L-Sistein Tayini için Çiçek Benzeri DOPANFs Modifiye Kalem Grafit Elektroda Dayalı Basit Bir Elektrokimyasal Sensör

Year 2023, , 1112 - 1121, 30.10.2023

Mükerrem Fındık

https://doi.org/10.35414/akufemubid.1347411

Abstract

L-sisteinin (L-Cys) elektrokimyasal tayini için yeni bir tek kullanımlık çiçek benzeri DOPANFs modifiye
edilmiş kalem grafit elektrot üretildi. DOPANFs’in yapısı SEM, EDX, FTIR ve XPS analizleri ile karakterize
edildi. Karakterizasyon, DOPANFs’in üç boyutlu hiyerarşik çiçek benzeri bir yapı sergilediğini
göstermiştir. DOPANFs modifiye kalem grafit elektrotun (PGE) elektrokimyasal özelliği döngüsel
voltametri (CV) tekniği ile incelendi. L-Cys tayini için diferansiyel puls voltametri (DPV) tekniği
kullanılarak daha hassas ölçümler yapıldı. L-Cys için 1-20 μM doğrusal aralığında tayin sınırı 0.989 μM
olarak hesaplandı.

Keywords

Hibrit nanoçiçek, Kalem grafit elektrot, L-sistein, Elektrokimyasal sensör

Thanks

Necmettin Erbakan Üniversitesi öğretim üyelerinden Prof. Dr. Emine Güler Akgemci'ye deneyler için laboratuvarını ve tüm laboratuvar olanaklarını sağladığı için teşekkür ederim.

A Simple Electrochemical Sensor Based on Flower-like DOPANFs Modified Pencil Graphite Electrode for L-Cysteine Determination

Abstract

A novel disposable flower-like DOPANFs modified pencil graphite electrode for the electrochemical
determination of L-cysteine (L-Cys) has been fabricated. The structure of DOPANFs was characterised
by SEM, EDX, FTIR and XPS analyses. The characterization showed that DOPANFs exhibited a three
dimensional hierarchical flower-like structure. The electrochemical property of DOPANFs modified
pencil graphite electrode (PGE) was investigated by cyclic voltammetry (CV) technique. More sensitive
measurements were made by using differential pulse voltammetry (DPV) technique for L-Cys
determination. The limit of detection for L-Cys in the linear range 1-20 μM was calculated as 0.989 μM.

Keywords

Hybrid nanoflowers, Pencil graphite electrode, L-cysteine, Electrochemical sensor

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