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[BW12O40]3- ve 2,2'-Bipiridil İçeren Yeni Bir Nikel(II) Kompleksinin Sentezi ve Karakterizasyonu

Year 2020, , 576 - 581, 25.09.2020
https://doi.org/10.35414/akufemubid.762026

Abstract

Keggin tipi bir polioksometalat olan {Ni(2,2'-bipy)2(H2O)[BW12O40]}3- (NiBWO) bileşiği yüksek ısıya dayanıklı cam şişede hidrotermal olarak ilk kez sentezlenmiştir. Bileşiğin yapısı elementel analiz, X-ışını kırınımı, Fourier Dönüşümlü Kızılötesi Spektroskopisi, Termogravimetrik Analiz, Taramalı Elektron Mikroskobu ve X-ışını tek kristal kırınım analizleri ile karakterize edilmiştir. X-ışını tek kristal analiz sonucu, NiBWO bileşiğinin asimetrik biriminin bir [BW12O40]5- anyonu, bir [Ni(2,2'-bipy)2(H2O)]2+ ve bir buçuk [Ni(2,2'-bipy)3]2+ katyonlarından oluştuğunu göstermiştir.

Supporting Institution

Necmettin Erbakan University Research Foundation

Project Number

151210002

References

  • Referans1 APEX2, Bruker AXS Inc. Madison Wisconsin USA 2013.
  • Referans2 Berzelius, JJ, 1826. Beitrag zur näheren Kenntniss des Molybdäns. Annalen der Physik, 82(4), 369–392.
  • Referans3 Cameron, JM, Wales, DJ, Newton, GN. 2018. Shining a light on the photo-sensitisation of organic–inorganic hybrid polyoxometalates. Dalton Transactions, 47, 5120-5136.
  • Referans4 Canioni, R, Roch-Marchal, C, Secheresse, F, Horcajada, P, Serre, C, Hardi-Dan, M, Ferey, G, Greneche, JM, Lefebvre, F, Chang, JS, Hwang, YK, Lebedev, O, Turner, SB, Tendeloo, GV. 2011. Stable polyoxometalate insertion within the mesoporous metal organic framework MIL-100(Fe). Journal of Materials Chemistry, 21, 1226–1233.
  • Referans5 Du, N, Gong, L, Fan, L, Yu, K, Luo, H, Pang, S, Gao, J, Zheng, Z, Lv, J, Zhou, B. 2019. Nanocomposites Containing Keggin Anions Anchored on Pyrazine Based Frameworks for Use as Supercapacitors and Photocatalysts. ACS Applide Nano Materials, 2, 3039−3049.
  • Referans6 Farrugia, LJ. 1999. WinGX suite for small-molecule single-crystal crystallography. Journal of Applied Crystallography, 32, 837–838.
  • Referans7 Findik, M, Ucar, A, Colak, AT, Sahin, O, Bingol, H, Sayin, U, Kocak, N. 2019. Self-assembly of a new building block of {BMo12O40} with excellent catalytic activity for methylene blue. Polyhedron, 160, 229–237.
  • Referans8 Kastner, K, Kibler, AJ, Karjalainen, E, Fernandes, JA, Sans, V, Newton, GN. 2017. Redox-active organic–inorganic hybrid polyoxometalate micelles. Journal of Materials Chemistry A, 5, 11577–11581.
  • Referans9 Liu, J, Zhang, Y, Shang, S, Li, Y, Chen, L, Zhao, J. 2015. Syntheses, structures and properties of three metal–organic complexes containing 2,2′-dipyridyl-5,5′-dicarboxylate ligands. Journal of Solid State Chemistry, 221, 5–13.
  • Referans10 Shakeri, A, Mighani, H, Salari, N, Salehi, H, 2019. Surface modification of forward osmosis membrane using polyoxometalate based open frameworks for hydrophilicity and water flux improvement. Journal of Water Process Engineering, 29, 100762.
  • Referans11 Sheldrick, GM. 2008. A short history of SHELX. Acta Crystallographica Section A, A64, 112–122.
  • Referans12 Sheldrick, GM. 2015. Crystal structure refinement with SHELXL. Acta Crystallographica Section C, C71, 3–8.
  • Referans13 Xiao, LN, Yang, LX, Du, XD, Lan, Q, Zhang, H, Cui, XB. 2018. Four new compounds based on Keggin polyoxotungstates and transition metal complexes. Polyhedron, 147, 42–48.
  • Referans14 Zhang, J, Song, YF, Cronin, L, Liu, T. 2008. Self-Assembly of Organic−Inorganic Hybrid Amphiphilic Surfactants with Large Polyoxometalates as Polar Head Groups. Journal of the American Chemical Society, 130(44), 14408–14409.
  • Referans15 Zhao, W, Cui, J, Hao, J, Horn, JDV, 2019. Co-assemblies of polyoxometalate {Mo72Fe30}/double-tailed magnetic-surfactant for magnetic-driven anchorage and enrichment of protein. Journal of Colloid and Interface Science, 536, 88–97.
  • Referans16 Zong, L, Wu, H, Lin, H, Chen, Y. 2018. A polyoxometalate-functionalized two-dimensional titanium carbide composite MXene for effective cancer theranostics. Nano Research, 11, 4149–4168.
  • Referans17 Mercury, version 3.3; CCDC, available online via ccdc.cam.ac.uk/products/mercury.

Synthesis and Characterization of a New Nickel(II) Compound Derived from [BW12O40]3- and 2,2'-Bipyridyl

Year 2020, , 576 - 581, 25.09.2020
https://doi.org/10.35414/akufemubid.762026

Abstract

A Keggin-type polyoxometalate {Ni(2,2'-bipy)2(H2O)[BW12O40]}3- (NiBWO) has been hydrothermally synthesized in the high temperature resistant glass bottle for the first time. The structure has been characterized.by elemental analyses, X-ray diffraction, Fourier Transform Infrared Spectroscopy, Thermogravimetric Analysis, Scanning Electron Microscope and X-ray single crystal diffraction analyses. The X-ray single crystal study shows that the asymmetric unit of NiBWO is composed of one [BW12O40]5- anion, one [Ni(2,2'-bipy)2(H2O)]2+ and one and a half of [Ni(2,2'-bipy)3]2+ cations.

Project Number

151210002

References

  • Referans1 APEX2, Bruker AXS Inc. Madison Wisconsin USA 2013.
  • Referans2 Berzelius, JJ, 1826. Beitrag zur näheren Kenntniss des Molybdäns. Annalen der Physik, 82(4), 369–392.
  • Referans3 Cameron, JM, Wales, DJ, Newton, GN. 2018. Shining a light on the photo-sensitisation of organic–inorganic hybrid polyoxometalates. Dalton Transactions, 47, 5120-5136.
  • Referans4 Canioni, R, Roch-Marchal, C, Secheresse, F, Horcajada, P, Serre, C, Hardi-Dan, M, Ferey, G, Greneche, JM, Lefebvre, F, Chang, JS, Hwang, YK, Lebedev, O, Turner, SB, Tendeloo, GV. 2011. Stable polyoxometalate insertion within the mesoporous metal organic framework MIL-100(Fe). Journal of Materials Chemistry, 21, 1226–1233.
  • Referans5 Du, N, Gong, L, Fan, L, Yu, K, Luo, H, Pang, S, Gao, J, Zheng, Z, Lv, J, Zhou, B. 2019. Nanocomposites Containing Keggin Anions Anchored on Pyrazine Based Frameworks for Use as Supercapacitors and Photocatalysts. ACS Applide Nano Materials, 2, 3039−3049.
  • Referans6 Farrugia, LJ. 1999. WinGX suite for small-molecule single-crystal crystallography. Journal of Applied Crystallography, 32, 837–838.
  • Referans7 Findik, M, Ucar, A, Colak, AT, Sahin, O, Bingol, H, Sayin, U, Kocak, N. 2019. Self-assembly of a new building block of {BMo12O40} with excellent catalytic activity for methylene blue. Polyhedron, 160, 229–237.
  • Referans8 Kastner, K, Kibler, AJ, Karjalainen, E, Fernandes, JA, Sans, V, Newton, GN. 2017. Redox-active organic–inorganic hybrid polyoxometalate micelles. Journal of Materials Chemistry A, 5, 11577–11581.
  • Referans9 Liu, J, Zhang, Y, Shang, S, Li, Y, Chen, L, Zhao, J. 2015. Syntheses, structures and properties of three metal–organic complexes containing 2,2′-dipyridyl-5,5′-dicarboxylate ligands. Journal of Solid State Chemistry, 221, 5–13.
  • Referans10 Shakeri, A, Mighani, H, Salari, N, Salehi, H, 2019. Surface modification of forward osmosis membrane using polyoxometalate based open frameworks for hydrophilicity and water flux improvement. Journal of Water Process Engineering, 29, 100762.
  • Referans11 Sheldrick, GM. 2008. A short history of SHELX. Acta Crystallographica Section A, A64, 112–122.
  • Referans12 Sheldrick, GM. 2015. Crystal structure refinement with SHELXL. Acta Crystallographica Section C, C71, 3–8.
  • Referans13 Xiao, LN, Yang, LX, Du, XD, Lan, Q, Zhang, H, Cui, XB. 2018. Four new compounds based on Keggin polyoxotungstates and transition metal complexes. Polyhedron, 147, 42–48.
  • Referans14 Zhang, J, Song, YF, Cronin, L, Liu, T. 2008. Self-Assembly of Organic−Inorganic Hybrid Amphiphilic Surfactants with Large Polyoxometalates as Polar Head Groups. Journal of the American Chemical Society, 130(44), 14408–14409.
  • Referans15 Zhao, W, Cui, J, Hao, J, Horn, JDV, 2019. Co-assemblies of polyoxometalate {Mo72Fe30}/double-tailed magnetic-surfactant for magnetic-driven anchorage and enrichment of protein. Journal of Colloid and Interface Science, 536, 88–97.
  • Referans16 Zong, L, Wu, H, Lin, H, Chen, Y. 2018. A polyoxometalate-functionalized two-dimensional titanium carbide composite MXene for effective cancer theranostics. Nano Research, 11, 4149–4168.
  • Referans17 Mercury, version 3.3; CCDC, available online via ccdc.cam.ac.uk/products/mercury.
There are 17 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Mükerrem Fındık 0000-0002-9441-0814

Asuman Uçar 0000-0003-2674-3120

Nuriye Koçak 0000-0002-0531-3538

Onur Şahin 0000-0003-3765-3235

Alper Çolak 0000-0003-4478-7792

Project Number 151210002
Publication Date September 25, 2020
Submission Date July 1, 2020
Published in Issue Year 2020

Cite

APA Fındık, M., Uçar, A., Koçak, N., Şahin, O., et al. (2020). [BW12O40]3- ve 2,2’-Bipiridil İçeren Yeni Bir Nikel(II) Kompleksinin Sentezi ve Karakterizasyonu. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 20(4), 576-581. https://doi.org/10.35414/akufemubid.762026
AMA Fındık M, Uçar A, Koçak N, Şahin O, Çolak A. [BW12O40]3- ve 2,2’-Bipiridil İçeren Yeni Bir Nikel(II) Kompleksinin Sentezi ve Karakterizasyonu. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. September 2020;20(4):576-581. doi:10.35414/akufemubid.762026
Chicago Fındık, Mükerrem, Asuman Uçar, Nuriye Koçak, Onur Şahin, and Alper Çolak. “[BW12O40]3- Ve 2,2’-Bipiridil İçeren Yeni Bir Nikel(II) Kompleksinin Sentezi Ve Karakterizasyonu”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 20, no. 4 (September 2020): 576-81. https://doi.org/10.35414/akufemubid.762026.
EndNote Fındık M, Uçar A, Koçak N, Şahin O, Çolak A (September 1, 2020) [BW12O40]3- ve 2,2’-Bipiridil İçeren Yeni Bir Nikel(II) Kompleksinin Sentezi ve Karakterizasyonu. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 20 4 576–581.
IEEE M. Fındık, A. Uçar, N. Koçak, O. Şahin, and A. Çolak, “[BW12O40]3- ve 2,2’-Bipiridil İçeren Yeni Bir Nikel(II) Kompleksinin Sentezi ve Karakterizasyonu”, Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 20, no. 4, pp. 576–581, 2020, doi: 10.35414/akufemubid.762026.
ISNAD Fındık, Mükerrem et al. “[BW12O40]3- Ve 2,2’-Bipiridil İçeren Yeni Bir Nikel(II) Kompleksinin Sentezi Ve Karakterizasyonu”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 20/4 (September 2020), 576-581. https://doi.org/10.35414/akufemubid.762026.
JAMA Fındık M, Uçar A, Koçak N, Şahin O, Çolak A. [BW12O40]3- ve 2,2’-Bipiridil İçeren Yeni Bir Nikel(II) Kompleksinin Sentezi ve Karakterizasyonu. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2020;20:576–581.
MLA Fındık, Mükerrem et al. “[BW12O40]3- Ve 2,2’-Bipiridil İçeren Yeni Bir Nikel(II) Kompleksinin Sentezi Ve Karakterizasyonu”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 20, no. 4, 2020, pp. 576-81, doi:10.35414/akufemubid.762026.
Vancouver Fındık M, Uçar A, Koçak N, Şahin O, Çolak A. [BW12O40]3- ve 2,2’-Bipiridil İçeren Yeni Bir Nikel(II) Kompleksinin Sentezi ve Karakterizasyonu. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2020;20(4):576-81.


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