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Year 2015, Volume: 2 Issue: 2, 1 - 10, 23.01.2015

Şeyda Taşar Şeyma Yüksel Nebihe Tunçel Ramazan Orhan

Abstract

In this study, hydrogels and clay composite polymeric gel were synthesized by using AAm monomer and clay, EGDM as a crosslinker and APS-TEMED as initiator-activator system. The swelling properties of the hydrogels, water absorption (swelling) and shrinking (deswelling) kinetics, the equilibrium swelling ratios in water were investigated. In distilled water, swelling kinetics at 25 °C, deswelling kinetics at 80 °C and swelling behaviour at different temperatures of synthesized hydrogels were determined by gravimetric methods. Then, their adsorption properties such as adsorption capacities and adsorption efficiency of synthesized hydrogel and clay composit polymeric gel were investigated in case of their usage in removal of Astrazon Yellow (AY), Astrazon Golden Yellow (AGY), basic Blue 3 (BB3) aqueous solutions at 25 °C. At equilibrium the swelling values and the diffusion coefficient of AAM based clay composit polymeric gel was determined to be significantly decreased compared to AAm based hydrogel. It was determined that adsorption capacity and removal percentage for three dyes of clay composit polymeric gel was higher

Keywords

Acrylamide dye material adsorption hydrogel

References

  • Gong RM, Li M, Yang C, Sun YZ, Chen J. Removal of cationic dyes from aqueous solution by adsorption on peanut hull. J Hazard Mater 2005; 121: 247-250.
  • Aksakal O, Ucun H. Equilibrium, kinetic and thermodynamic studies of the biosorption of textile dye (Reactive Red 195) onto Pinus sylvestris L. J Hazard Mater 2010; 181: 666-672.
  • Dizge N, Aydiner C, Demirbas E, Kobya M, Kara S. Adsorption of reactive dyes from aqueous solutions by fly ash: Kinetic and equilibrium studies. J Hazard Mater 2008; 150:737-746.
  • Dulman V, Cucu-Man SM. Sorption of some textile dyes by beech wood sawdust. J Hazard Mater 2009; 162: 1457-1464.
  • Annadurai G. Ling, LY, Lee J.F. Adsorption of reactive dye from an aqueous solution by chitosan: isotherm, kinetic and thermodynamic analysis. Journal of Hazardous Materials 2008; 152: 337-346.
  • Turgay O, Ersoz G, Atalay S, Forss J, Welander U. The treatment of azo dyes found in textile industry wastewater by anaerobic biological method and chemical oxidation. Sep Purif Technol 2011; 79: 26-33.
  • Kim TH, Park C, Kim S. Water recycling from desalination and purification process of reactive dye manufacturing industry by combined membrane filtration. J Clean Prod 2005; 13: 779-786.
  • Moghaddam SS, Moghaddam MRA, Arami M. Coagulation/flocculation process for dye removal using sludge from water treatment plant: Optimization through response surface methodology. J Hazard Mater 2010; 175: 651-657.
  • Nataraj SK, Hosamani KM, Aminabhavi TM. Nanofiltration and reverse osmosis thin film composite membrane module for the removal of dye and salts from the simulated mixtures. Desalination 2009; 249: 12-17.
  • Selen V, Özer D. Reactive Blue 19 Boyarmaddesinin Sulu Çözeltilerden Uzaklaştırılması, Fırat Univ. Journal of Science 2012; 24(2): 63-75.
  • Amin NK. Removal of reactive dye from aqueous solutions by adsorption onto activated carbons prepared from sugarcane bagasse pith. Desalination 2008; 223: 152-161.
  • Öz M. Sıcaklığa duyarlı poli(N-izopropil akrilamid) kopolimerinin sentezi, Yüksek Lisans Tezi. İstanbul: İstanbul Üniversitesi; 2005.
  • Üzüm BÖ. Yeni Akrilamid esaslı anyonik IPN’lerin sentezi, karakterizasyonu ve şişme/soğurum/denetimli salınım potansiyellerinin araştırılması. Doktora Tezi. Aydın: Adnan Menderes Üniversitesi; 2008.
  • Şenkal F, Gürsel Y, Saraç A, Kandaz MEY. Tekstil boyalarının giderilmesi için yeni polimer ve reaktiflerin geliştirilmesi, Tübitak Projesi, Proje No: 106T406, 2009.
  • Saraydın D, Karadağ E, Güven O. Adsorption of some heavy metal ions in aqueous solutions by acrylamide/maleic acid hydrogels. Sep.Sci. Tech. 1995; 30 (17): 3291-3302.
  • Pan G, Kurumada KI, Yamada Y, Application of hydrogel for the removal of pollutant phenol in water. Journal of the Chinese Institute of Chemical Engineers 2008; 39: 361-366.
  • Karadağ E, Saraydın D, Güven O. Behaviors of acrylamide itaconic acid hydrogels in uptake of uranyl ions from aqueous solutions. Sep. Sci. Tech. 1995; 30 (20): 3747-3760.
  • Duran S, Şolpan D, Güven O. Synthesis and characterization of acrylamide–acrylic acid hydrogels and adsorption of some textile dyes. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 1999; 151(1–4): 196–199.
  • Can HK, Kirci B, Kavlak S, Guner A. Removal of some textile dyes from aqueous solutions by poly(N-vinyl-2-pyrrolidone) and poly(N-vinyl-2-pyrrolidone)/K2S2O8 hydrogels. Radiation Physics and Chemistry 2003; 68: 811.
  • Dadhaniya PV, Patel MP, Patel RG. Removal of anionic dyes from aqueous solution using poly [N-vinyl pyrrolidone/2-(methacryloyloxyethyl) trimethyl ammonium chloride] superswelling hydrogels. Polym. Bull. 2007; 58: 359–369.
  • Kaşgöz H. New sorbent hydrogels for removal of acidic dyes and metal ions from aqueous solutions. Polym. Bull 2006; 56: 517–528.
  • Sezgin O. Metakrilamid Tabanlı Hidrojel Matrislerin Sentez ve Karakterizasyonu, Yüksek Lisans Tezi. Eskişehir: Osmangazi Üniversitesi; 2007.
  • Penıche C, Cohen ME, Vázquez B, Román JS. Water Sorption of Flexible Networks Based on 2-Hydroxyethyl Methacrylate-Triethylenglycol Dimethacrylate Copolymers. Polymer 1996; 38(24): 5977-5982.
  • Vallés E, Durando D, Katıme I, Mendızábal E, Puıg JE. Equilibrium Swelling And Mechanical Properties of Hydrogels of Acrylamide And Itaconic Acid or its Esters, Polymer Bulletin 2000; 44:109-114.
  • Saraydın D, Karadağ E, Isıkver Y, Sah N, Güven O. The Influence of Preparation Methods on The Swelling and Network Properties of Acrylamide Hydrogels With Crosslinkers. Pure and Applied Chemistry 2004; A41(4): 421-433.
  • Ende MT, Peppas NA, Transport of Ionizable Drugs And Proteins İn Crosslinked Poly(Acrylic Acid) And Poly(Acrylic Acid-Co-2-Hydroxyethyl Methacrylate) Hydrogels, I. Polymer Characterization. Journal of Applied Polymer Science 1996; 59: 673-685.
  • Ende MT, Peppas NA. Transport of Ionizable Drugs and Proteins in Crosslinked Poly(Acrylic Acid) And Poly(Acrylic Acid-Co-2-Hydroxyethyl Methacrylate) Hydrogels. II. Diffusion and Release Studies. Journal of Controlled Release 1997; 48: 47-56.
  • Peppas NA, Franson NM. The Swelling Interface Number as a Criterion For Prediction of Diffusional Solute Release Mechanisms in Swellable Polymers. Polymer Physics Edition 1983; 21: 983-997.
  • Dengre V, Bajpaı M, Bajpaı SK. Release of Vitamin B12 From Poly(N-Vinyl-2-Pyrrolidone)-Crosslinked Polyacrylamide Hydrogels: A Kinetic Study. Journal of Applied Polymer Science 2000; 76: 1706-1714.

Akrilamid Esaslı Jel ve Kompozit Polimerik Jel Sentezi, Şişme-Büzülme Karakterizasyonunun incelenmesi ve Atık Sulardan Boyar Maddelerin Giderimi Üzerine Bir Çalışma

Year 2015, Volume: 2 Issue: 2, 1 - 10, 23.01.2015

Şeyda Taşar Şeyma Yüksel Nebihe Tunçel Ramazan Orhan

Abstract

Bu çalışmada; Akrilamid monomeri ve kil ile çapraz bağlayıcı (EGDM), başlatıcı-hızlandırıcı sistemi (APS-TEMED) kullanılarak  hidrojel ve kompozit polimerik jeller sentezlenmiştir.  Hidrojellerin su absorpsiyon (şişme)- desoprsiyon (büzülme) kinetikleri, sudaki denge şişme değerleri ve sıcaklıkla denge şişme oranındaki değişim incelenmiştir. Sentezlenen jellerin destile su içinde 25 °C’de şişme kinetikleri, 80 °C’de büzülme kinetikleri gravimetrik metodla belirlenmiştir. Sentezlenen hidrojel ve kil polimer kompozit jelin 25 °C’de Astrazon Yellow (AY), Astrazon Golden Yellow (AGY) ve Bazik Blue 3 (BB3) boyar moddelerini içeren sulu çözeltiler kullanılarak, adsorpsiyon verimleri ve adsorpsiyon kapasiteleri gibi boyar madde giderim verimleri belirlenmiş ve bu sonuçlar birbirleri ile karşılaştırılmıştır

Keywords

Akrilamid; boyar madde; adsorpsiyon hidrojel

References

  • Gong RM, Li M, Yang C, Sun YZ, Chen J. Removal of cationic dyes from aqueous solution by adsorption on peanut hull. J Hazard Mater 2005; 121: 247-250.
  • Aksakal O, Ucun H. Equilibrium, kinetic and thermodynamic studies of the biosorption of textile dye (Reactive Red 195) onto Pinus sylvestris L. J Hazard Mater 2010; 181: 666-672.
  • Dizge N, Aydiner C, Demirbas E, Kobya M, Kara S. Adsorption of reactive dyes from aqueous solutions by fly ash: Kinetic and equilibrium studies. J Hazard Mater 2008; 150:737-746.
  • Dulman V, Cucu-Man SM. Sorption of some textile dyes by beech wood sawdust. J Hazard Mater 2009; 162: 1457-1464.
  • Annadurai G. Ling, LY, Lee J.F. Adsorption of reactive dye from an aqueous solution by chitosan: isotherm, kinetic and thermodynamic analysis. Journal of Hazardous Materials 2008; 152: 337-346.
  • Turgay O, Ersoz G, Atalay S, Forss J, Welander U. The treatment of azo dyes found in textile industry wastewater by anaerobic biological method and chemical oxidation. Sep Purif Technol 2011; 79: 26-33.
  • Kim TH, Park C, Kim S. Water recycling from desalination and purification process of reactive dye manufacturing industry by combined membrane filtration. J Clean Prod 2005; 13: 779-786.
  • Moghaddam SS, Moghaddam MRA, Arami M. Coagulation/flocculation process for dye removal using sludge from water treatment plant: Optimization through response surface methodology. J Hazard Mater 2010; 175: 651-657.
  • Nataraj SK, Hosamani KM, Aminabhavi TM. Nanofiltration and reverse osmosis thin film composite membrane module for the removal of dye and salts from the simulated mixtures. Desalination 2009; 249: 12-17.
  • Selen V, Özer D. Reactive Blue 19 Boyarmaddesinin Sulu Çözeltilerden Uzaklaştırılması, Fırat Univ. Journal of Science 2012; 24(2): 63-75.
  • Amin NK. Removal of reactive dye from aqueous solutions by adsorption onto activated carbons prepared from sugarcane bagasse pith. Desalination 2008; 223: 152-161.
  • Öz M. Sıcaklığa duyarlı poli(N-izopropil akrilamid) kopolimerinin sentezi, Yüksek Lisans Tezi. İstanbul: İstanbul Üniversitesi; 2005.
  • Üzüm BÖ. Yeni Akrilamid esaslı anyonik IPN’lerin sentezi, karakterizasyonu ve şişme/soğurum/denetimli salınım potansiyellerinin araştırılması. Doktora Tezi. Aydın: Adnan Menderes Üniversitesi; 2008.
  • Şenkal F, Gürsel Y, Saraç A, Kandaz MEY. Tekstil boyalarının giderilmesi için yeni polimer ve reaktiflerin geliştirilmesi, Tübitak Projesi, Proje No: 106T406, 2009.
  • Saraydın D, Karadağ E, Güven O. Adsorption of some heavy metal ions in aqueous solutions by acrylamide/maleic acid hydrogels. Sep.Sci. Tech. 1995; 30 (17): 3291-3302.
  • Pan G, Kurumada KI, Yamada Y, Application of hydrogel for the removal of pollutant phenol in water. Journal of the Chinese Institute of Chemical Engineers 2008; 39: 361-366.
  • Karadağ E, Saraydın D, Güven O. Behaviors of acrylamide itaconic acid hydrogels in uptake of uranyl ions from aqueous solutions. Sep. Sci. Tech. 1995; 30 (20): 3747-3760.
  • Duran S, Şolpan D, Güven O. Synthesis and characterization of acrylamide–acrylic acid hydrogels and adsorption of some textile dyes. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 1999; 151(1–4): 196–199.
  • Can HK, Kirci B, Kavlak S, Guner A. Removal of some textile dyes from aqueous solutions by poly(N-vinyl-2-pyrrolidone) and poly(N-vinyl-2-pyrrolidone)/K2S2O8 hydrogels. Radiation Physics and Chemistry 2003; 68: 811.
  • Dadhaniya PV, Patel MP, Patel RG. Removal of anionic dyes from aqueous solution using poly [N-vinyl pyrrolidone/2-(methacryloyloxyethyl) trimethyl ammonium chloride] superswelling hydrogels. Polym. Bull. 2007; 58: 359–369.
  • Kaşgöz H. New sorbent hydrogels for removal of acidic dyes and metal ions from aqueous solutions. Polym. Bull 2006; 56: 517–528.
  • Sezgin O. Metakrilamid Tabanlı Hidrojel Matrislerin Sentez ve Karakterizasyonu, Yüksek Lisans Tezi. Eskişehir: Osmangazi Üniversitesi; 2007.
  • Penıche C, Cohen ME, Vázquez B, Román JS. Water Sorption of Flexible Networks Based on 2-Hydroxyethyl Methacrylate-Triethylenglycol Dimethacrylate Copolymers. Polymer 1996; 38(24): 5977-5982.
  • Vallés E, Durando D, Katıme I, Mendızábal E, Puıg JE. Equilibrium Swelling And Mechanical Properties of Hydrogels of Acrylamide And Itaconic Acid or its Esters, Polymer Bulletin 2000; 44:109-114.
  • Saraydın D, Karadağ E, Isıkver Y, Sah N, Güven O. The Influence of Preparation Methods on The Swelling and Network Properties of Acrylamide Hydrogels With Crosslinkers. Pure and Applied Chemistry 2004; A41(4): 421-433.
  • Ende MT, Peppas NA, Transport of Ionizable Drugs And Proteins İn Crosslinked Poly(Acrylic Acid) And Poly(Acrylic Acid-Co-2-Hydroxyethyl Methacrylate) Hydrogels, I. Polymer Characterization. Journal of Applied Polymer Science 1996; 59: 673-685.
  • Ende MT, Peppas NA. Transport of Ionizable Drugs and Proteins in Crosslinked Poly(Acrylic Acid) And Poly(Acrylic Acid-Co-2-Hydroxyethyl Methacrylate) Hydrogels. II. Diffusion and Release Studies. Journal of Controlled Release 1997; 48: 47-56.
  • Peppas NA, Franson NM. The Swelling Interface Number as a Criterion For Prediction of Diffusional Solute Release Mechanisms in Swellable Polymers. Polymer Physics Edition 1983; 21: 983-997.
  • Dengre V, Bajpaı M, Bajpaı SK. Release of Vitamin B12 From Poly(N-Vinyl-2-Pyrrolidone)-Crosslinked Polyacrylamide Hydrogels: A Kinetic Study. Journal of Applied Polymer Science 2000; 76: 1706-1714.
There are 29 citations in total.

Details

Primary Language Turkish
Journal Section Makaleler
Authors

Şeyda Taşar This is me

Şeyma Yüksel This is me

Nebihe Tunçel This is me

Ramazan Orhan

Publication Date January 23, 2015
Submission Date January 23, 2015
Published in Issue Year 2015 Volume: 2 Issue: 2

Cite

APA Taşar, Ş., Yüksel, Ş., Tunçel, N., Orhan, R. (2015). Akrilamid Esaslı Jel ve Kompozit Polimerik Jel Sentezi, Şişme-Büzülme Karakterizasyonunun incelenmesi ve Atık Sulardan Boyar Maddelerin Giderimi Üzerine Bir Çalışma. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi, 2(2), 1-10.
AMA Taşar Ş, Yüksel Ş, Tunçel N, Orhan R. Akrilamid Esaslı Jel ve Kompozit Polimerik Jel Sentezi, Şişme-Büzülme Karakterizasyonunun incelenmesi ve Atık Sulardan Boyar Maddelerin Giderimi Üzerine Bir Çalışma. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi. March 2015;2(2):1-10.
Chicago Taşar, Şeyda, Şeyma Yüksel, Nebihe Tunçel, and Ramazan Orhan. “Akrilamid Esaslı Jel Ve Kompozit Polimerik Jel Sentezi, Şişme-Büzülme Karakterizasyonunun Incelenmesi Ve Atık Sulardan Boyar Maddelerin Giderimi Üzerine Bir Çalışma”. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi 2, no. 2 (March 2015): 1-10.
EndNote Taşar Ş, Yüksel Ş, Tunçel N, Orhan R (March 1, 2015) Akrilamid Esaslı Jel ve Kompozit Polimerik Jel Sentezi, Şişme-Büzülme Karakterizasyonunun incelenmesi ve Atık Sulardan Boyar Maddelerin Giderimi Üzerine Bir Çalışma. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi 2 2 1–10.
IEEE Ş. Taşar, Ş. Yüksel, N. Tunçel, and R. Orhan, “Akrilamid Esaslı Jel ve Kompozit Polimerik Jel Sentezi, Şişme-Büzülme Karakterizasyonunun incelenmesi ve Atık Sulardan Boyar Maddelerin Giderimi Üzerine Bir Çalışma”, Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi, vol. 2, no. 2, pp. 1–10, 2015.
ISNAD Taşar, Şeyda et al. “Akrilamid Esaslı Jel Ve Kompozit Polimerik Jel Sentezi, Şişme-Büzülme Karakterizasyonunun Incelenmesi Ve Atık Sulardan Boyar Maddelerin Giderimi Üzerine Bir Çalışma”. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi 2/2 (March 2015), 1-10.
JAMA Taşar Ş, Yüksel Ş, Tunçel N, Orhan R. Akrilamid Esaslı Jel ve Kompozit Polimerik Jel Sentezi, Şişme-Büzülme Karakterizasyonunun incelenmesi ve Atık Sulardan Boyar Maddelerin Giderimi Üzerine Bir Çalışma. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi. 2015;2:1–10.
MLA Taşar, Şeyda et al. “Akrilamid Esaslı Jel Ve Kompozit Polimerik Jel Sentezi, Şişme-Büzülme Karakterizasyonunun Incelenmesi Ve Atık Sulardan Boyar Maddelerin Giderimi Üzerine Bir Çalışma”. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi, vol. 2, no. 2, 2015, pp. 1-10.
Vancouver Taşar Ş, Yüksel Ş, Tunçel N, Orhan R. Akrilamid Esaslı Jel ve Kompozit Polimerik Jel Sentezi, Şişme-Büzülme Karakterizasyonunun incelenmesi ve Atık Sulardan Boyar Maddelerin Giderimi Üzerine Bir Çalışma. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi. 2015;2(2):1-10.