Hardal Yağından Biyodizel Üretiminin Optimizasyonu ve Motor Performans Testleri (025901) (1-9) Optimization of Biodiesel Production from Mustard Oil and Engine Performance Tests DOI:10.5578/fmbd.7669

Year 2014, Volume: 14 Issue: 2, 1 - 9, 01.08.2014

Faruk Emre Aysal Fatih Aksoy Adil Şahin Laçine Aksoy Harun Yıldırım

Abstract

In this study mustard oil produced from biodiesel production process are optimized. Parameters such as methanol / oil ratio, the catalyst concentration, reaction time and temperature have been investigated in the optimization process. Mustard oil-diesel fuel consisting of blends at the different proportions has been examined effects on engine performance and exhaust emissions. While proportion of biodiesel rising, power and torque of the internal combustion engine are reduced and specific fuel consumption (SFC) is increased. In addition, biodiesel, diesel fuels and blends of biodiesel-diesel fuels were investigated and their compared to NOx and CO emissions. It is found that biodiesel of mustard oil emissions more less than that of diesel fuel. © Afyon Kocatepe Üniversitesi

Keywords

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Hardal Yağından Biyodizel Üretiminin Optimizasyonu ve Motor Performans Testleri

Abstract

Bu çalışmada hardal yağından biyodizel üretim sürecinin optimizasyonu yapılmıştır. Optimizasyon süreci metanol/yağ oranı, katalizör konsantrasyonu reaksiyonu süresi ve sıcaklığı gibi parametrelere göre ele alınmıştır. Değişen oranlarda hardal yağı-dizel karışımından elde edilen biyodizel yakıtının motor performansına ve egzoz emisyonlarına etkileri incelenmiştir. Biyodizel oranı arttıkça içten yanmalı motorun güç ve momenti azalırken, özgül yakıt tüketimi (SFC) artmıştır. Ayrıca, biyodizel, dizel yakıtları ve biyodizel-dizel yakıtlarının karışımlarının NOx ve CO emisyonları karşılaştırılmıştır. Hardal yağı biyodizelinin emisyon değerlerinin dizel yakıttan düşük olduğu görülmüştür

Keywords

Hardal Yağı, Optimizasyon, Biodizel, Motor performansı

References

• Aktaş, A., ve Y. Segmen. «The effetcs of advance fuel injection on engine performance and exhaust emissions of a diesel engine fuelled with biodiesel.» J. Fac. Eng. Arch. Gazi Univ., 2008: 23: 199-206.
• Altıparmak, D., A.Keskin, A. Koca, ve M. Gürü. «Alternative fuel properties of tall oil fatty acid methyl ester-diesel fuel blends.» Bioresource Technology, 2007: Volume 98, 241-246.
• Antolin, G., F.V. Tinaut, Y. Briceno, V. Castano, C. Perez, ve A.I. Ramirez. «Optimisation of biodiesel production by sunflower oil transesteriŞcation.» .” Bioresource Technology, 2002: 83 :111-114.
• Berrios, M., ve RL. Skelton. «Comparison of puriŞcation methods for biodiesel.» Chem Eng J, 2008: 144:459-65.
• Bhatti, H. N., A. Hanif M., M. Qasim, ve Ata-ur- Rehman. «Biodiesel production from waste tallow.» Fuel, 2008: 87 : 2961–2966.
• Biswas, D., ve Parivesh. «Biodiesel as Automobile Fuel. Central Pollution Control Board, Ministry of Environment and Forests.» 2002. http://www.cpcb.delhi.nic.in/diesel/ch709 02.htm.
• Crabbe, E., C. Nolasco-Hipolito, Kobayashi G., Sonomoto K., ve Ishizaki A. «Biodiesel production from crude palm oil and evaluation of butanol extraction and fuel properties.» Process Biochem, 2001: 37:65- 71.
• Demirbas, A. «”biodiesel production from vegetabe oils via catalytic and non-catalytic supercritical methanol transesterification methods.» Progres in Energy and Combustion Science, 2009: 31: 466-87.
• Ghadge, S.V., ve H. Raheman. «Process optimization for biodiesel production from mahua (Madhuca indica) oil using response surface methodology.» .” Bioresource Technology, 2006: 97 : 379–384.
• Gürü, M., A. Koca, Ö. Can, C. Çınar, ve F. Şahin. «, “Biodiesel production from waste chicken fat based sources and evaluation with Mg based additive in a diesel engine.» Renewable Energy, 2010: 35 : 637–643.
• Gürü, M., U. Karakaya, D. Altıparmak, ve A. Alıcılar. «Improvement of diesel fuel properties by using additives.» Energy Conversion and Management, 2002: Vol:43: 1021-1025.
• Kalam, M.A., ve H.H. Masjuki. «Biodiesel from palmoil—an analysis of its properties and potential.» Biomass and Bioenergy, 2002: Volume 23, Issue 6, December, 471-479, 21-29.
• Knothe, G., ve M.A. Hanna. «The efect of mixing on transesterication of beef tallow.» ” Bioresource Technol, 1999: 69, 289-293.
• Lopez, D.E., J.G. Goodwin, D.A. Bruce, ve E. Lotero. «Transesterification of triacetin with methanol on solid acid and base catalysts.» Applied Catalysis A: General, 2005: 97-105.
• Meher, L.C., D.V. Sagar, ve S.N. Naik. «Technical aspects of biodiesel production by transesterification- a review.» Renewable and Sustainable Energy Reviews, 2006: 10 : 248–268.
• Nabi, M.N., M.S. Akhter, ve M.M. Zaglul, Shahadat. «Improvement of engine emissions with conventional diesel fuel and diesel–biodiesel blends.» Bioresour Technol, 2006: 97:372-8.
• Özsezen, A.N., ve M. Çanakcı. «Atık Palmiye ve Kanola Yağı Metil Esterlerinin Kullanıldığı Direkt Püskürtmeli Bir Dizel Motorda Perfotmans ve Yanma.» Gazi Üniv. Müh. Mim. Fak. Der., 2009: 24: 275-84.
• Phan, A. N., ve T. M. Phan. «Biodiesel production from waste cooking oils.» Fuel, 2008: 87 : 3490–3496.
• Puhan, S., N. Vedaraman, B.V.B. Ram, G. Sankarnarayanan, ve K. Jeychandran. «Mahua oil (Madhuca Indica seed oil) methyl ester as biodiesel-preparation and emission characterstics.» Biomass and Bioenergy, 2005: 28 : 87–93.
• Riberto, A., F. Castro, ve J. Carvalho. «INFLUENCE OF FREE FATTY ACID CONTENT IN BIODIESEL PRODUCTION.» WASTES: Solutions, Treatments and Opportunities 1st International Conference, 2011.
• Sinha., S., A K. Agarwal, ve S. Garg. «Biodiesel development from rice bran oil: TransesteriŞcation process optimization and fuel characterization.» ” Energy Conversion and Management, 2008: 49 :1248–1257.
• Tashtoush, G.M., M.I. Al-Widyan, ve M.M. Al- Jarrah. «Experimental Study on Evaluation and Optimisation of Conversion of Waste Animal Fats into Biodiesel.» Energy Convertion and Management, 2004: 45: 2697-2711.
• Thomas, T.P., D.M. Birney, ve D.L. Aulda. «Optimizing esteriŞcation of safflower, cottonseed, castor and used cottonseed oils.» Industrial Crops and Products, 2013: 41 :102-106.
• Usta, N., et al. «Combustion of biodiesel fuel produced from hazelnut soapstock/waste sunflower oil mixture in a diesel engine.» Energy Convertion & Management, 2004: 46:741-755.
• Varuvel, E.G., N. Mrad, M.Tazerout, ve F. Aloui. «, “Assessment of liquid fuel (bio-oil) production from waste Şsh fat and utilizationin diesel engine.» Applied Energy, 2012: 100 : 249–257.
• Wang, Y., S. Ou, P. Liu, F. Xue, ve S. Tang. «Comparison of two different processes to synthesize biodiesel by waste cooking oil.» Journal of Molecular Catalysis A: Chemical, 2006: 252: 107-112 .
• Xue, J., T.E. Grifta, ve A. C. Hansena. «Effect of biodiesel on engine performances and emissions.» Renewable and Sustainable Energy Reviews, 2011: 15 : 1098–1116.
• Yao, C., C.S. Cheung, C. Cheng, Y. Wang, T.L. Chan, ve S.C. Lee. «Effect of Diesel/methanol compound combustion on Diesel engine combustion and emissions.» Energy Conversion and Management, 2008: 49: 1696-1704.
• Yucesu, H.S., R. Altın, ve S. Çetinkaya. «Experimental investigation of vegetable oil usage as alternative fuel in idesel engines.» Turk J Eng Environ Sci, 2001: 25: 39-49.