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(2,3-Difenil-1,3-oksazolidin-5-il)metil Metakrilat’ın Metil Metakrilat ile Kopolimerlerinin Sentezi, Karakterizasyonu ve Termal Özellikleri

Year 2012, Volume: 2 Issue: 2, 75 - 86, 01.03.2012

Abstract

Bu çalışmada (2,3-difenil-1,3-oksazolidin-5-il)metil metakrilat (DOMMA), glisidil metakrilat (GMA) ile N-benziliden anilinin SnCl4 katalizörü yanında kondenzasyon reaksiyonu ile sentezlendi. Bu monomerin homopolimerizasyonu ve metil metakrilat monomeri ile kopolimerizasyonu, ?-?'-Azobisizobütironitril (AIBN) başlatıcısı varlığında dioksan çözeltisinde 70 oC’de serbest radikalik yolla gerçekleştirildi. Monomer, homopolimer ve kopolimerlerin karakterizasyonunda FT-IR, 1H-NMR ve 13C-NMR teknikleri kullanıldı. Homopolimer ve kopolimerlerin camsı geçiş sıcaklıkları DSC, termal kararlılıkları TGA ile araştırıldı. Homopolimerin molekül ağırlığı GPC ile belirlendi.

References

  • B. Yactine, A. Ratsimihety, F. Ganachaud, Polym. Adv. Technol., 2010, 21, 139–149.
  • T. Fresvig, P. Ludvigsen, H. Steen, O. Reikeras, Med. Eng. Phys., 2008, 30, 104–108.
  • M. Ishio, T. Terashima, M. Ouchi, M. Sawamoto, Macromolecules., 2010, 43, 920–926.
  • I. Erol, J. Fluorine. Chem., 2008, 129, 613–620.
  • I. Erol, S. Kolu, Journal of Applied Polymer Science., 2011, 120, 279–290.
  • C. Soykan, A. Delibas, R. Coskun, J. Macro. Sci. Part A: Pure and Appl. Chem., 2009, , 250-267.
  • K. B. Kwarteng, SAMPE Quarterly., 1988.
  • S. Parker, M. Braden, Biomaterials., 1989, 10, 91.
  • J. W. Nicholson, P. J. Brookman, O. M. Lacy, G. S. Sayers, A. D. Wilson, J. Biomed. Mater. Res., 1988, 22, 623.
  • J. N. Patel, M. B. Dolia, K. H. Patel, R. M. Patel, J. Polym. Research., 2006, 13, 219
  • K. Ichimura, Y. Nishio, J. Polym. Sci. Part A Polym. Chem., 1987, 25, 1579–1590.
  • P. S. Vijayanand, R. Arun Prasath, R. Balaji, S. Nanjundan, J. Appl. Polym. Sci., 2002, , 2261–2270.
  • P. G. Vijayaraghavan, B. S. R. Reddy, J. Appl. Polym. Sci., 1996, 61, 936–943.
  • C. S. Jone Selvamalar, P. S. Vijayanand, A. Penlidis, S. Nanjundan, J. Appl. Polym. Sci., , 91, 3602–3604.
  • R. Balaji, D. Grande, S. Nanjundan, Polymer., 2004, 45, 1089–1099.
  • S. C. Pandey, N. Rather, A. Singh, J. Polym. Mater., 1999, 16, 253–258.
  • A. Arun, B. S. R. Reddy, Biomaterials., 2005, 26, 1185–1193.
  • M. Johnck, L. Muller, A. Neyer, J. W. Hofstraat, Eur. Polym. J., 2000, 36, 1251–1264.
  • D. L. Rakhmankulov, V. V. Zorin, F. N. Latypova, S. S. Zlot-skii, Khim. Getterotsikl. Soedia., 1982, 4, 435.
  • E. S. Kurmaeva, O. B. Chalova, R. F. Khazipov, D. K. Kıladze, E. A. Kator, D. L. Rakhmankulov, Invertor’s Certificate, No: 1211258 (1983); Syul. Izobr., 1986, 6, 118.
  • D. Bonerjie, S. Mukerjie, N. K. Dutta, B.N Mıtra, Indian J. Chem., 1971, 8, 799-800.
  • D. L. Rakhmankulov, R. A. Karakhanov, S. S. Zlotskii, E. A. Kantor, U. B. Imashev, A. M. Syrkin, Itogi Nauki i Tekhniki, Ser. Tekhnol. Organ. Veshchestv, Moscow: VINITI, 1979, , 287.
  • D. L. Rakhmankulov, V. V. Zorin, E. M. Kuramshin, S. S. Zlotskii, L. N. Zorina, L. G. Sergeeva, V. V. Sherepovets, Methods of Investigation of Reactivity of Organic Compounds.,Ufa:GINTL[Reaktiv], 1999.

Copolymers of (2,3-Diphenyl-1,3-oxazolidin-5-yl)methyl Methacrylate with Methyl Methacrylate: Synthesis, Characterization and Thermal Properties

Year 2012, Volume: 2 Issue: 2, 75 - 86, 01.03.2012

Abstract

In this work, (2,3-diphenyl-1,3-oxazolidin-5-yl)methyl methacrylate(DOMMA) was synthesized by condensation reaction of N-benzyliden aniline with glycidyl methacrylate (GMA) in the presence of SnCl4 as catalyst. Homopolymerization and copolymerization of this monomer with methyl methacrylate were carried out by free radical polymerization in dioxane solution using ?-?'-Azobisisobutyronitrile (AIBN) as initiator at 70 oC. FT-IR, 1H-NMR and 13C-NMR techniques were used in characterization of the monomer, homopolymer and copolymers. The glass transition temperature and thermal stabilities of the homopolymer and the copolymers were investigated by DSC and TGA, respectivelly. The molecular weight of the homopolymer was determined by GPC.

References

  • B. Yactine, A. Ratsimihety, F. Ganachaud, Polym. Adv. Technol., 2010, 21, 139–149.
  • T. Fresvig, P. Ludvigsen, H. Steen, O. Reikeras, Med. Eng. Phys., 2008, 30, 104–108.
  • M. Ishio, T. Terashima, M. Ouchi, M. Sawamoto, Macromolecules., 2010, 43, 920–926.
  • I. Erol, J. Fluorine. Chem., 2008, 129, 613–620.
  • I. Erol, S. Kolu, Journal of Applied Polymer Science., 2011, 120, 279–290.
  • C. Soykan, A. Delibas, R. Coskun, J. Macro. Sci. Part A: Pure and Appl. Chem., 2009, , 250-267.
  • K. B. Kwarteng, SAMPE Quarterly., 1988.
  • S. Parker, M. Braden, Biomaterials., 1989, 10, 91.
  • J. W. Nicholson, P. J. Brookman, O. M. Lacy, G. S. Sayers, A. D. Wilson, J. Biomed. Mater. Res., 1988, 22, 623.
  • J. N. Patel, M. B. Dolia, K. H. Patel, R. M. Patel, J. Polym. Research., 2006, 13, 219
  • K. Ichimura, Y. Nishio, J. Polym. Sci. Part A Polym. Chem., 1987, 25, 1579–1590.
  • P. S. Vijayanand, R. Arun Prasath, R. Balaji, S. Nanjundan, J. Appl. Polym. Sci., 2002, , 2261–2270.
  • P. G. Vijayaraghavan, B. S. R. Reddy, J. Appl. Polym. Sci., 1996, 61, 936–943.
  • C. S. Jone Selvamalar, P. S. Vijayanand, A. Penlidis, S. Nanjundan, J. Appl. Polym. Sci., , 91, 3602–3604.
  • R. Balaji, D. Grande, S. Nanjundan, Polymer., 2004, 45, 1089–1099.
  • S. C. Pandey, N. Rather, A. Singh, J. Polym. Mater., 1999, 16, 253–258.
  • A. Arun, B. S. R. Reddy, Biomaterials., 2005, 26, 1185–1193.
  • M. Johnck, L. Muller, A. Neyer, J. W. Hofstraat, Eur. Polym. J., 2000, 36, 1251–1264.
  • D. L. Rakhmankulov, V. V. Zorin, F. N. Latypova, S. S. Zlot-skii, Khim. Getterotsikl. Soedia., 1982, 4, 435.
  • E. S. Kurmaeva, O. B. Chalova, R. F. Khazipov, D. K. Kıladze, E. A. Kator, D. L. Rakhmankulov, Invertor’s Certificate, No: 1211258 (1983); Syul. Izobr., 1986, 6, 118.
  • D. Bonerjie, S. Mukerjie, N. K. Dutta, B.N Mıtra, Indian J. Chem., 1971, 8, 799-800.
  • D. L. Rakhmankulov, R. A. Karakhanov, S. S. Zlotskii, E. A. Kantor, U. B. Imashev, A. M. Syrkin, Itogi Nauki i Tekhniki, Ser. Tekhnol. Organ. Veshchestv, Moscow: VINITI, 1979, , 287.
  • D. L. Rakhmankulov, V. V. Zorin, E. M. Kuramshin, S. S. Zlotskii, L. N. Zorina, L. G. Sergeeva, V. V. Sherepovets, Methods of Investigation of Reactivity of Organic Compounds.,Ufa:GINTL[Reaktiv], 1999.
There are 23 citations in total.

Details

Primary Language Turkish
Journal Section Research Articles
Authors

Gamze Barım This is me

Mehmet Coşkun This is me

Publication Date March 1, 2012
Published in Issue Year 2012 Volume: 2 Issue: 2

Cite

APA Barım, G., & Coşkun, M. (2012). (2,3-Difenil-1,3-oksazolidin-5-il)metil Metakrilat’ın Metil Metakrilat ile Kopolimerlerinin Sentezi, Karakterizasyonu ve Termal Özellikleri. Adıyaman University Journal of Educational Sciences, 2(2), 75-86.

                                                                                                                                                                                                                                                      
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