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EFFECT OF MEMBRANE DEGUMMING CONDITIONS ON PERMEATE FLUX AND PHOSPHOLIPIDS REJECTION

Yıl 2017, Cilt: 42 Sayı: 5, 597 - 602, 19.08.2017

Öz

The
objective of this study was to investigate the performance of

PVDF membrane in degumming of undiluted crude soybean oil by using reverse
osmosis/ultrafiltration module.
The
effects of membrane degumming conditions including temperature, membrane
pressure, feed velocity, and volumetric concentration factor on permeate flux
and phospholipids rejection were evaluated statistically. The effect of
membrane pressure and volumetric concentration factor on the permeate flux was
found to be statistically significant (P<0.05).
An 86.1 % rejection of phospholipids and a permeate flux of
11.19 L/m2.h
were achieved at 400C, 20 bar pressure, 9L/min feed velocity and 5
volumetric concentration factor. The flux behavior of PVDF membrane was also
studied. Behavior of permeate flux with process time showed two separate
regions namely; falling permeate flux region and constant permeate flux
region.  A second degree polynomial
relationship was observed during falling permeate flux region; whereas a linear
dependency was set for constant permeate flux region. A logarithmic equation
was obtained when total process behavior was examined. 

Kaynakça

  • Referans1 Akin O., Temelli F., Köseoğlu S. (2012). Membrane applications in functional foods and nutraceuticals. Crit. Rev. Food Sci. and Nutrition 52(4):347-371, doi:10.1080/10408398.2010.500240
  • Referans2 Araki M.S., Coutinho C.M., Gonçalves L.A.G., Viotto L.A. (2010). Solvent permeability in commercial ultrafiltration polymeric membranes and evaluation of the structural and chemical stability towards hexane. Sep.Purif.Technol. 71:13-21, doi:10.1016/j.seppur.2009.10.005
  • Referans3 Firman, L.R., Ochoa N.A., Marchese J., Pagliero C.L. (2013). Deacidification and solvent recovery of soybean oil by nanofiltration membranes. J.Membr.Sci. 431:187-196, doi:10.1016/j.memsci.2012.12.040
  • Referans4 IUPAC (1982). Standard Methods for the Analysis of Oils, Fats and Derivatives. International Union of Pure and Applied Chemistry (IUPAC). Scientific Publications, London.
  • Referans5 Lin L., Rhee K.C., Koseoglu S.S. (1997). Bench-scale membrane degumming of crude vegetable oil: Process optimization. J.Membrane Sci. 134:101-108.
  • Referans6 Manjula S., Subramanian R. (2006). Membrane technology in degumming, dewaxing, deacidifying, and decolorizing edible oils. Crit.Rev.Food Sci. 46(7): 569-592, doi:10.1080/10408390500357746
  • Referans7 Manjula S., Nebetani H., Subramanian R. (2011). Flux behavior in a hydrophobic dense membrane with undiluted and hexane-diluted vegetable oils. J.Membrane Sci. 366:43-47, doi:10.1016/j.memsci.2010.09.041
  • Referans8 Niazmand R, Razavi SMA, Farhoosh R. (2015). Colloid-enhanced ultrafiltration of canola oil: Effect of process conditions and MCO on flux, fouling and rejections. J.Food Processing and Preservation, 39:292-300, doi:10.1111/jfpp.122232
  • Referans9 Ochoa N., Pagliero C., Marchese J., Mateea M. (2001). Ultrafiltration of vegetable oils degumming by polymeric membranes. Seperation Purification Technology,22-23: 417-422.
  • Referans10 Pagliero C, Ochoa N, Marchese J, Mattea M (2001) Degumming of crude soybean oil by ultrafiltration using polymeric membranes. J.Am.Oil Chem.,78(8):793-796.
  • Referans11 Pagliero C., Ochoa N.A., Martino P., Marchese J. (2011). Separation of sunflower oil from hexane by use of composite polymeric membranes. J.Am.Oil Chem.Soc.88(11):1813-1819, doi:10.1007/s11746-011-1839-3
  • Referans12 Penha F.M., Rezzadori K., Proner M.C., Zin G., Fogaça L.A., Petrus J.C.C., De Oliveira V., Di Luccio M. (2015). Evaluation of permeation of macauba oil and n-hexane mixtures through polymeric commercial membranes subjected to different pre-treatments. J.Food Eng. 155:79-86, doi:10.1016/j.jfoodeng.2015.01.020
  • Referans13 Roy B., Dey S., Sahoo G.C., Roy S.N., Bandyopadhhyay S. (2014). Degumming, dewaxing and deacidification of rice bran oil-hexane miscella using ceramic membrane: Pilot plant study. J.Am.Oil Chem.:1453-1460, doi:10.1007/s11746-014-2473-7
  • Referans14 Sehn G.A.R., Gonçalves L.A.G., Ming C.C. (2016). Ultrafilration-based degumming of crude rice bran oil using a polymer membrane. Grasas y Aceites, 67(1), doi:10.3989/gys.0498151
  • Referans15 Ulusoy B.O., Tur E., Akdogan E., Mutlu M. (2014). Plasma polymerization modified polyvinylidene fluoride (PVDF) membrane development and characterization for degumming of soybean oil. J.Am.Oil Chem.91:1813-1822, doi:10.1007/s11746-014-2522-2
  • Referans16 Vaisali C., Charanyaa S., Belur P.D., Regupathi I. (2015). Refining of edible oils: a critical appraisal of current and potential technologies. Int.J.FoodSci.Technol. 50:13-23, doi:10.1111/ijfs.12657

MEMBRAN DEGUMMING KOŞULLARININ PERMEAT AKISI VE FOSFOLİPİDLERIN REDDEDİLMESİ ÜZERİNDEKİ ETKİSİ

Yıl 2017, Cilt: 42 Sayı: 5, 597 - 602, 19.08.2017

Öz

Bu
çalışmanın amacı; ters osmos/ultrafiltrasyon modülü kullanılarak soya yağına
uygulanan degumming işleminde polyvinylidene fluoride (PVDF) membranın
performansının incelenmesidir. Membran degumming işlem koşullarının (sıcaklık, membran
basıncı, besleme hızı, hacimsel konsantrasyon faktörü) permeat akısı ve fosfolipitlerin
reddedilme yüzdesi üzerindeki etkisi istatistiksel olarak incelenmiştir. Membran
ba
sıncının ve hacimsel konsantrasyon faktörünün permeat akısı üzerindeki
etkisi istatistiksel olarak önemli bulunmuştur
(P<0.05).. Membran sıcaklığının 40oC, membrane
basıncının 20 bar, besleme hızının 9L/dak ve hacimsel konsantrasyon faktörünün
5 olduğu işlem koşullarında  fosfolipidlerin
reddedilme yüzdesi 86.1, permeat akısı ise 11.19L/m2.s olarak
belirlenmiştir. Ayrıca PVDF membranın akı davranışı da incelenmiştir. Permeat
akısının işlem süresi ile değişimi; akının sürekli düşme gösterdiği birinci
bölge ve akının sabit kaldığı ikinci bölge olmak üzere iki bölgede
tanımlanmıştır. Düşen akı bölgesi 2. dereceden polinomiyal, sabit akı bölgesi
doğrusal, tüm işlem için  logaritmik
model geliştirilmiştir.

Kaynakça

  • Referans1 Akin O., Temelli F., Köseoğlu S. (2012). Membrane applications in functional foods and nutraceuticals. Crit. Rev. Food Sci. and Nutrition 52(4):347-371, doi:10.1080/10408398.2010.500240
  • Referans2 Araki M.S., Coutinho C.M., Gonçalves L.A.G., Viotto L.A. (2010). Solvent permeability in commercial ultrafiltration polymeric membranes and evaluation of the structural and chemical stability towards hexane. Sep.Purif.Technol. 71:13-21, doi:10.1016/j.seppur.2009.10.005
  • Referans3 Firman, L.R., Ochoa N.A., Marchese J., Pagliero C.L. (2013). Deacidification and solvent recovery of soybean oil by nanofiltration membranes. J.Membr.Sci. 431:187-196, doi:10.1016/j.memsci.2012.12.040
  • Referans4 IUPAC (1982). Standard Methods for the Analysis of Oils, Fats and Derivatives. International Union of Pure and Applied Chemistry (IUPAC). Scientific Publications, London.
  • Referans5 Lin L., Rhee K.C., Koseoglu S.S. (1997). Bench-scale membrane degumming of crude vegetable oil: Process optimization. J.Membrane Sci. 134:101-108.
  • Referans6 Manjula S., Subramanian R. (2006). Membrane technology in degumming, dewaxing, deacidifying, and decolorizing edible oils. Crit.Rev.Food Sci. 46(7): 569-592, doi:10.1080/10408390500357746
  • Referans7 Manjula S., Nebetani H., Subramanian R. (2011). Flux behavior in a hydrophobic dense membrane with undiluted and hexane-diluted vegetable oils. J.Membrane Sci. 366:43-47, doi:10.1016/j.memsci.2010.09.041
  • Referans8 Niazmand R, Razavi SMA, Farhoosh R. (2015). Colloid-enhanced ultrafiltration of canola oil: Effect of process conditions and MCO on flux, fouling and rejections. J.Food Processing and Preservation, 39:292-300, doi:10.1111/jfpp.122232
  • Referans9 Ochoa N., Pagliero C., Marchese J., Mateea M. (2001). Ultrafiltration of vegetable oils degumming by polymeric membranes. Seperation Purification Technology,22-23: 417-422.
  • Referans10 Pagliero C, Ochoa N, Marchese J, Mattea M (2001) Degumming of crude soybean oil by ultrafiltration using polymeric membranes. J.Am.Oil Chem.,78(8):793-796.
  • Referans11 Pagliero C., Ochoa N.A., Martino P., Marchese J. (2011). Separation of sunflower oil from hexane by use of composite polymeric membranes. J.Am.Oil Chem.Soc.88(11):1813-1819, doi:10.1007/s11746-011-1839-3
  • Referans12 Penha F.M., Rezzadori K., Proner M.C., Zin G., Fogaça L.A., Petrus J.C.C., De Oliveira V., Di Luccio M. (2015). Evaluation of permeation of macauba oil and n-hexane mixtures through polymeric commercial membranes subjected to different pre-treatments. J.Food Eng. 155:79-86, doi:10.1016/j.jfoodeng.2015.01.020
  • Referans13 Roy B., Dey S., Sahoo G.C., Roy S.N., Bandyopadhhyay S. (2014). Degumming, dewaxing and deacidification of rice bran oil-hexane miscella using ceramic membrane: Pilot plant study. J.Am.Oil Chem.:1453-1460, doi:10.1007/s11746-014-2473-7
  • Referans14 Sehn G.A.R., Gonçalves L.A.G., Ming C.C. (2016). Ultrafilration-based degumming of crude rice bran oil using a polymer membrane. Grasas y Aceites, 67(1), doi:10.3989/gys.0498151
  • Referans15 Ulusoy B.O., Tur E., Akdogan E., Mutlu M. (2014). Plasma polymerization modified polyvinylidene fluoride (PVDF) membrane development and characterization for degumming of soybean oil. J.Am.Oil Chem.91:1813-1822, doi:10.1007/s11746-014-2522-2
  • Referans16 Vaisali C., Charanyaa S., Belur P.D., Regupathi I. (2015). Refining of edible oils: a critical appraisal of current and potential technologies. Int.J.FoodSci.Technol. 50:13-23, doi:10.1111/ijfs.12657
Toplam 16 adet kaynakça vardır.

Ayrıntılar

Diğer ID GD17053
Bölüm Makaleler
Yazarlar

Aytaç Gümüşkesen

Pınar Boynueğri Bu kişi benim

Fahri Yemişçioğlu Bu kişi benim

Yayımlanma Tarihi 19 Ağustos 2017
Yayımlandığı Sayı Yıl 2017 Cilt: 42 Sayı: 5

Kaynak Göster

APA Gümüşkesen, A., Boynueğri, P., & Yemişçioğlu, F. (2017). MEMBRAN DEGUMMING KOŞULLARININ PERMEAT AKISI VE FOSFOLİPİDLERIN REDDEDİLMESİ ÜZERİNDEKİ ETKİSİ. Gıda, 42(5), 597-602.
AMA Gümüşkesen A, Boynueğri P, Yemişçioğlu F. MEMBRAN DEGUMMING KOŞULLARININ PERMEAT AKISI VE FOSFOLİPİDLERIN REDDEDİLMESİ ÜZERİNDEKİ ETKİSİ. GIDA. Ekim 2017;42(5):597-602.
Chicago Gümüşkesen, Aytaç, Pınar Boynueğri, ve Fahri Yemişçioğlu. “MEMBRAN DEGUMMING KOŞULLARININ PERMEAT AKISI VE FOSFOLİPİDLERIN REDDEDİLMESİ ÜZERİNDEKİ ETKİSİ”. Gıda 42, sy. 5 (Ekim 2017): 597-602.
EndNote Gümüşkesen A, Boynueğri P, Yemişçioğlu F (01 Ekim 2017) MEMBRAN DEGUMMING KOŞULLARININ PERMEAT AKISI VE FOSFOLİPİDLERIN REDDEDİLMESİ ÜZERİNDEKİ ETKİSİ. Gıda 42 5 597–602.
IEEE A. Gümüşkesen, P. Boynueğri, ve F. Yemişçioğlu, “MEMBRAN DEGUMMING KOŞULLARININ PERMEAT AKISI VE FOSFOLİPİDLERIN REDDEDİLMESİ ÜZERİNDEKİ ETKİSİ”, GIDA, c. 42, sy. 5, ss. 597–602, 2017.
ISNAD Gümüşkesen, Aytaç vd. “MEMBRAN DEGUMMING KOŞULLARININ PERMEAT AKISI VE FOSFOLİPİDLERIN REDDEDİLMESİ ÜZERİNDEKİ ETKİSİ”. Gıda 42/5 (Ekim 2017), 597-602.
JAMA Gümüşkesen A, Boynueğri P, Yemişçioğlu F. MEMBRAN DEGUMMING KOŞULLARININ PERMEAT AKISI VE FOSFOLİPİDLERIN REDDEDİLMESİ ÜZERİNDEKİ ETKİSİ. GIDA. 2017;42:597–602.
MLA Gümüşkesen, Aytaç vd. “MEMBRAN DEGUMMING KOŞULLARININ PERMEAT AKISI VE FOSFOLİPİDLERIN REDDEDİLMESİ ÜZERİNDEKİ ETKİSİ”. Gıda, c. 42, sy. 5, 2017, ss. 597-02.
Vancouver Gümüşkesen A, Boynueğri P, Yemişçioğlu F. MEMBRAN DEGUMMING KOŞULLARININ PERMEAT AKISI VE FOSFOLİPİDLERIN REDDEDİLMESİ ÜZERİNDEKİ ETKİSİ. GIDA. 2017;42(5):597-602.

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