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Sulu Çözeltilerden Lewatit S-108 Katyon Değişim Reçinesiyle Bakır İyonlarının Adsorpsiyonu

Year 2016, Volume: 3 Issue: 5, 77 - 87, 06.12.2016

Emir Tosun , Mehmet Kayra Tanaydın Gülistan Deniz Turhan Özdemir , Nizamettin Demirkıran

Abstract

Bu çalışmada, Lewatit S-108 katyon değişim reçinesi kullanılarak bakır iyonlarının adsorpsiyonu incelenmiştir. Adsorpsiyon prosesi üzerine bakır iyonlarının başlangıç derişimi, çözeltinin başlangıç pH değeri, reçine miktarı, temas süresi ve karıştırma hızının etkileri çalışılmıştır. Reçine miktarı arttığı zaman adsorplanan bakır miktarının arttığı belirlenmiştir. En fazla adsorpsiyonun doğal pH değerlerinde meydana geldiği gözlenmiştir. Çözelti başlangıç derişimi, başlangıç pH değeri, temas süresi, karıştırma hızı ve reçine miktarı sırasıyla 0.005 mol/L, doğal (5.15), 90 dk, 250 rpm ve 6 g/L iken bakır adsorpsiyon verimi % 99.5 olarak gerçekleşmiştir. Adsorpsiyon prosesiyle ilgili izoterm ve kinetik analiz yapılmıştır. Denge verilerinin Langmuir izoterm modeline uyduğu ve prosesin kinetiğinin yalancı ikinci mertebe kinetik model ile tanımlanabileceği belirlenmiştir.

References

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  • Rafatullah M, Sulaiman O, Hashim R, Ahmad A. Adsorption of methylene blue on low cost adsorbent: A review. Journal of Hazardous Materials 2010: 177: 70-80.
  • Liu D, Sun D, Li Y. Removal of Cu(II) and Cd(II) from aqueous solutions by polyaniline on sawdust. Separation Science and Technology 2011: 46: 321-329.
  • Sharma YC, Uma Upadhyay SN. An economically viable removal of methylene blue by adsorption on activated carbon prepared from rice husk. Canadian Journal of Chemical Engineering 2011: 89: 377-383.
  • Dave PN, Subrahmanyam N, Sharma S. Kinetics and thermodynamics of copper ions removal from aqueous solution by use of activated charcoal. Indian Journal of Chemical Technology 2009: 16: 234-239.
  • Nguyen NV, Lee JC, Jha MK, Yoo K,. Jeong J. Copper recovery from low concentration waste solution using Dowex G-26 resin. Hydrometallurgy 2009: 97: 237-242.
  • Caprarescu S, Purcar V, Sarbu A, Radu AL, Ghiurea M, Maior I. The use of electrodialysis for Cu2+ removal from wastewater. Revue Roumaine de Chimie 2014: 59: 639-644.
  • Lee IH, Kuan YC, Chern JM. Equilibrium and kinetics of heavy metal ion exchange. Journal of Chinese Institute of Chemical Engineers 2007: 38: 71–84.
  • Rengaraj S, Yeon JW, Kim Y, Jung Y, Ha YK, Kim WH. Adsorption characteristics of Cu(II) onto ion exchange resins 252H and 1500H: Kinetics, isotherms and error analysis. Journal of Hazardous Materials 2007: 143: 469-477.
  • Xiong CH, Feng YJ, Yao CP, Shen C. Removal of Co(II) from aqueous solutions by NKC-9 strong acid resin. Transactions of Nonferrous Metals Society of China 2010: 20: 1141–1147.
  • Rengaraj S, Kim Y, Joo CK, Choi K, Yi J. Batch adsorptive removal of copper ions in aqueous solutions by ion exchange resins: 1200H and IRN97H. Korean Journal of Chemical Engineering 2004: 21: 187-194.
  • Fil BA, Boncukoğlu R, Yılmaz AE, Bayar S. Adsorption of Ni(II) on ion exchange resin: Kinetics, equilibrium and thermodynamic studies. Korean Journal of Chemical Engineering 2012: 29: 1232-1238.
  • Rengaraj S, Joo CK, Kim Y, Yi J. Kinetics of removal of chromium from water and electronic process wastewater by ion exchange resins: 1200H, 1500H and IRN97H. Journal of Hazardous Materials 2003: 102: 257-275.
  • Zhang Y, Yu X, Wang Q, Jiang Z, Fang T. Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution. Chinese Journal of Chemical Engineering 2015: 23: 646-651.
  • Wang F, Wang LJ, Li JS, Sun XY, Han WG. Adsorption behavior and mechanism of cadmium on strong-acid cation exchange resin. Transactions of Nonferrous Metals Society of China 2009: 19: 740-744.
  • Li X, Yao C, Xiong C, Li J. Adsorption of Pb(II) in Aqueous Solution on SQD-85 Resin. Asian Journal of Chemistry 2011: 23: 3387-3392.
  • http://lanxess.in/en/industries-products-india/industries-india/water-treatment-india/lewatit-m-s-108-india/
  • Shojaeimehr T, Rahimpour F, Khadivi MA, Sadeghi M. A modeling study by response surface methodology (RSM) and artificial neural network (ANN) on Cu2+ adsorption optimization using light expended clay aggregate (LECA). Journal of Industrial and Engineering Chemistry 2014: 20: 870-880.
  • Wang LH, Lin C, Wu FC. Kinetic study of adsorption of copper (II) ion from solution using rice hull ash. Journal of Taiwan Institute Chemical Engineers 2010: 41: 599-605

Year 2016, Volume: 3 Issue: 5, 77 - 87, 06.12.2016

Emir Tosun , Mehmet Kayra Tanaydın Gülistan Deniz Turhan Özdemir , Nizamettin Demirkıran

Abstract

References

  • Deliyanni EA, Lazaridis NK, Peleka EN, Matis KA. Metal removal from aqueous solution by iron-based bonding agents. Environmental Science and Pollution Research 2004: 11: 18-21.
  • Rafatullah M, Sulaiman O, Hashim R, Ahmad A. Adsorption of methylene blue on low cost adsorbent: A review. Journal of Hazardous Materials 2010: 177: 70-80.
  • Liu D, Sun D, Li Y. Removal of Cu(II) and Cd(II) from aqueous solutions by polyaniline on sawdust. Separation Science and Technology 2011: 46: 321-329.
  • Sharma YC, Uma Upadhyay SN. An economically viable removal of methylene blue by adsorption on activated carbon prepared from rice husk. Canadian Journal of Chemical Engineering 2011: 89: 377-383.
  • Dave PN, Subrahmanyam N, Sharma S. Kinetics and thermodynamics of copper ions removal from aqueous solution by use of activated charcoal. Indian Journal of Chemical Technology 2009: 16: 234-239.
  • Nguyen NV, Lee JC, Jha MK, Yoo K,. Jeong J. Copper recovery from low concentration waste solution using Dowex G-26 resin. Hydrometallurgy 2009: 97: 237-242.
  • Caprarescu S, Purcar V, Sarbu A, Radu AL, Ghiurea M, Maior I. The use of electrodialysis for Cu2+ removal from wastewater. Revue Roumaine de Chimie 2014: 59: 639-644.
  • Lee IH, Kuan YC, Chern JM. Equilibrium and kinetics of heavy metal ion exchange. Journal of Chinese Institute of Chemical Engineers 2007: 38: 71–84.
  • Rengaraj S, Yeon JW, Kim Y, Jung Y, Ha YK, Kim WH. Adsorption characteristics of Cu(II) onto ion exchange resins 252H and 1500H: Kinetics, isotherms and error analysis. Journal of Hazardous Materials 2007: 143: 469-477.
  • Xiong CH, Feng YJ, Yao CP, Shen C. Removal of Co(II) from aqueous solutions by NKC-9 strong acid resin. Transactions of Nonferrous Metals Society of China 2010: 20: 1141–1147.
  • Rengaraj S, Kim Y, Joo CK, Choi K, Yi J. Batch adsorptive removal of copper ions in aqueous solutions by ion exchange resins: 1200H and IRN97H. Korean Journal of Chemical Engineering 2004: 21: 187-194.
  • Fil BA, Boncukoğlu R, Yılmaz AE, Bayar S. Adsorption of Ni(II) on ion exchange resin: Kinetics, equilibrium and thermodynamic studies. Korean Journal of Chemical Engineering 2012: 29: 1232-1238.
  • Rengaraj S, Joo CK, Kim Y, Yi J. Kinetics of removal of chromium from water and electronic process wastewater by ion exchange resins: 1200H, 1500H and IRN97H. Journal of Hazardous Materials 2003: 102: 257-275.
  • Zhang Y, Yu X, Wang Q, Jiang Z, Fang T. Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution. Chinese Journal of Chemical Engineering 2015: 23: 646-651.
  • Wang F, Wang LJ, Li JS, Sun XY, Han WG. Adsorption behavior and mechanism of cadmium on strong-acid cation exchange resin. Transactions of Nonferrous Metals Society of China 2009: 19: 740-744.
  • Li X, Yao C, Xiong C, Li J. Adsorption of Pb(II) in Aqueous Solution on SQD-85 Resin. Asian Journal of Chemistry 2011: 23: 3387-3392.
  • http://lanxess.in/en/industries-products-india/industries-india/water-treatment-india/lewatit-m-s-108-india/
  • Shojaeimehr T, Rahimpour F, Khadivi MA, Sadeghi M. A modeling study by response surface methodology (RSM) and artificial neural network (ANN) on Cu2+ adsorption optimization using light expended clay aggregate (LECA). Journal of Industrial and Engineering Chemistry 2014: 20: 870-880.
  • Wang LH, Lin C, Wu FC. Kinetic study of adsorption of copper (II) ion from solution using rice hull ash. Journal of Taiwan Institute Chemical Engineers 2010: 41: 599-605
There are 19 citations in total.

Details

Journal Section Makaleler
Authors

Emir Tosun

Mehmet Kayra Tanaydın This is me

Gülistan Deniz Turhan Özdemir

Nizamettin Demirkıran

Publication Date December 6, 2016
Submission Date September 12, 2016
Published in Issue Year 2016 Volume: 3 Issue: 5

Cite

APA Tosun, E., Tanaydın, M. K., Turhan Özdemir, G. D., Demirkıran, N. (2016). Sulu Çözeltilerden Lewatit S-108 Katyon Değişim Reçinesiyle Bakır İyonlarının Adsorpsiyonu. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi, 3(5), 77-87.
AMA Tosun E, Tanaydın MK, Turhan Özdemir GD, Demirkıran N. Sulu Çözeltilerden Lewatit S-108 Katyon Değişim Reçinesiyle Bakır İyonlarının Adsorpsiyonu. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi. December 2016;3(5):77-87.
Chicago Tosun, Emir, Mehmet Kayra Tanaydın, Gülistan Deniz Turhan Özdemir, and Nizamettin Demirkıran. “Sulu Çözeltilerden Lewatit S-108 Katyon Değişim Reçinesiyle Bakır İyonlarının Adsorpsiyonu”. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi 3, no. 5 (December 2016): 77-87.
EndNote Tosun E, Tanaydın MK, Turhan Özdemir GD, Demirkıran N (December 1, 2016) Sulu Çözeltilerden Lewatit S-108 Katyon Değişim Reçinesiyle Bakır İyonlarının Adsorpsiyonu. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi 3 5 77–87.
IEEE E. Tosun, M. K. Tanaydın, G. D. Turhan Özdemir, and N. Demirkıran, “Sulu Çözeltilerden Lewatit S-108 Katyon Değişim Reçinesiyle Bakır İyonlarının Adsorpsiyonu”, Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi, vol. 3, no. 5, pp. 77–87, 2016.
ISNAD Tosun, Emir et al. “Sulu Çözeltilerden Lewatit S-108 Katyon Değişim Reçinesiyle Bakır İyonlarının Adsorpsiyonu”. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi 3/5 (December 2016), 77-87.
JAMA Tosun E, Tanaydın MK, Turhan Özdemir GD, Demirkıran N. Sulu Çözeltilerden Lewatit S-108 Katyon Değişim Reçinesiyle Bakır İyonlarının Adsorpsiyonu. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi. 2016;3:77–87.
MLA Tosun, Emir et al. “Sulu Çözeltilerden Lewatit S-108 Katyon Değişim Reçinesiyle Bakır İyonlarının Adsorpsiyonu”. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi, vol. 3, no. 5, 2016, pp. 77-87.
Vancouver Tosun E, Tanaydın MK, Turhan Özdemir GD, Demirkıran N. Sulu Çözeltilerden Lewatit S-108 Katyon Değişim Reçinesiyle Bakır İyonlarının Adsorpsiyonu. Adıyaman Üniversitesi Mühendislik Bilimleri Dergisi. 2016;3(5):77-8.