Bal Kabağı Sapı Tozunun Katyonik Tekstil Boyası Gideriminde Biyosorbent Olarak Kullanımı ve Optimum Koşulların Belirlenmesi

Year 2024, , 1431 - 1441, 02.12.2024

Sevgi Fersiz

https://doi.org/10.35414/akufemubid.1446078

Abstract

Bu çalışmada kabak sapı tozu, sulu çözeltilerden Astrazon Red 5BL boyasının adsorpsiyon yöntemiyle gideriminde adsorbent olarak kullanılmıştır. Adsorpsiyon çalışmaları kesikli sistemde çalışılarak adsorbent miktarı, karıştırma hızı, temas süresi, sıcaklık ve iyonik yükün boya giderim verimliliğine etkisi araştırılmıştır. 0,5 g/100 ml adsorbent miktarı, 250 rpm karştırma hızı, 15 dakika temas süresi ve 25 0C sıcaklık gibi çalışma şartlarında en yüksek boya giderimi verimi %94.5 olarak elde edilmiştir. Kinetik veriler değerlendirildiğinde adsorpsiyonun hızlı bir şekilde 15 dakikada tamamlandığı ve yalancı ikinci dereceden kinetik modeline uyumlu olduğu görülmüştür (R2=1). Elde edilen verilerin Langmuir, Freundlich, Temkin ve Dubinin-Radushkevich (D-R) izoterm modellerine uygunluğu incelenmiş ve Freundlich izoterminin, korelasyon katsayısına göre (R2=0.95) en iyi temsil eden model olduğu görülmüştür. Termodinamik parametreler incelendiğinde negatif ∆G0 değeri, adsorpsiyon prosesinin kendiliğinden gerçekleştiğini işaret etmektedir. Negatif ∆H0 ve negatif ∆S0 değerleri sırasıyla adsorpsiyon prosesinin ekzotermik olduğunu ve sistemin düzenli hale geçtiğini göstermiştir. Ayrıca çözeltinin tuz içermesi durumunda adsorpsiyon veriminin tuzun varlığında olumsuz olarak etkilenmediği ortaya konmuştur. Bir tarımsal atık olan kabak sapı tozunun, katyonik boya gideriminde; elde edilmesi kolay, ilave işletme ve kimyasal masrafı gerektirmeyen bir adsorbent olduğu ortaya konmuştur.

Keywords

Adsorpsiyon, Kabak sapı tozu, Katyonik boya, Kinetik, İzoterm

Use of Powdered Pumpkin Stalk as a Biosorbent in Cationic Textile Dye Removal and Determination of Optimum Conditions

Abstract

In this study, powdered pumpkin stalk was used as an adsorbent in the removal of Astrazon Red 5BL dye from aqueous solutions by adsorption method. Adsorption studies were conducted in a batch system and the effects of adsorbent dosage, mixing speed, contact time, temperature and ionic strenght on dye removal efficiency were investigated. The highest dye removal efficiency was obtained as 94.5% under operating conditions such as 0.5 g/100 ml adsorbent dosage, 250 rpm mixing speed, 15 minutes contact time and 25 0C temperature. When the kinetic data were evaluated, it was seen that the adsorption was completed quickly in 15 minutes and was compatible with the pseudo-second order kinetic model (R2 = 1). The suitability of the obtained data to Langmuir, Freundlich, Temkin and Dubinin-Radushkevich (D-R) isotherm models was examined and it was found that the Freundlich isotherm was the most representative model according to the correlation coefficient (R2 = 0.95). When thermodynamic parameters are examined, a negative ∆G0 value indicates that the adsorption process occurs spontaneously. Negative ∆H0 and negative ∆S0 values respectively showed that the adsorption process was exothermic and the system became ordered. It has also been shown that if the solution contains salt, the adsorption efficiency is not negatively affected by the presence of salt. In the cationic dye removal of powdered pumpkin stalk, which is an agricultural waste; It has been demonstrated that it is an adsorbent that is easy to obtain and does not require additional operating and chemical costs.

Keywords

Adsorption, Powdered pumpkin stalk, Cationic dye, Kinetic, Isotherm

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