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Metoksimetiltrifenilfosfonyum Klorür Tek Kristalinde Oluşturulan Yapısal Bozukluğun Elektron Paramanyetik Rezonans ile Tespiti

Year 2023, Volume: 26 Issue: 1, 457 - 468, 27.03.2023
https://doi.org/10.2339/politeknik.992660

Abstract

Metoksimetiltrifenilfosfonyum klorür (MOMTPPC) tek kristalleri Elektron Paramanyetik Rezonans (EPR) spektroskopi yöntemi ile analiz edilmiştir. MOMTPPC tek kristalleri, 60Co- kaynağı ile ışınlanarak paramanyetik bozukluklar oluşturulmuştur. MOMTPPC tek kristallerinin EPR spektrumları, 120 K sıcaklıkta üç dik eksen etrafında belirli açılarda döndürülerek EPR spektrumları alınmıştır. MOMTPPC'de ışınlama etkisiyle oluşan radikalin yapısı, EPR spektrumlarının detaylı incelenmesi ile elde edilmiştir. Radyasyonun etkisiyle C20-H24 bağı kopmuş ve bir paramanyetik merkez oluşmuştur. Kimyasal bağın kopması sonucu oluşan radikalin eşleşmemiş elektronunun C20 atomu üzerinde bulunduğu belirlenmiştir. Radyasyon hasar merkezine ait anizotropik g-faktörü ve aşırı ince yapı çiftlenim sabitleri belirlenmiştir. Spektroskopik yarılma faktörünün izotropik değeri g = 2,00764 olarak elde edilirken, aşırı ince yapı sabitlerinin izotropik değerleri ise sırasıyla, 〖(a_H)〗_α = 2,010 mT, 〖(a_P)〗_β = 3,196 mT ve 〖(a_(C_6 H_5 ))〗_γ= 〖(a_fenil)〗_γ = 0,472 mT olarak hesaplanmıştır. EPR parametrelerine ait yön kosinüsleri elde edilmiştir. Ayrıca, simülasyon çalışmaları ile deneysel verilerimizin doğruluğu desteklenmiştir.  

Supporting Institution

Pamukkale Üniversitesi-BAP

Project Number

The BAP of Pamukkale University [grant number 2012FBE037].

Thanks

2012FBE037 numaralı projeye desteklerinden dolayı Pamukkale Üniversitesi Bilimsel Araştırma Projeleri Birimi’ne teşekkür ederiz.

References

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Detection of Structural Defect in Methoxymethyltriphenylphosphonium Chloride Single Crystal by Electron Paramagnetic Resonance

Year 2023, Volume: 26 Issue: 1, 457 - 468, 27.03.2023
https://doi.org/10.2339/politeknik.992660

Abstract

Single crystals of methoxymethyltriphenylphosphonium chloride (MOMTPPC) were analyzed by Electron Paramagnetic Resonance (EPR) spectroscopy method. Gamma radiation from 60Co was used to create paramagnetic defects in MOMTPPC single crystal. EPR spectra of MOMTPPC single crystals were obtained at 120 K temperature by rotating around three orthogonal axes. The structure of the radical formed by the irradiation effect in MOMTPPC was found by detailed examination of the EPR spectra. With the effect of radiation, the C20-H24 bond was broken and a paramagnetic center was formed. It has been determined that the unpaired electron of the radical formed as a result of the breaking of the chemical bond is located mainly on the C20 atom. The anisotropic g-factor and hyperfine coupling constants of the radiation damage center were determined. While the isotropic value of the spectroscopic splitting factor is obtained as g = 2.00764, the isotropic values of the hyperfine structure constants are 〖(a_H)〗_α = 2.010 mT, 〖(a_P)〗_β = 3.196 mT and 〖(a_(C_6 H_5 ))〗_γ= 〖(a_fenil)〗_γ = 0.472 mT. Direction cosines of EPR parameters were obtained. Simulation was also carried out to prove the accuracy of our experimental data.

Project Number

The BAP of Pamukkale University [grant number 2012FBE037].

References

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  • [5] Çadırcı M., Demirci T., ‘‘Yüksek oranda eş parçacık boyutlu cdse kuantum noktaların sentezi ve optiksel özelliklerinin parçacık boyutlarına bağlılığı’’, Politeknik Dergisi, 24(1):25-30, (2021).
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  • [26] Zheng Y., Ji S., Tomaselli E., Ernest C., Freiji and Liu S., ‘‘Effect of co-ligands on chemical and biological properties of 99mTc(III) complexes [99mTc(L)(CDO)(CDOH)2BMe] (L = Cl, F, SCN and N3; CDOH2 = cyclohexanedione dioxime)’’, Nucl. Med. Biol., 41(10): 813-824, (2014).
  • [27] Haslop A., Wells L., Gee A., Plisson C. and Long N., ‘‘One-pot multi-tracer synthesis of novel 18F-labeled PET imaging agents’’, Mol. Pharm., 11(11): 3818-3822, (2014).
  • [28] Kim D. Y., Kim H. S., Jang H. Y., Kim J. H., Bom H. S. and Min J. J., ‘‘Comparison of the cardiac microPET images obtained using [18F]FPTP and [13N]NH3 in rat myocardial infarction models’’, ACS Med. Chem. Lett., 5(10): 1124-1128, (2014).
  • [29] Liu S., Li D., Shan H., Gabbai F. P., Li Z. and Conti P. S., ‘‘Evaluation of ¹⁸F-labeled BODIPY dye as potential PET agents for myocardial perfusion imaging’’, Nucl. Med. Biol., 41(1): 120-126, (2014).
  • [30] Maddahi J. and Packard R. R. S., ‘‘Cardiac PET perfusion tracers: Current status and future directions’’, Semin. Nucl. Med., 44(5): 333-343, (2014).
  • [31] Neves A. A. and Brindle K. M., ‘‘Imaging cell death’’, J. Nucl. Med., 55(1): 1-4, (2014).
  • [32] Ravert H. T., Holt D. P. and Dannals R. F., ‘‘A microwave radiosynthesis of the 4‐[18F]‐fluorobenzyltriphenylphosphonium ion’’, J. Labelled Cmpd. Radiopharm., 57(12): 695-698, (2014).
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There are 56 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Research Article
Authors

Ali Cengiz Çalışkan 0000-0001-9627-8768

Betül Çalışkan 0000-0001-6748-1169

Project Number The BAP of Pamukkale University [grant number 2012FBE037].
Publication Date March 27, 2023
Submission Date September 8, 2021
Published in Issue Year 2023 Volume: 26 Issue: 1

Cite

APA Çalışkan, A. C., & Çalışkan, B. (2023). Metoksimetiltrifenilfosfonyum Klorür Tek Kristalinde Oluşturulan Yapısal Bozukluğun Elektron Paramanyetik Rezonans ile Tespiti. Politeknik Dergisi, 26(1), 457-468. https://doi.org/10.2339/politeknik.992660
AMA Çalışkan AC, Çalışkan B. Metoksimetiltrifenilfosfonyum Klorür Tek Kristalinde Oluşturulan Yapısal Bozukluğun Elektron Paramanyetik Rezonans ile Tespiti. Politeknik Dergisi. March 2023;26(1):457-468. doi:10.2339/politeknik.992660
Chicago Çalışkan, Ali Cengiz, and Betül Çalışkan. “Metoksimetiltrifenilfosfonyum Klorür Tek Kristalinde Oluşturulan Yapısal Bozukluğun Elektron Paramanyetik Rezonans Ile Tespiti”. Politeknik Dergisi 26, no. 1 (March 2023): 457-68. https://doi.org/10.2339/politeknik.992660.
EndNote Çalışkan AC, Çalışkan B (March 1, 2023) Metoksimetiltrifenilfosfonyum Klorür Tek Kristalinde Oluşturulan Yapısal Bozukluğun Elektron Paramanyetik Rezonans ile Tespiti. Politeknik Dergisi 26 1 457–468.
IEEE A. C. Çalışkan and B. Çalışkan, “Metoksimetiltrifenilfosfonyum Klorür Tek Kristalinde Oluşturulan Yapısal Bozukluğun Elektron Paramanyetik Rezonans ile Tespiti”, Politeknik Dergisi, vol. 26, no. 1, pp. 457–468, 2023, doi: 10.2339/politeknik.992660.
ISNAD Çalışkan, Ali Cengiz - Çalışkan, Betül. “Metoksimetiltrifenilfosfonyum Klorür Tek Kristalinde Oluşturulan Yapısal Bozukluğun Elektron Paramanyetik Rezonans Ile Tespiti”. Politeknik Dergisi 26/1 (March 2023), 457-468. https://doi.org/10.2339/politeknik.992660.
JAMA Çalışkan AC, Çalışkan B. Metoksimetiltrifenilfosfonyum Klorür Tek Kristalinde Oluşturulan Yapısal Bozukluğun Elektron Paramanyetik Rezonans ile Tespiti. Politeknik Dergisi. 2023;26:457–468.
MLA Çalışkan, Ali Cengiz and Betül Çalışkan. “Metoksimetiltrifenilfosfonyum Klorür Tek Kristalinde Oluşturulan Yapısal Bozukluğun Elektron Paramanyetik Rezonans Ile Tespiti”. Politeknik Dergisi, vol. 26, no. 1, 2023, pp. 457-68, doi:10.2339/politeknik.992660.
Vancouver Çalışkan AC, Çalışkan B. Metoksimetiltrifenilfosfonyum Klorür Tek Kristalinde Oluşturulan Yapısal Bozukluğun Elektron Paramanyetik Rezonans ile Tespiti. Politeknik Dergisi. 2023;26(1):457-68.