Kazein Bazlı Yapıştırıcıların Üretimi ve Fizikokimyasal Özellikleri

Year 2022, Volume: 20 Issue: 1, 12 - 19, 03.04.2022

Zeynep Atamer

https://doi.org/10.24323/akademik-gida.1097805

Cited By: 1

Abstract

Bu çalışmada, çeşitli kazein tozları (misel kazein, αS-, β- ve ĸ-kazein fraksiyonları, sodyum kazeinat ve kalsiyum kazeinat) kullanılarak üretilen farklı yapıştırıcıların özellikleri ve gıda endüstrisinde kullanım olanağı araştırılmıştır. Farklı kazein kaynakları kullanılarak kazein bazlı yapıştırıcılar üretilmiş ve yapışkan mukavemetlerindeki farklılıkları belirlenmiştir. Kazein fraksiyonlarının izolasyonu için seçici çözünürlük, çökeltme ve dekanter santrifüj (çöktürülmüş kazeinin ve süpernatantın ayrılması için) yöntemleri kullanılmıştır. αS-, β- ve ĸ-kazein fraksiyonları için elde edilen saflıklar sırasıyla %25, 91 ve 54’ten büyük bulunmuştur. Sonuçlar, yapıştırıcıların üretiminde kullanılan kazein hammaddesinin türünün yapıştırıcı özellikleri üzerinde etkili olduğunu ve en yüksek yapışkan gücünün zenginleştirilmiş αS-kazein fraksiyonu ve misel kazein ile elde edildiğini göstermiştir.

Keywords

Kazein, Yapışkanlık, Gıda endüstrisi, Ayırma işlemi

Production and Physicochemical Properties of Casein-Based Adhesives

Abstract

In this study, different adhesives manufactured by using various casein powders (micellar casein, αS-, β- and ĸ-casein fractions, sodium caseinate and calcium caseinate) were investigated for their properties and potential application in the food industry. Casein-based adhesives using different sources of caseins were produced and the differences in their adhesive strength were determined. For the isolation of casein fractions, the methods of selective solubility, precipitation and a decanter centrifuge (for separation of precipitated casein and supernatant) were used. Achieved purities of αS-, β- and κ-casein fractions were higher than 25, 91 and 54%, respectively. Results showed that the type of casein raw material used in the production of adhesives had an influence on the adhesive properties and the highest adhesive strength was achieved with the enriched αS-casein fraction and micellar casein.

Keywords

Casein, Adhesive, Food industry, Separation process

Thanks

The author would like to thank Prof. Dr. Ahmet Kucukcetin (Akdeniz University, Turkey) and Prof. Dr. Joerg Hinrichs (University of Hohenheim, Germany).

References

• [1] Walstra, P., Wouters, J.T.M., Geurts, T.J. (2006). Dairy Science and Technology. Second Edition. Taylor & Francis Group, Boca Raton, FL, USA.
• [2] Guo, M. Wang, G. (2016). Milk protein polymer and its application in environmentally safe adhesives. Polymers, 8(9), 324.
• [3] Habenicht, G. (2009). Kleben - Grundlagen, Technologien, Anwendungen. Springer-Verlag, Berlin.
• [4] Atamer, Z., Post, A.E., Schubert, T., Holder, A., Boom, R.M., Hinrichs, J. (2017). Bovine β-casein: Isolation, properties and functionality. A review. International Dairy Journal, 66, 115-125.
• [5] Thienel, K.J.F., Holder, A., Schubert, T., Boom, R.M., Hinrichs, J., Atamer, Z. (2018). Fractionation of milk proteins on pilot scale with particular focus on β-casein. International Dairy Journal, 79, 73-77.
• [6] Audic, J.L., Chaufer, B., Daufi, G. (2003). Non-food applications of milk components and dairy co-products: A review. Lait, 417-438.
• [7] Sutermeister, E., Brühl, E. (1932). Das Kasein: Chemie und technische Verwertung, Aichstetten, Kremer Reprint.
• [8] U.S. Department of Agriculture, Forest Products Laboratory & University of Wisconsin, M. (1967). Casein glues: their manufacture, preparation, and application, U.S. Department of Agriculture, U.S. Forest Service Research Note FPL-0158.
• [9] United States Tariff Commission (1926). Casein: Report of the United States Tariff Commission to the President of the United States.
• [10] VLB Berlin, Forschungsinstitut für Maschinen- und Verpackungstechnik & Wenk, G. (2010). Abloeseverhalten von Getraenkeflaschen-Etiketten aus Papier, Berlin.
• [11] Lüttgen, C. (1953) Die Technologie der Klebstoffe, Berlin-Wilmersdorf, Wilhelm Pansegrau Verlag.
• [12] Broich, L., Herlfterkamp, B., Onusseit, H. (1992a) Wasserhaltiger Klebstoff auf Basis von Casein EP 0 597 920 B1.
• [13] Corwin, J.F. White, R.C. (1941) Bottle Labeling Adhesive US2351109.
• [14] Koerzendoerfer, A., Noebel, S., Hinrichs, J. (2017). Particle formation induced by sonication during yogurt fermentation e impact of exopolysaccharide-producing starter cultures on physical properties. Food Research International, 97, 170-177.
• [15] Schaefer, J., Schubert, T., Atamer, Z. (2019). Pilot-scale b-casein depletion from micellar casein via cold microfiltration in diafiltration mode. International Dairy Journal, 97, 222-229.
• [16] Schubert, T., Ergin, I., Panetta, F., Hinrichs, J., Atamer, Z. (2021). Application of a temperature-controlled decanter centrifuge for the fractionation of aS-, b- and k-casein on pilot scale. International Dairy Journal, 122, 105148.
• [17] Law, A.J.R., Leaver, J. (2007). Methods of extracting casein fractions from milk and caseinates and production of novel products. WO patent 2003003847.
• [18] Post, A.E., Hinrichs, J. (2011). Large-scale isolation of food-grade -casein. Milchwissenschaft, 66, 361-364.
• [19] Post, A.E., Ebert, M., Hinrichs, J. (2009). β-casein as a bioactive precursor-Processing for purification. Australian Journal of Dairy Technology, 64, 84-88.
• [20] Broyard, C., Gaucheron, F. (2015). Modifications of structures and functions of caseins: A scientific and technological challenge. Dairy Science & Technology, 95, 831-862.
• [21] Korhonen, H.J. (2009). Bioactive milk proteins and peptides: From science to functional applications. Australian Journal of Dairy Technology, 64, 16-25.
• [22] Strube, O.I., Rüdiger, A.A., Bremser, W. (2015). Buildup of biobased adhesive layers by enzymatically controlled deposition on the example of casein. International Journal of Adhesion and Adhesives, 63, 9-13. [23] Schubert, T., Meric, A., Boom, R., Hinrichs, J., Atamer, Z. (2018). Application of a decanter centrifuge for casein fractionation on pilot scale: Effect of operational parameters on total solid, purity and yield in solid discharge. International Dairy Journal, 84, 6-14.
• [24] Holder, A. (2014). Cross-flow electro membrane filtration for the fractionation of dairy-based functional peptides (Dissertation). Stuttgart, Germany: University of Hohenheim, Verlag Dr. Hut.
• [25] Patent No: US5455066 (1995), Broich, L; Herlfterkamp, B.; Onusseit, H: Water-containing adhesive based on casein. USA.
• [26] Patent No: CN103333657 A (2013). Ben: Natural environmental-friendly low-conductivity casein glue and production method thereof. China.
• [27] Bacigalupe, A., Fernández Solarte, A.M., Fernández, M.A., Torres Sánchez, R.M., Eisenberg, P., Escobar, M.M. (2017). Bio-adhesives from soy protein concentrate and montmorillonite: Rheological and thermal behaviour. International Journal of Adhesion and Adhesives, 77, 35-40.
• [28] Liu, Y., Li, K. (2007). Development and characterization of adhesives from soy protein for bonding wood. International Journal of Adhesion and Adhesives, 27(1), 59-67.
• [29] Khosravi, S., Khabbaz, F., Nordqvist, P., Johansson, M. (2010). Protein-based adhesives for particleboards. Industrial Crops and Products, 32(3), 275-283.
• [30] Kessler, A., Menéndez-Aguirre, O., Hinrichs, J., Stubenrauch, C., Weiss, J. (2013). Properties of an αs-casein-rich casein fraction: Influence of dialysis on surface properties, miscibility, and micelle formation. Journal of Dairy Science, 96(9), 5575–5590.
• [31] Kessler, A., Menéndez-Aguirre, O., Hinrichs, J., Stubenrauch, C., Weiss, J. (2014). αs-Casein-PE6400 mixtures: Surface properties, miscibility and self-assembly. Colloids and Surfaces B: Biointerfaces, 118, 49-56.
• [32] Chen, H., Xu, Z., Mo, J., Lyu, Y., Tang, X., Shen, X. (2017). Effects of guar gum on adhesion properties of soybean protein isolate onto porcine bones. International Journal of Adhesion and Adhesives, 75, 124-131.
• [33] Ling, Z., Hori, N., Iwata, T., Takemura, A. (2015). In-situ analysis of chemical structure of API adhesive using FT-NIR spectroscopy. Journal of The Adhesion Society of Japan, 51(S1), 322-331.
• [34] Liu, H., Li, C., Sun, X.S. (2017). Soy-oil-based waterborne polyurethane improved wet strength of soy protein adhesives on wood. International Journal of Adhesion and Adhesives, 73, 66-74.
• [35] Allen, S.W. (1920). Glues used in airplane parts. Committee, National Advisory Aeronautics, 189, 1-28.
• [36] Patel, J.P., Xiang, Z.G., Hsu, S.L., Schoch, A.B., Carleen, S.A., Matsumoto, D. (2017). Characterization of the crosslinking reaction in high performance adhesives. International Journal of Adhesion and Adhesives, 78, 256-262.
• [37] ASTM D4300-01 (2013). Standard test methods for ability of adhesive films to support or resist the growth of fungi.
• [38] Xu, L.C., Siedlecki, C.A. (2007). Effects of surface wettability and contact time on protein adhesion to biomaterial surfaces. Biomaterials, 28(22), 3273-3283.
• [39] Zheng, S., Ashcroft, I.A. (2005). A depth sensing indentation study of the hardness and modulus of adhesives. International Journal of Adhesion and Adhesives, 25(1), 67-76.
• [40] Sakaguchi, Y., Kosaka, N., Hori, N., Iwata, T., Takemura, A., Harada, E. (2011). Rheological analysis of the adhesion surface with a scanning probe microscope (SPM). International Journal of Adhesion and Adhesives, 31(1), 1-8.
• [41] ISO 11339 (2010). Adhesives-T-peel test for flexible-to-flexible bonded assemblies.
• [42] ISO 9653 (1998). Adhesives-Test method for shear impact strength of adhesive bonds.
• [43] ISO 4587 (2003). Adhesives-Determination of tensile lap-shear strength of rigid-to-rigid bonded assemblies.
• [44] Umemura, K., Inoue, A., Kawai, S. (2003). Development of new natural polymer-based wood adhesives I: Dry bond strength and water resistance of konjac glucomannan, chitosan, and their composites. Journal of Wood Science, 49(3), 221-226.