Hidrojel Esaslı Kompozit Kullanılarak Naftol Yeşili B içeren Atıksuların Arıtımında Ortam Parametrelerinin Etkisi

Year 2022, , 1129 - 1138, 27.10.2022

Mehtap Tanyol , Güzin Pıhtılı

https://doi.org/10.35414/akufemubid.1142743

Abstract

Bu çalışmada, EuCl3 ile katkılanmış poli (4-vinilpridin-ko-akrilamid) {P(4-VP-ko-AAm)/EuCl3} hidrojel kompozit adsorbent olarak kullanılarak atıksulardan naftol yeşili B boyasının giderim verimliliği araştırılmıştır. Naftol yeşili B adsorpsiyon verimliliğinin pH, adsorbent madde miktarı, başlangıç naftol yeşili B boya konsantrasyonu, sıcaklık ve temas süresi gibi değişkenlere bağımlılığı kesikli sistemde incelenmiştir. En yüksek giderim verimi 30 mg/L başlangıç naftol yeşili B konsantrasyonu, 0,05 g/100 mL P(4-VP-ko-AAm)/EuCl3 dozajı, pH=5,42 ve 25 °C sıcaklıkta %98,40 olarak elde edilmiştir. Deneysel denge verileri Langmuir izoterm modeli ile daha iyi uyum sağlamıştır. Kinetik sonuçlar, adsorpsiyon prosesinin hız belirleme basamaklarından biri olarak iç difüzyon ile yalancı ikinci derece kinetiği ile tanımlanabileceğini göstermiştir. Elde edilen deneysel sonuçlar, adsorbent olarak P(4-VP-ko-AAm)/EuCl3 hidrojeli kullanılarak naftol yeşili B boyasının başarılı bir şekilde atıksulardan giderilebileceğini göstermiştir.

Keywords

Polimerik adsorbent, Adsorpsiyon, Naftol yeşili B, Kinetik parametre

Supporting Institution

MUNZUR ÜNİVERSİTESİ

Project Number

YLMUB020-10

Thanks

Bu tez çalışmasını YLMUB020-10 proje numarası ile destekleyen Munzur Üniversitesi Bilimsel Araştırma Projeleri Birimine teşekkür ederim.

The Effect of Environmental Parameters on the Treatment of Naphthol Green B Containing Wastewater Using Hydrogel Based Composite

Abstract

In this study, the removal efficiency of naphthol green B dye from wastewater was investigated by using poly(4-vinylpyridine-co-acrylamide) {P(4-VP-co-AAm)/EuCl3} hydrogel composite adsorbent doped with EuCl3. The dependence of naphthol green B adsorption efficiency on variables such as pH, amount of adsorbent substance, initial naphthol green B dye concentration, temperature and contact time were investigated in batch system. The highest removal efficiency was found as 30 mg/L initial naphthol green B concentration, 0.05 g/100 mL P(4-VP-co-AAm)/EuCl3 dosage, pH=5.42 and 98.40% at 25 °C. has been obtained. Experimental equilibrium data were in better agreement with the Langmuir isotherm model. The kinetic results showed that the adsorption process can be described by pseudo-second-order kinetics with internal diffusion as one of the rate-determining steps. Obtained experimental results showed that naphthol green B dye can be successfully removed from wastewater by using P(4-VP-co-AAm)/EuCl3 hydrogel as adsorbent.

Keywords

Polymeric adsorbent, Adsorption, Naphtol green B, Kinetic parameter

Project Number

YLMUB020-10

References

• Akkaya, R., Ulusoy, U., 2011. Preparation and characterization of poly(acrylamide/maleic acid)-based hydrogels composites, Hacettepe Journal of Biology and Chemistry, 39, 359-370.
• Bartoňová, L., Ruppenthalová, L., Ritz, M., 2017. Adsorption of naphthol green B on unburned carbon: 2- and 3-parameter linear and non-linear equilibrium modelling. Chinese Journal of Chemical Engineering, 25, 37-44.
• Baskaralingam, P., Pulikesi, M., Elango, D., Ramamurthi, V., Sivanesan, S., 2006. Adsorption of acid dye onto organobentonite. Journal of Hazardous Material, 128, 138-144.
• Boztepe, C., Şölener, M., Yüceer, M., Künkül, A., 2015. Kabasakal, O.S., Modeling of swelling behaviors of acrylamide-based polymeric hydrogels by intelligent system. Journal of Dispersion Science and Technology, 36,1647-1656.
• Budtova, T.V., Suleıman, I.E., Frenkel, S.Y., 1993. On the swelling of polyelectrolyte hydrogels in solutions of linear-polymers. Vyskom. Sodeny, 35,93-98.
• Das A, Dey A., 2020. P-nitrophenol-bioremediation using potent Pseudomonas strain from the textile dye industry effluent. Journal of Environmental Chemical Engineering, 8, 103830.
• Duran, S., Şolpan, D., Güven, O., 1999. Synthesis and characterization of acrylamide-acrylic acid hydrogels and adsorption of some textile dyes. Nuclear Instruments and Methods in Physics Research Section B Beam Interactions with Materials and Atoms, 151, 196-199.
• Freundlich, H., 1906. Over the adsorption in solution. The Journal of Physical Chemistry A, 57(385471): 1100-1107.
• Javadian, H., Ghaemy, M., Taghavi, M., 2014. Adsorption kinetics, isotherm, and thermo-dynamics of Hg2+ to polyaniline/hexagonal mesoporous silica nanocomposite in water/wastewater. Journal of Material Science, 49, 232-242.
• Keskin, C.S., 2017. Dispers mavi 56 boyasının Fe3O4 gömülü akrilamit temelli polimer ile giderimi, Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 21, 363-371.
• Mittal, H., Alili, A.A., Alhassan, S.M., 2020. Adsorption isotherm and kinetics of water vapors on novel superporous hydrogel composites, Microporous and Mesoporous Materials, 299, 110106.
• Mousavi, S., Parvini, M., Ghorbani, M., 2018. Adsorption of heavy metals (Cu2+ and Zn2+) on novel bifunctional ordered mesoporous silica: Optimization by response surface methodology, Journal of the Taiwan Institute of Chemical Engineers, 84, 123–141.
• Ödemiş, H., 2014. Ksantan gam ve sepiyolit içeren yeni akrilamid/çinko akrilat kompozit hidrojellerin hazırlanışı, karakterizasyonu ve adsorpsiyon özelliklerinin incelenmesi. Yüksek Lisans Tezi, Adnan Menderes Üniversitesi Fen Bilimleri Enstitüsü, Aydın, 101.
• Oztop, H.N., Saraydin, D., Karadag, E., Caldıran, Y., Güven, O., 1998. Influence of some aromatic amino acids on the swelling behavior of acrylamide/maleic acid hydrogel. Polymer Bulletin, 40, 575-582.
• Pérez-Marín, A., Zapata, V.M., Ortuno, J., Aguilar, M., Sáez, J., Lloréns, M., 2007. Removal of cadmium from aqueous solutions by adsorption onto orange waste. Journal of Hazardous Material, 139, 122-131.
• Pıhtılı G., Tanyol M., Birkan K. 2022, Naphthol green B Removal using a Novel Hydrogel Composite: Thermodynamics, Isotherms, Kinetics and Optimization by RSM, ChemistrySelect DOI: 10.1002/slct.202201719, Article ID: SLCT202201719.
• Ramírez, E., Burillo, S.G., Barrera-Díaz, C., Roa, G., Bilyeu, B., 2011. Use of pH-sensitive polymer hydrogels in lead removal from aqueous solution. Journal of Hazardous Material, 192, 432-439.
• Rehman, M.S.U., Munir, M., Ashfaq, M., Rashid, N., Nazar, M.F., Danish, M., Han, J.I., 2013. Adsorption of brilliant green dye from aqueous solution onto red clay, Chemical Engineering Science, 228, 54-62.
• Rizk, S.E., Hamed, M.M., 2014. Batch sorption of iron complex dye, naphthol green B, from wastewater on charcoal, kaolinite, and tafla. Desalination and Water Treatment, 56, 1536-1546.
• Saini, J., Garg,V.K., Gupta, R.K., Kataria, N., 2017. Removal of Orange G and Rhodamine B dyes from aqueous system using hydrothermally synthesized zinc oxide loaded activated carbon (ZnO-AC). Journal of Environmental Chemical Engineering, 5, 884–892.
• Saraydın, D., Karadag, E., Güven, O., 2001. Use of superswelling acrylamide/maleic acid hydrogels for monovalent cationic dye adsorption. Journal of Applied Polymer Science, 79, 1809-1815.
• Tosun, E., Boztepe, C., Baysar, A., Künkül, A., 2019. Asidik boyaların poli(akrilamid-vinilimidazol) hidrojel kullanılarak atık sulardan giderimi. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 25, 914-921.
• Üzüm, B.Ö., 2008. Yeni akrilamid esaslı anyonik IPN’lerin sentezi,karakterizasyonu ve şişme/soğurum/ denetimli salınım potansiyellerinin araştırılması. Doktora Tezi, Adnan Menderes Üniversitesi Fen Bilimleri Enstitüsü, Aydın, 162.
• Varjani, S.J., Upasani, V.N. 2017. Critical review on biosurfactant analysis, purification and characterization using rhamnolipid as a model biosurfactant. Bioresource Technology, 232, 389–397.
• Yagub M.T., Sen T. K., Afroze S., Ang H.M. 2014. Dye and its removal from aqueous solution by adsorption: A review, Adv. Colloid Interface Sci, 209, 172–184.
• Weber, W.J., Morris, J.C., 1963. Kinetics of adsorption on carbon from solution. Journal of the Sanitary Engineering Division, 89, 31-60.
• Zhang, F., Ni, Z., Xia S., Liu, X., Wang, Q., 2009. Removal of naphthol green B from aqueous solution by calcined layered double hydroxides: adsorption property and mechanism studies. Chinese Journal of Chemistry, 27, 1767-1772.