The Synthesis of Urea, Thiourea and Selenourea Derivatives of Tetraaminoalkenes Bearing Substituted Benzyl Group
Abstract
Tetraaminoalkenes were obtained by the reaction of 1,2-dialkylaminoethanes with N,N-dimethylformamide dimethylacetal. Urea, thiourea and selenourea compounds were synthesized by the reaction of tetraaminoalkenes with oxygen, sulfur or selenium in toluene. The structure of all compounds synthesized were determined by using spectroscopic techniques such as 1H-NMR, 13C-NMR, IR and elemental analyses.
References
- R. W. Hoffmann, Angew. Chem. Int. Ed. Engl.,1968, 7, 754.
- N. Wiberg, Angew. Chem. Int. Ed. Engl.,1968, 7, 766.
- E. Çetinkaya, Doğa Türk Kimya Dergisi, 1988, 12, 31.
- H. E. Winberg, J. E. Carnahan, D. D. Coffman, M. Brown, J. Am. Chem. Soc., 1965, 87,
- M. D. Lemal, K. I. Kawano, J. Am. Chem. Soc., 1962, 1761.
- E. Çetinkaya, P. B. Hitchcock, H. A. Jasim, M. F. Lappert, K. Sypropoulos, J. Chem. Soc. Perkin Trans., 1992, 1, 561.
- J. Hocker, R. Merten, Angew. Chem. Int. Ed. Engl., 1972, 11, 964.
- H. W. Wanzlick, A. Ahrens, Chem. Ber., 1964, 97, 2447.
- M. F. Lappert, R. K. Maskell, J. Chem. Soc., Chem. Commun., 1982, 580.
- D. M. Lemal, A. R. Lovald, K. I. Kawano, J. Am. Chem. Soc., 1969, 86, 2518.
- F. Roeterdink, J. W. Scheeren, W. H. Laarhoven, Tetrahedron Lett., 1983, 24, 2307.
- B. Çetinkaya, A. Hudson, M. F. Lappert, H. Goldwhite, J. Chem. Soc., Chem. Commun., , 609. M. F. Lappert, R. K. Maskell, J. Organomet. Chem., 1984, 264, 217.
- B. Alıcı, E. Çetinkaya, B. Çetinkaya, D. Ülkü, M. N. Tahir, J. Chem. Research, 1996,
- B. Çetinkaya, E. Çetinkaya, H. Küçükbay, R. Durmaz, Arzneim. Forsch. / Drug. Res., , 46, 1154.
Abstract
1,2-Dialkilaminoetanların N,N-dimetilformamit dimetilasetal ile reaksiyonu sonucu tetraaminoalkenler elde edildi. Tetraaminoalkenlerin toluen içerisinde oksijen, kükürt veya selenyum ile etkileştirilmesiyle üre, tiyoüre ve selenoüre bileşikleri sentezlendi. Sentezlenen bütün bileşiklerin yapıları 1H-NMR, 13C-NMR, IR gibi spektroskopik teknikler ve element analizi ile belirlendi.
References
- R. W. Hoffmann, Angew. Chem. Int. Ed. Engl.,1968, 7, 754.
- N. Wiberg, Angew. Chem. Int. Ed. Engl.,1968, 7, 766.
- E. Çetinkaya, Doğa Türk Kimya Dergisi, 1988, 12, 31.
- H. E. Winberg, J. E. Carnahan, D. D. Coffman, M. Brown, J. Am. Chem. Soc., 1965, 87,
- M. D. Lemal, K. I. Kawano, J. Am. Chem. Soc., 1962, 1761.
- E. Çetinkaya, P. B. Hitchcock, H. A. Jasim, M. F. Lappert, K. Sypropoulos, J. Chem. Soc. Perkin Trans., 1992, 1, 561.
- J. Hocker, R. Merten, Angew. Chem. Int. Ed. Engl., 1972, 11, 964.
- H. W. Wanzlick, A. Ahrens, Chem. Ber., 1964, 97, 2447.
- M. F. Lappert, R. K. Maskell, J. Chem. Soc., Chem. Commun., 1982, 580.
- D. M. Lemal, A. R. Lovald, K. I. Kawano, J. Am. Chem. Soc., 1969, 86, 2518.
- F. Roeterdink, J. W. Scheeren, W. H. Laarhoven, Tetrahedron Lett., 1983, 24, 2307.
- B. Çetinkaya, A. Hudson, M. F. Lappert, H. Goldwhite, J. Chem. Soc., Chem. Commun., , 609. M. F. Lappert, R. K. Maskell, J. Organomet. Chem., 1984, 264, 217.
- B. Alıcı, E. Çetinkaya, B. Çetinkaya, D. Ülkü, M. N. Tahir, J. Chem. Research, 1996,
- B. Çetinkaya, E. Çetinkaya, H. Küçükbay, R. Durmaz, Arzneim. Forsch. / Drug. Res., , 46, 1154.
Details
| Primary Language | Turkish |
|---|---|
| Journal Section | Research Articles |
| Authors | |
| Publication Date | February 1, 2012 |
| Published in Issue | Year 2012 Volume: 2 Issue: 1 |
