A. Asthana, A.K. Singh, B. Jain, & A.B.H. Susan, Adsorption of heavy metal ions by various low-cost adsorbents: a review. International Journal of Environmental Analytical Chemistry. 102 (2022) 342-379.
  • C. Tang, P. Brodie, Y. Li, N. J. Grishkewich, M. Brunsting, & K.C. Tam, Shape recoverable and mechanically robust cellulose aerogel beads for efficient removal of copper ions. Chemical Engineering Journal. 392 (2020) 124821.
  • A.M. Donia, A.A. Atia, & D.H. Mabrouk, Fast kinetic and efficient removal of As (V) from aqueous solution using anion exchange resins. Journal of hazardous materials, 191 (2011) 1-7.
  • L. Joseph, B.M. Jun, J.R. Flora, C.M. Park, & Y. Yoon, Removal of heavy metals from water sources in the developing world using low-cost materials: A review. Chemosphere, 229 (2019) 142-159.
  • J. Landaburu-Aguirre, V. García, E. Pongrácz, & R.L. Keiski, The removal of zinc from synthetic wastewaters by micellar-enhanced ultrafiltration: statistical design of experiments. Desalination. 240 (2009) 262-269.
  • A.K. Tolkou, G.Z. Kyzas, & I.A. Katsoyiannis, Arsenic (III) and Arsenic (V) Removal from Water Sources by Molecularly Imprinted Polymers (MIPs): A Mini Review of Recent Developments. Sustainability. 14 (2022) 5222.
  • E.Y. Bivián-Castro, A. Zepeda-Navarro, J. L. Guzmán-Mar, M. Flores-Alamo, & B. Mata-Ortega, Ion-imprinted polymer structurally preorganized using a phenanthroline-divinylbenzoate complex with the Cu (II) ion as template and some adsorption results. Polymers, 15 (2023) 1186.
  • S.M. Muk Ng, R.Narayanaswamy, Fluorescence sensor using a molecularly imprinted polymer as a recognition receptor for the detection of aluminium ions in aqueous media. Anal. Bioanal. Chem. 386 (2006) 1235–1244.
  • H. Su, J. Li, T. Tan, Adsorption mechanism for imprinted ion (Ni2+) of the surface molecular imprinting adsorbent (SMIA). Biochem. Eng. J. 39 (2008) 503–509.
  • I. Dakova, I. Karadjova, V. Georgieva, G. Georgiev, Ion-imprinted polymethacrylic microbeads as new sorbent for preconcentration and speciation of mercury. Talanta. 78 (2009) 523–529.
  • Y. Lu, C.L. Yan, S.Y. Gao, Preparation and recognition of surface molecularly imprinted core–shell microbeads for protein in aqueous solutions. Appl. Surf. Sci. 255 (2009) 6061–6066.
  • G. Bayramoglu, M.Y. Arica, Synthesis of Cr(VI)-imprinted poly(4-vinyl pyridine-co-hydroxyethyl methacrylate) particles: Its adsorption propensity to Cr(VI). J. Hazard. Mater. 187 (2011) 213-221.
  • S. Akgönüllü, S. Kılıç, C. Esen, & A.Denizli, Molecularly imprinted polymer-based sensors for protein detection. Polymers. 15 (2023) 629.
  • K. Haupt, K. Mosbach, Molecularly Imprinted Polymers and Their Use in Biomimetic Sensors. Chem. Rev. 100 (2000) 2495–2504.
  • D.A. Spivak, Optimization, Evaluation, and Characterization of Molecularly Imprinted Polymers. Adv. Drug Deliv. Rev. 57 (2005) 1779–1794.
  • H. Wang, C. Huang, S. Ma, C. Bo, J. Ou, & B. Gong, Recent advances of restricted access molecularly imprinted materials and their applications in food and biological samples analysis. TrAC Trends in Analytical Chemistry. (2022) 116526.
  • B. Rezaei, S. Mallakpour, N. Majidi, Solid-phase molecularly imprinted preconcentration and spectrophotometric determination of isoxicam in pharmaceuticals and human serum. Talanta 78 (2009) 418-423.
  • S. Ansari, M. Karimi, Recent progress, challenges and trends in trace determination of drug analysis using molecularly imprinted solid-phase microextraction technology, Talanta 164 (2017) 612-625.
  • M. Contin, P. Bonelli, S. Lucangioli, A. Cukierman, V. Tripodi, Synthesis and characterization of molecularly imprinted polymer nanoparticles for coenzyme Q10 dispersive micro solid phase extraction, J. Chromatogr. A 1456 (2016) 1-9.
  • J.W. Lowdon, H. Dili€en, P. Singla, M. Peeters, T.J. Cleij, B. van Grinsven, K. Eersels, MIPs for commercial application in low-cost sensors and assays - an overview of the current status quo, Sensor. Actuator. B Chem. 325 (2020) 128973.
  • K. Araki, T. Maruyama, N. Kamiya, M. Goto, Metal ion-selective membrane prepared by surface molecular imprinting. J. Chromatogr. B, 818 (2005) 141–145.
  • M. Karabörk, E. Kırveli, H. Kırpık, D. Suluoğlu, M. Köse, Competitive Liquid–Liquid Extraction of Cu (II) Ion from Aqueous Using New Diazo-Compounds. Water, Air, & Soil Pollution, 234 (2023) 130.
  • R. Kose, S. A. Gungor, S. E. Kariper, M. Kose, M. Kurtoglu, The new O, O and N, O type ligands and their Cu (II) and Ni (II) complexes: Crystal structure, absorption-emission properties and superoxide dismutase mimetic studies. Inorganica Chimica Acta, 462 (2017) 130-141.
  • M. Karabörk, A. Ersöz, E. Birlik, S. A. Y. Rıdvan, Preconcentration of Fe III Using Fe III-Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS. Hacettepe Journal of Biology and Chemistry, 35 (2007) 135-142.
  • M. Karabörk, A. Ersöz, A. Denizli, R. Say, Polymer− clay nanocomposite iron traps based on intersurface ion-imprinting. Industrial & engineering chemistry research, 47 (2008) 2258-2264.
  • M. Karabörk, Solid-Phase Extraction Applıcations Based On Ion Imprinting (Doctoral dissertation, Anadolu University (Turkey)) (2015).

Synthesis of Microspheres Printed with Metals and Investigation of Their Detection Performance Against Some Metals by ICP-OES

Year 2024, Volume: 52 Issue: 1, 41 - 54, 04.01.2024
https://doi.org/10.15671/hjbc.1359536

Abstract

In this study, ion-imprinted polymers were prepared. These polymers can be used for the selective removal of Cu(II) ions from aqueous solutions. To this end, (E)-2-hydroxy-5-((vinylphenyl)diazonyl) benzaldehyde was used as a functional monomer in the synthesis stage of the polymeric adsorbent. Cu(II) imprinted poly[Cu(C15H11N2O2)] microspheres have been synthesised by dispersion polymerisation technique through interaction of the template molecule Cu(II) ion with the functional monomer. The specific surface area of Cu(II) imprinted poly[Cu(C15H11N2O2)] microspheres was 374.26 m2/g. The swelling rate was 80%. The maximum adsorption capacity, the optimum pH and the adsorption equilibrium time were determined to be 153.03 mg/g, in the 8-10 range and 30 min, respectively. The relative selectivity coefficients of the imprinted microspheres were found to be 13.09, 57.88, 44.719 and 35.006 for Cu(II)/Ni(II), Cu(II)/Pb(II), Cu(II)/Zn(II) and Cu(II)/Co(II), respectively. These results showed that the Cu(II)-imprinted microspheres were more selective with respect to Cu(II) ions. Reproducibility studies showed that Cu(II) imprinted poly[Cu(C15H11N2O2)] microspheres can be used repeatedly without significant decrease in adsorption capacity.

Project Number

2013/6-4YLS

Thanks

This study was financially supported in the scope of the research project coded “ 2013/6-4YLS” by Kahramanmaras Sutcu Imam University Scientific Research Projects Unit (KSÜ BAP). We would like to thank Dr. Mukerrem Kurtoğlu for his contributions in the synthesis phase.

References

  • C.H. Walker, R.M. Sibly, S.P. Hopkin, D. B. Peakall, Principles of Ecotoxicology; Group, T. And F., Ed.; 4th Edition, CRC Press, 2012.
  • D. Türkmen, M. Bakhshpour, S. Akgönüllü, S. Aşır, & A. Denizli, Heavy metal ions removal from wastewater using cryogels: A review. Frontiers in Sustainability. 3 (2022) 765592.
  • H. Wu, G. Lin, C. Liu, S. Chu, C. Mo, & X. Liu, Progress and challenges in molecularly imprinted polymers for adsorption of heavy metal ions from wastewater. Trends in Environmental Analytical Chemistry. 36 (2022) e00178.
  • S. Nam, & P.G. Tratnyek, Reduction of azo dyes with zero-valent iron. Water Research. 34 (2000) 1837-1845.
  • A.R. Bagheri, N. Aramesh, A.A. Khan, I. Gul, S. Ghotekar, & M. Bilal, Molecularly imprinted polymers-based adsorption and photocatalytic approaches for mitigation of environmentally-hazardous pollutants─ A review. Journal of Environmental Chemical Engineering. 9 (2021) 104879.
  • L. Duan, Y. Zhang, M. He, R. Deng, H. Yi, Q. Wei, & A. Uddin, Burn-in degradation mechanism identified for small molecular acceptor-based high-efficiency nonfullerene organic solar cells. ACS applied materials & interfaces. 12 (2020) 27433-27442.
  • Y. Gao, N. Yan, C. Jiang, C. Xu, S. Yu, P. Liang, & X. Huang, Filtration-enhanced highly efficient photocatalytic degradation with a novel electrospun rGO@ TiO2 nanofibrous membrane: Implication for improving photocatalytic efficiency. Applied Catalysis B: Environmental. 268 (2020) 118737.
  • F. Fu, Q. Wang, Removal of heavy metal ions from wastewaters: A review. Journal of Environmental Management. 92 (2011) 407-418.
  • P. Häyrynen, J. Landaburu-Aguirre, E. Pongrácz, R.L. Keiski, Study of permeate flux in micellar-enhanced ultrafiltration on a semi-pilot scale: Simultaneous removal of heavy metals from phosphorous rich real wastewaters. Separation and Purification Technology. 93 (2012) 59-66.
  • M. Adrees, S. Ali, M. Rizwan, M. Zia-Ur-Rehman, M. Ibrahim, F. Abbas, M. Farid, M. F. Qayyum, M. K. Irshad, Mechanisms of silicon-mediated alleviation of heavy metal toxicity in plants: A review. Ecotoxicology and Environmental Safety, 119 (2015) 186-197.
  • M. Singh, J. Kumar, S. Singh, V.P. Singh, S.M. Prasad, M. Singh, Adaptation strategies of plants against heavy metal toxicity: A short review. Biochemistry and Pharmacology (Los Angeles). 4 (2015) 501-2167.
  • C. K. Yap, M. Saleem, W. S. Tan, W. M. Syazwan, N. Azrizal-Wahid, R. Nulit, L. S. Wong, Ecological–Health Risk Assessments of Copper in the Sediments: A Review and Synthesis. Pollutants, 2 (2022) 269-288.
  • R. N. Khalef, A. I. Hassan, H. M. Saleh, (2022) Metal’s Environmental Impact. In: Environmental Impact and Remediation of Heavy Metals. IntechOpen.
  • Panel on Micronutrients, & Nutrition Board. (2002). Dietary Reference Intakes for vitamin A, vitamin K, arsenic, boron, chromium, copper, iodine, iron, manganese, molybdenum, nickel, silicon, vanadium, and zinc. Dietary Reference Intakes.
  • L.M. Gaetke, & C.K. Chow, Copper toxicity, oxidative stress, and antioxidant nutrients. Toxicology. 189 (2003) 147-163.
  • C.F. Carolin, P.S. Kumar, A. Saravanan, G.J. Joshiba, & M. Naushad, Efficient techniques for the removal of toxic heavy metals from aquatic environment: A review. Journal of environmental chemical engineering. 5 (2017) 2782-2799.
  • R. Chakraborty, A. Asthana, A.K. Singh, B. Jain, & A.B.H. Susan, Adsorption of heavy metal ions by various low-cost adsorbents: a review. International Journal of Environmental Analytical Chemistry. 102 (2022) 342-379.
  • C. Tang, P. Brodie, Y. Li, N. J. Grishkewich, M. Brunsting, & K.C. Tam, Shape recoverable and mechanically robust cellulose aerogel beads for efficient removal of copper ions. Chemical Engineering Journal. 392 (2020) 124821.
  • A.M. Donia, A.A. Atia, & D.H. Mabrouk, Fast kinetic and efficient removal of As (V) from aqueous solution using anion exchange resins. Journal of hazardous materials, 191 (2011) 1-7.
  • L. Joseph, B.M. Jun, J.R. Flora, C.M. Park, & Y. Yoon, Removal of heavy metals from water sources in the developing world using low-cost materials: A review. Chemosphere, 229 (2019) 142-159.
  • J. Landaburu-Aguirre, V. García, E. Pongrácz, & R.L. Keiski, The removal of zinc from synthetic wastewaters by micellar-enhanced ultrafiltration: statistical design of experiments. Desalination. 240 (2009) 262-269.
  • A.K. Tolkou, G.Z. Kyzas, & I.A. Katsoyiannis, Arsenic (III) and Arsenic (V) Removal from Water Sources by Molecularly Imprinted Polymers (MIPs): A Mini Review of Recent Developments. Sustainability. 14 (2022) 5222.
  • E.Y. Bivián-Castro, A. Zepeda-Navarro, J. L. Guzmán-Mar, M. Flores-Alamo, & B. Mata-Ortega, Ion-imprinted polymer structurally preorganized using a phenanthroline-divinylbenzoate complex with the Cu (II) ion as template and some adsorption results. Polymers, 15 (2023) 1186.
  • S.M. Muk Ng, R.Narayanaswamy, Fluorescence sensor using a molecularly imprinted polymer as a recognition receptor for the detection of aluminium ions in aqueous media. Anal. Bioanal. Chem. 386 (2006) 1235–1244.
  • H. Su, J. Li, T. Tan, Adsorption mechanism for imprinted ion (Ni2+) of the surface molecular imprinting adsorbent (SMIA). Biochem. Eng. J. 39 (2008) 503–509.
  • I. Dakova, I. Karadjova, V. Georgieva, G. Georgiev, Ion-imprinted polymethacrylic microbeads as new sorbent for preconcentration and speciation of mercury. Talanta. 78 (2009) 523–529.
  • Y. Lu, C.L. Yan, S.Y. Gao, Preparation and recognition of surface molecularly imprinted core–shell microbeads for protein in aqueous solutions. Appl. Surf. Sci. 255 (2009) 6061–6066.
  • G. Bayramoglu, M.Y. Arica, Synthesis of Cr(VI)-imprinted poly(4-vinyl pyridine-co-hydroxyethyl methacrylate) particles: Its adsorption propensity to Cr(VI). J. Hazard. Mater. 187 (2011) 213-221.
  • S. Akgönüllü, S. Kılıç, C. Esen, & A.Denizli, Molecularly imprinted polymer-based sensors for protein detection. Polymers. 15 (2023) 629.
  • K. Haupt, K. Mosbach, Molecularly Imprinted Polymers and Their Use in Biomimetic Sensors. Chem. Rev. 100 (2000) 2495–2504.
  • D.A. Spivak, Optimization, Evaluation, and Characterization of Molecularly Imprinted Polymers. Adv. Drug Deliv. Rev. 57 (2005) 1779–1794.
  • H. Wang, C. Huang, S. Ma, C. Bo, J. Ou, & B. Gong, Recent advances of restricted access molecularly imprinted materials and their applications in food and biological samples analysis. TrAC Trends in Analytical Chemistry. (2022) 116526.
  • B. Rezaei, S. Mallakpour, N. Majidi, Solid-phase molecularly imprinted preconcentration and spectrophotometric determination of isoxicam in pharmaceuticals and human serum. Talanta 78 (2009) 418-423.
  • S. Ansari, M. Karimi, Recent progress, challenges and trends in trace determination of drug analysis using molecularly imprinted solid-phase microextraction technology, Talanta 164 (2017) 612-625.
  • M. Contin, P. Bonelli, S. Lucangioli, A. Cukierman, V. Tripodi, Synthesis and characterization of molecularly imprinted polymer nanoparticles for coenzyme Q10 dispersive micro solid phase extraction, J. Chromatogr. A 1456 (2016) 1-9.
  • J.W. Lowdon, H. Dili€en, P. Singla, M. Peeters, T.J. Cleij, B. van Grinsven, K. Eersels, MIPs for commercial application in low-cost sensors and assays - an overview of the current status quo, Sensor. Actuator. B Chem. 325 (2020) 128973.
  • K. Araki, T. Maruyama, N. Kamiya, M. Goto, Metal ion-selective membrane prepared by surface molecular imprinting. J. Chromatogr. B, 818 (2005) 141–145.
  • M. Karabörk, E. Kırveli, H. Kırpık, D. Suluoğlu, M. Köse, Competitive Liquid–Liquid Extraction of Cu (II) Ion from Aqueous Using New Diazo-Compounds. Water, Air, & Soil Pollution, 234 (2023) 130.
  • R. Kose, S. A. Gungor, S. E. Kariper, M. Kose, M. Kurtoglu, The new O, O and N, O type ligands and their Cu (II) and Ni (II) complexes: Crystal structure, absorption-emission properties and superoxide dismutase mimetic studies. Inorganica Chimica Acta, 462 (2017) 130-141.
  • M. Karabörk, A. Ersöz, E. Birlik, S. A. Y. Rıdvan, Preconcentration of Fe III Using Fe III-Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS. Hacettepe Journal of Biology and Chemistry, 35 (2007) 135-142.
  • M. Karabörk, A. Ersöz, A. Denizli, R. Say, Polymer− clay nanocomposite iron traps based on intersurface ion-imprinting. Industrial & engineering chemistry research, 47 (2008) 2258-2264.
  • M. Karabörk, Solid-Phase Extraction Applıcations Based On Ion Imprinting (Doctoral dissertation, Anadolu University (Turkey)) (2015).
There are 42 citations in total.

Details

Primary Language English
Subjects Separation Science
Journal Section Research Article
Authors

Sibel Çolak 0009-0004-2889-3813

Muharrem Karabörk 0000-0002-5996-6243

Derya Kılıçaslan 0000-0001-7830-8214

Project Number 2013/6-4YLS
Publication Date January 4, 2024
Acceptance Date November 20, 2023
Published in Issue Year 2024 Volume: 52 Issue: 1

Cite

APA Çolak, S., Karabörk, M., & Kılıçaslan, D. (2024). Synthesis of Microspheres Printed with Metals and Investigation of Their Detection Performance Against Some Metals by ICP-OES. Hacettepe Journal of Biology and Chemistry, 52(1), 41-54. https://doi.org/10.15671/hjbc.1359536
AMA Çolak S, Karabörk M, Kılıçaslan D. Synthesis of Microspheres Printed with Metals and Investigation of Their Detection Performance Against Some Metals by ICP-OES. HJBC. January 2024;52(1):41-54. doi:10.15671/hjbc.1359536
Chicago Çolak, Sibel, Muharrem Karabörk, and Derya Kılıçaslan. “Synthesis of Microspheres Printed With Metals and Investigation of Their Detection Performance Against Some Metals by ICP-OES”. Hacettepe Journal of Biology and Chemistry 52, no. 1 (January 2024): 41-54. https://doi.org/10.15671/hjbc.1359536.
EndNote Çolak S, Karabörk M, Kılıçaslan D (January 1, 2024) Synthesis of Microspheres Printed with Metals and Investigation of Their Detection Performance Against Some Metals by ICP-OES. Hacettepe Journal of Biology and Chemistry 52 1 41–54.
IEEE S. Çolak, M. Karabörk, and D. Kılıçaslan, “Synthesis of Microspheres Printed with Metals and Investigation of Their Detection Performance Against Some Metals by ICP-OES”, HJBC, vol. 52, no. 1, pp. 41–54, 2024, doi: 10.15671/hjbc.1359536.
ISNAD Çolak, Sibel et al. “Synthesis of Microspheres Printed With Metals and Investigation of Their Detection Performance Against Some Metals by ICP-OES”. Hacettepe Journal of Biology and Chemistry 52/1 (January 2024), 41-54. https://doi.org/10.15671/hjbc.1359536.
JAMA Çolak S, Karabörk M, Kılıçaslan D. Synthesis of Microspheres Printed with Metals and Investigation of Their Detection Performance Against Some Metals by ICP-OES. HJBC. 2024;52:41–54.
MLA Çolak, Sibel et al. “Synthesis of Microspheres Printed With Metals and Investigation of Their Detection Performance Against Some Metals by ICP-OES”. Hacettepe Journal of Biology and Chemistry, vol. 52, no. 1, 2024, pp. 41-54, doi:10.15671/hjbc.1359536.
Vancouver Çolak S, Karabörk M, Kılıçaslan D. Synthesis of Microspheres Printed with Metals and Investigation of Their Detection Performance Against Some Metals by ICP-OES. HJBC. 2024;52(1):41-54.

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