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Arıtma Çamuru Küllerinden Kimyasal Ekstraksiyonla Fosfor Geri Kazanımının Araştırılması

Year 2022, Volume: 19 Issue: 2, 177 - 182, 30.12.2022
https://doi.org/10.25308/aduziraat.1050158

Abstract

Arıtma çamurlarının yakılarak bertarafı sonucu oluşan küllerin yüksek fosfor içeriğinden dolayı fosfor geri kazanımı, oluşan bu küllerin değerlendirilmesinde önemli bir seçenektir. Bu çalışmada Köyceğiz-Dalyan bölgesindeki arıtma tesisinden alınan arıtma çamurunda kimyasal ekstraksiyon yöntemi ile fosfor geri kazanımı araştırıldı. Arıtma çamurları 850 °C’de kül haline getirilmiş ve HCI, H2SO4 ve NaOH’ın farklı derişimlerdeki çözeltileri ile ekstrakte edilerek fosfor miktarları spektrofotometrik olarak tespit edilmiştir. Sonuç olarak en yüksek verim 38,3 g/kg olarak 1M H2SO4 çözeltisi ile elde edildiği belirlenmiştir. Ancak ekonomik ve çevresel faktörler göz önüne alındığında 0.05 M H2SO4 çözeltisi ile elde edilen 36 g/kg verimin daha etkin olabileceği vurgulanmıştır. Bu sonuçlarla birlikte metal toksisitesi düşük olan arıtma çamuru örneklerinin bu alandaki arıtma çamurlarından, çevresel riski daha düşük fosfor elde edileceğini göstermektedir.

Supporting Institution

Muğla Sıtkı Koçman Üniversitesi

Project Number

BAP No: 19/081/16/1

Thanks

Bu çalışma yüksek lisans tez projesi kapsamında tamamlandı. Projeyi BAP No: 19/081/16/1 ile destekleyen Muğla Sıtkı Koçman Üniversitesi Bilimsel Araştırma Projeleri Yönetim Birimi Başkanlığı’na teşekkür ederiz. MUSKİ yetkililerine ve Dalyan Atık Su Arıtma Tesisi çalışanlarına arıtma çamuru temini ve ağır metal analizleri için teşekkürü bir borç biliriz.

References

  • Abis M, Calmano W, Kuchta K (2018) Innovative technologies for phosphorus recovery from sewage sludge ash. Detritus 1: 23-29.
  • Amann A, Zoboli O, Krampe J, Rechberger H, Zessner M, Egle L (2018) Environmental impacts of phosphorus recovery from municipal wastewater. Resources, Conservation and Recycling, 130: 127-139.
  • APHA, AWWA, WEF, (2012) Standart Methods for The Examination of Water and Wastewater. 22st. Edition, American Public Health Association, Washington, 4-103:4-169.
  • Boinardi G, Turolla A, Fiameni L, Gelmi E, Malpei F, Bontempi E, Canziani R (2021) Assessment of a simple and replicable procedure for selective phosphorus recovery from sewage sludge ashes by wet chemical extraction and precipitation. Chemosphere 285: 131476.
  • Chapagain Y (2016) Metots and Possibility of Recycling of Phosphorus from Sludge, Environmental Engineering. Helsinki Metropolia University of Applied Sciences Helsinki Finland: 1-51.
  • Chrispim MC, Scholz M, Nolasco MA (2019) Phosphorus recovery from municipal wastewater treatment: Critical review of challenges and opportunities for developing countries. Journal of environmental management, 248: 109268.
  • Donatello S, Cheeseman CR, (2013) Recycling and recovery routes for incinerated sewage sludge ash (ISSA): a review. Waste Manag. 33: 2328-2340.
  • European Commission (EC 2017) https://ec.europa.eu/growth/sectors/raw-materials/ specifc-interest/critical_en.
  • Karabacak, E (2021) Arıtma Çamuru Yakma Fırını Küllerinden Fosfor Geri Kazanımı. Yüksek Lisans Tezi, Bursa Uludağ Üniversitesi, Fen Bilimleri Enstitüsü, Bursa.
  • Koutsoukos PG, Valsami-Jones E (2004) Principles of phosphate dissolution and precipitation. In: Valsami-Jones, E. (Editor). Phosphorus in Environmental Technologies, Principles and Applications. IWA publishing, London, ISBN: 1 84339 001 9:195-248.
  • Lee C-G, Alvarez PJJ, Kim H-G, Jeong S, Lee S, Lee KB, Lee S-H, Choi J-W (2018) Phosphorous recovery from sewage sludge using calcium silicate hydrates. Chemosphere 193: 1087-1093.
  • Mihelcic JR, Fry LM, Shaw R (2011) Global potential of phosphorus recovery from human urine and feces. Chemosphere 84: 832-839.
  • Pires A, Martinho G (2019) Waste hierarchy index for circular economy in waste management. Waste Manage 95: 298-305.
  • Pradhan SK, Heinonen-Tanski H, Veijalainen AM, Peräniemi S, Torvinen E (2021) Phosphorus Recovery from Sewage Sludge Using Acidithiobacilli. Int. J. Environ. Res. Public Health 18: 7135.
  • Remmen K, Müller B, Köser J, Wessling M, Wintgens T (2019) Phosphorus recovery in an acidic environment using layer-by-layer modified membranes. Journal of Membrane Science 582: 254-263.
  • Semerci N, Kunt B, Calli B (2019) Phosphorus recovery from sewage sludge ash with bioleaching and electrodialysis. International Biodeterioration & Biodegradation 144: 104739.
  • Smol M, Adam C, Kugler SA (2020) Inventory of Polish municipal sewage sludge ash (SSA)-Mass flows, chemical composition, and phosphorus recovery potential. Waste Management 116: 31-39.
  • Stark K (2005) Phosphorus Release from Swage Sludge by use of Acids and Bases. Division of water resources engineering. Royal institute of technology (KTH), S-100 44 Stockholm, Sweden, 1-12.
  • Stark K (2006) Phosphorus Recovery by use of Sludge Fractionation. Royal institute of technology (KTH), Vatten 62:49-56. S-100 44 Stockholm, Sweden, 1-8.
  • TÜİK 2018 Türkiye İstatistik Kurumu. www.tuik.gov.tr.
  • Wang Q, Li J-S, Xue Q, Poon CS (2021) Alkaline modification of the acid residue of incinerated sewage sludge ash after phosphorus recovery for heavy metal removal from aqueous solutions. Waste Management 123: 80-87.
  • Yang F, Chen J, Yang M, Wang X, Sun Y, Xu Y, Qian G (2019) Phosphorus recovery from sewage sludge via incineration with chlorine-based additives. Waste Management 95: 644-651.
  • Yu X, Nakamura Y, Otsuka M, Omori D, Haruta S (2021) Development of a novel phosphorus recovery system using incinerated sewage sludge ash (ISSA) and phosphorus-selective adsorbent. Waste Management 120: 41-49.
  • Zhou K, Barjenbruch M, Kabbe C, Inial G, Remy C (2017) Phosphorus recovery from municipal and fertilizer wastewater: China's potential and perspective. Journal of Environmental Sciences, 52: 151-159.

Investigation of Phosphorus Recovery by Chemical Extraction from Sewage Sludge Ashes

Year 2022, Volume: 19 Issue: 2, 177 - 182, 30.12.2022
https://doi.org/10.25308/aduziraat.1050158

Abstract

Phosphorus recovery due to the high phosphorus content of the ashes formed as a result of the burning and disposal of treatment sludge is an important option in the evaluation of these ashes. In this study, phosphorus recovery was investigated by chemical extraction method in the treatment sludge taken from the treatment plant in the Köyceğiz-Dalyan region. Treatment sludge was ashed at 850 °C and extracted with solutions of HCI, H2SO4 and NaOH in different concentrations and phosphorus quantities were detected spectrophotometrically. As a result, the highest yield was determined to be obtained with 1 M H2SO4 solution as 38.3 g/kg. However, considering the economic and environmental factors, it is emphasized that the yield of 36 g/kg obtained with 0.05 M H2SO4 solution may be more effective. These results show that treatment sludge samples with low metal toxicity will obtain phosphorus with lower environmental risk from the treatment sludge in this area.

Project Number

BAP No: 19/081/16/1

References

  • Abis M, Calmano W, Kuchta K (2018) Innovative technologies for phosphorus recovery from sewage sludge ash. Detritus 1: 23-29.
  • Amann A, Zoboli O, Krampe J, Rechberger H, Zessner M, Egle L (2018) Environmental impacts of phosphorus recovery from municipal wastewater. Resources, Conservation and Recycling, 130: 127-139.
  • APHA, AWWA, WEF, (2012) Standart Methods for The Examination of Water and Wastewater. 22st. Edition, American Public Health Association, Washington, 4-103:4-169.
  • Boinardi G, Turolla A, Fiameni L, Gelmi E, Malpei F, Bontempi E, Canziani R (2021) Assessment of a simple and replicable procedure for selective phosphorus recovery from sewage sludge ashes by wet chemical extraction and precipitation. Chemosphere 285: 131476.
  • Chapagain Y (2016) Metots and Possibility of Recycling of Phosphorus from Sludge, Environmental Engineering. Helsinki Metropolia University of Applied Sciences Helsinki Finland: 1-51.
  • Chrispim MC, Scholz M, Nolasco MA (2019) Phosphorus recovery from municipal wastewater treatment: Critical review of challenges and opportunities for developing countries. Journal of environmental management, 248: 109268.
  • Donatello S, Cheeseman CR, (2013) Recycling and recovery routes for incinerated sewage sludge ash (ISSA): a review. Waste Manag. 33: 2328-2340.
  • European Commission (EC 2017) https://ec.europa.eu/growth/sectors/raw-materials/ specifc-interest/critical_en.
  • Karabacak, E (2021) Arıtma Çamuru Yakma Fırını Küllerinden Fosfor Geri Kazanımı. Yüksek Lisans Tezi, Bursa Uludağ Üniversitesi, Fen Bilimleri Enstitüsü, Bursa.
  • Koutsoukos PG, Valsami-Jones E (2004) Principles of phosphate dissolution and precipitation. In: Valsami-Jones, E. (Editor). Phosphorus in Environmental Technologies, Principles and Applications. IWA publishing, London, ISBN: 1 84339 001 9:195-248.
  • Lee C-G, Alvarez PJJ, Kim H-G, Jeong S, Lee S, Lee KB, Lee S-H, Choi J-W (2018) Phosphorous recovery from sewage sludge using calcium silicate hydrates. Chemosphere 193: 1087-1093.
  • Mihelcic JR, Fry LM, Shaw R (2011) Global potential of phosphorus recovery from human urine and feces. Chemosphere 84: 832-839.
  • Pires A, Martinho G (2019) Waste hierarchy index for circular economy in waste management. Waste Manage 95: 298-305.
  • Pradhan SK, Heinonen-Tanski H, Veijalainen AM, Peräniemi S, Torvinen E (2021) Phosphorus Recovery from Sewage Sludge Using Acidithiobacilli. Int. J. Environ. Res. Public Health 18: 7135.
  • Remmen K, Müller B, Köser J, Wessling M, Wintgens T (2019) Phosphorus recovery in an acidic environment using layer-by-layer modified membranes. Journal of Membrane Science 582: 254-263.
  • Semerci N, Kunt B, Calli B (2019) Phosphorus recovery from sewage sludge ash with bioleaching and electrodialysis. International Biodeterioration & Biodegradation 144: 104739.
  • Smol M, Adam C, Kugler SA (2020) Inventory of Polish municipal sewage sludge ash (SSA)-Mass flows, chemical composition, and phosphorus recovery potential. Waste Management 116: 31-39.
  • Stark K (2005) Phosphorus Release from Swage Sludge by use of Acids and Bases. Division of water resources engineering. Royal institute of technology (KTH), S-100 44 Stockholm, Sweden, 1-12.
  • Stark K (2006) Phosphorus Recovery by use of Sludge Fractionation. Royal institute of technology (KTH), Vatten 62:49-56. S-100 44 Stockholm, Sweden, 1-8.
  • TÜİK 2018 Türkiye İstatistik Kurumu. www.tuik.gov.tr.
  • Wang Q, Li J-S, Xue Q, Poon CS (2021) Alkaline modification of the acid residue of incinerated sewage sludge ash after phosphorus recovery for heavy metal removal from aqueous solutions. Waste Management 123: 80-87.
  • Yang F, Chen J, Yang M, Wang X, Sun Y, Xu Y, Qian G (2019) Phosphorus recovery from sewage sludge via incineration with chlorine-based additives. Waste Management 95: 644-651.
  • Yu X, Nakamura Y, Otsuka M, Omori D, Haruta S (2021) Development of a novel phosphorus recovery system using incinerated sewage sludge ash (ISSA) and phosphorus-selective adsorbent. Waste Management 120: 41-49.
  • Zhou K, Barjenbruch M, Kabbe C, Inial G, Remy C (2017) Phosphorus recovery from municipal and fertilizer wastewater: China's potential and perspective. Journal of Environmental Sciences, 52: 151-159.
There are 24 citations in total.

Details

Primary Language Turkish
Subjects Agricultural Engineering (Other)
Journal Section Research
Authors

Nigar Zeynalova 0000-0002-4625-1986

Bülent Yorulmaz 0000-0003-1654-8874

Ahmet Demirak 0000-0002-6815-8037

Feyyaz Keskin 0000-0002-2813-994X

Project Number BAP No: 19/081/16/1
Publication Date December 30, 2022
Published in Issue Year 2022 Volume: 19 Issue: 2

Cite

APA Zeynalova, N., Yorulmaz, B., Demirak, A., Keskin, F. (2022). Arıtma Çamuru Küllerinden Kimyasal Ekstraksiyonla Fosfor Geri Kazanımının Araştırılması. Adnan Menderes Üniversitesi Ziraat Fakültesi Dergisi, 19(2), 177-182. https://doi.org/10.25308/aduziraat.1050158
AMA Zeynalova N, Yorulmaz B, Demirak A, Keskin F. Arıtma Çamuru Küllerinden Kimyasal Ekstraksiyonla Fosfor Geri Kazanımının Araştırılması. ADÜ ZİRAAT DERG. December 2022;19(2):177-182. doi:10.25308/aduziraat.1050158
Chicago Zeynalova, Nigar, Bülent Yorulmaz, Ahmet Demirak, and Feyyaz Keskin. “Arıtma Çamuru Küllerinden Kimyasal Ekstraksiyonla Fosfor Geri Kazanımının Araştırılması”. Adnan Menderes Üniversitesi Ziraat Fakültesi Dergisi 19, no. 2 (December 2022): 177-82. https://doi.org/10.25308/aduziraat.1050158.
EndNote Zeynalova N, Yorulmaz B, Demirak A, Keskin F (December 1, 2022) Arıtma Çamuru Küllerinden Kimyasal Ekstraksiyonla Fosfor Geri Kazanımının Araştırılması. Adnan Menderes Üniversitesi Ziraat Fakültesi Dergisi 19 2 177–182.
IEEE N. Zeynalova, B. Yorulmaz, A. Demirak, and F. Keskin, “Arıtma Çamuru Küllerinden Kimyasal Ekstraksiyonla Fosfor Geri Kazanımının Araştırılması”, ADÜ ZİRAAT DERG, vol. 19, no. 2, pp. 177–182, 2022, doi: 10.25308/aduziraat.1050158.
ISNAD Zeynalova, Nigar et al. “Arıtma Çamuru Küllerinden Kimyasal Ekstraksiyonla Fosfor Geri Kazanımının Araştırılması”. Adnan Menderes Üniversitesi Ziraat Fakültesi Dergisi 19/2 (December 2022), 177-182. https://doi.org/10.25308/aduziraat.1050158.
JAMA Zeynalova N, Yorulmaz B, Demirak A, Keskin F. Arıtma Çamuru Küllerinden Kimyasal Ekstraksiyonla Fosfor Geri Kazanımının Araştırılması. ADÜ ZİRAAT DERG. 2022;19:177–182.
MLA Zeynalova, Nigar et al. “Arıtma Çamuru Küllerinden Kimyasal Ekstraksiyonla Fosfor Geri Kazanımının Araştırılması”. Adnan Menderes Üniversitesi Ziraat Fakültesi Dergisi, vol. 19, no. 2, 2022, pp. 177-82, doi:10.25308/aduziraat.1050158.
Vancouver Zeynalova N, Yorulmaz B, Demirak A, Keskin F. Arıtma Çamuru Küllerinden Kimyasal Ekstraksiyonla Fosfor Geri Kazanımının Araştırılması. ADÜ ZİRAAT DERG. 2022;19(2):177-82.