Mikrodalga ve Hidrotermal Sentez Yöntemleriyle Vanadyumun 5-Aminoizoftalato Ligantıyla Oluşturduğu Bileşiğin Sentezi ve Kısmi Karakterizasyonu (021201) (1-8)

Sabri Çevik; Muruvvet Düz

Hydrotermal and Microwave Synthesis and Partial Characterization of Coordination Compound of Vanadium Involving 5-Aminoisophthalato Ligand

Year 2014, Volume: 14 Issue: 2, 1 - 8, 01.08.2014

Abstract

A new coordination compounds of vanadium involving 5-aminoizofitalato (ASP) ligand was prepared with the reaction between vanadium compounds and 5-aminoisophthalic acid (H2ASP) by using hydrotermal and microwave synthetic methods. The compound with undefined basic formula and prepared with both synthetic methods was compared and partly characterized by using elemental analysis, IR spectroscopy, TGA, XRD powder diffraction and the room temperature magnetic susceptibility measurements.© Afyon Kocatepe Üniversitesi

Keywords

5-Aminoisoftalato; 5Aminoisophthalic acid

References

Cappellazzo, O., Cao, G., Messina, G. and Morbidelli, M., 1991., Kinetics of shape-selective xylene isomerization over a ZSM-5 catalyst. Industrial & Engineering Chemistry Research, 30, 2280-2284.
Costa, B.S., Wagner, C.C. and Baran, E.J., 2004. Vibration spectra and electrochemical behavior of bispicolinate copper(II).The Journal of the Argentine Chemical Society, 92,109-117.
Degnan, T.F., Chitnis, G.K. and Schipper, P.H., 2000. History of ZSM-5 fluid catalytic cracking additive development at Mobil. Microporous and Mesoporous Material, 245, 6-35.
Davis, M.E. and Lobo, R.F., 1992. Zeolite and molecular sieve synthesis. Chemistry of Materials, 4, 756-768.
Du, M. and Zhao, X.J., 2004. {[Cu(bipy)2.5(H2O)](ClO4)2.(H2O). (CH3OH)1.5}n (bipy = 4,4'-Bipyridine): organic template effect in formation of a novel bilayer coordination polymer with Communications, 7, 1056-1061. Inorganic Chemistry
Erdik, E., 1993. Organik Kimyada Spektroskopik Yöntemler. Gazi Büro Kitabevi, Ankara.
Feorey, G., Serre, C. and Draznieks, M., 2004. A Hybrid solid with giant pores prepared by a combination of targeted chemistry, Angewandte Chemie International Edition, 43 6296-6301.
Fromm, K.M., Sague, L.J. and Mirolo, L., 2010. Coordination polymer networks: an alternative to classical polymers? Macromolecular Symposia, 291–292, 75–83.
Holman, K.T., Hammud, H.H., Isber, S. and Tabbal, M., 2005. One-dimensional coordination polymer [Co(H2O)4(pyz)] (NO3)2 2H2O (pyz = pyrazine) with intra- and inter-chain H- bonds: structure, electronic spectral studies and magnetic properties. Polyhedron, 24, 221-225.
Huang, J., Fu, X., Wang, G. and Miao, O. 2011. Novel organic polymer–inorganic hybrid material zinc poly(styrene- phenylvinylphosphonate)-phosphate prepared with a simple method. Journay of Solid State Chemistry, 184, 2605–2609.
Janiak, C. 2003., Engineering coordination polymers towards applications. Juornal of The Chemical Society-Dalton Transactions, 2781-2804.
James, S.L., 2003. Metal-organic frameworks. Chemical Society Review, 32, 276-288. Kitagawa, S., Kitaura, R. and Noro, S., 2004. Angewandte Chemie-International Edition, 43, 2334-2375.
Kitagawa, S. and Kondo, M., 1998. Functional micropore chemistry of crystalline metal complex-assembled compounds. Bulletin of the Chemical Society of Japan, 71 1739–1753.
Lee L., 2008. Design of porous solids from 2-D and 3-D coordination frameworks utilizing imidazolylbenzoic acids and esters. MSc Thesis, Department of Chemistry & Biochemistry, Worcester Polytechnıc Institute, Worcester, USA.
Li, C., Peng, Y., Wang, S., Zhang, X., Li, L., Dou, J. and Li, D. 2011. pH and metal-dependent structural diversity from mononuclear to two-dimensional polymers based on a flexible tricarboxylate ligand. Journal of Solid State Chemistry, 184, 1581–1590.
Li, X.J., Cao, R., Gua Z., Wang, Y.Q. and Zhu, X. 2006. In situ synthesis architecture from modified flexible ligand. Journal of Molecular Structure, 798, 64–68. supramolecular
Murugavel, R., Krishnamurthy, D., and Sathiyendiran, M., 2002. Anionic metal organic and cationic organic layer alternation in the coordination polymers [{M(BTEC)(OH2)4} {C4H12N2}4H2O]n (M=Co, Ni, and Zn; BTEC=1,2,4,5-benzen etetracarboxylate). Journal of the Chemical Society, 34–39.
Meek, S.T., Greathouse, J.A. and Allendorf, M.D., 2011. Metal- organic frameworks: a rapidly growing class of versatile nanoporous materials. Advanced Materials, 23, 249–267.
McGoff, M., 2008. Design of Crystalline Splids via Solid-State Reaction. PhD Thesis, The Faculty of Worcester Polytechnıc Institute.
Nakamoto, K., 1986., Infrared and Raman Spectra of Inorganic and Publication, New York.
Wiley-Interscience frameworks: a new class of porous materials. Microporous and Mesoporous Materials, 73, 3–14.
Robin, Y.A. and Fromm, M.K., 2006. Coordination polymer networks with O- and N-donors: what they are, why and how they are made. Coordination Chemical Review, 250, 2127-2157.
Sgarabotto, P., Bisceglie, F., Pelosi, G., Abdel, R.L., 1999. Synthesis, X ray crystal structures and characterization of copper (II) -2,2’-bipyridyl derivatives of (4-amino)-hippuric acid and of proline. Polyhedron, 18, 2505-2510.
Sun, F.X., Zhu, G.S., Fang, Q.R. and Qiu, S.L., 2007. A novel 3D metal-organic framework with the pcu topology constructed dioxide. Inorganic Chemistry Communications, 10, 649- 651.
Tarushi, A., Christofis, P. and Psomas, G., 2007. Synthesis, characterization and interaction mononuclear Polyhedron, 26, 3963-3972. with DNA of acid complexes with oxolinic
Wu, H.P., Janiak, C., Rheinwald, G. and Lang, H., 1999. 5,5'- Dicyano-2,2'-bipyridine silver complexes: Discrete units or co-ordination polymers through a chelating and/or bridging metal-ligand interaction. Journal of the Chemical Society Dalton Transactions, 183–190.
Wilson, S.T., Lok, B.M., Messina, C.A., Cannan, T.R. and Flanigen, E.M., 1982. Aluminophosphate molecular sieves: a new class of microporous crystalline inorganic solids. Journal of the American Chemical Society, 104, 1146-1151.
Yaghi, O.M. and Li, H. ,1995. Hydrothermal synthesis of a metal-organic framework containing large rectangular channels. Journal of the American Chemical Society, 117, 10401-10402.
Yaghi, O.M., Davis, C.E. and Li, G.M., 1997. Selective guest binding by tailored channels in a 3-d porous zinc(II)- benzenetricarboxylate network. Journal of The American Chemical Society, 119, 2861-2868.
Yaghi, O.M., O’Keeffe and Ockwing. M., 2003. Reticular synthesis and the design of new materials. Nature, 423, 705-714.
Yaghi, O.M., Li, H.L. and Davis, C., 1998. Synthetic strategies, structure patterns, and emerging properties ın the chemistry of modular porous solids. Accounts of Chemical Research, 31, 474-484.
Yan, W., Yu, J., Shi, Z. and Xu, R., 2001. Synthesis and characterization phosphate. [AlP2O6(OH)2][H3O] containing propeller-like chiral motifs. Studies in Surface Science and Catalysis, 135, 245-249.
open-framework alumino
Yan, Z.W., Li, F., Zeng, H.F., Luo S.J. and Li, T.H., 2010. A new coordination mode of 5-aminoisophthalate in lead coordination photoluminescence properties. Journal of the Iranian Chemical Society, 7, 978-985. structure, and
Zhang, K., Qiao, N., Gao, H., Zhou, F. and Zhang, M. 2007. Self assembly of two novel three-dimensional supramolecular networks with blue photoluminescence. Polyhedron, 26, 2461–2469.
Zhu, H., Huang, C., Huang, W. and Gou, S., 2004. A novel coordination polymer constructed from 1D neutral chains via inter-chain π-π stacking and hydrogen bonding. Inorganic Chemistry Communications, 7, 1095-1101.