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Poli(2-Hidroksi-3-Benzofenoksipropil Metakrilat-Benzil Metakrilat) Kopolimerinin Ters Gaz Kromatografisi ile Termodinamik Özelliklerinin İncelenmesi

Year 2018, Volume: 18 Issue: 1, 178 - 189, 30.04.2018

Aslışah Açıkses Fatih Biryan

Abstract

Bu çalışmada (2-hidroksi-3-benzofenoksipropil metakrilat0.45 - benzil metakrilat) kopolimerinin
ters gaz kromatografisi (IGC) ile polimer-prob sistemleri için termodinamik özellikleri incelendi.
Farklı sıcaklıklarda prob olarak bir seri alkan ve alkol kullanıldı. Her bir prob kolona enjekte
edilerek probların spesifik alıkonma hacimleri (
o
g V ) tayin edildi. Camsı geçiş sıcaklığı Tg’ yi tayin
etmek için (1/T; ln
o
g V ) grafikleri çizildi. Her iki grafikten de P(HBFPMA0.45-ko-BMA)’ nin camsı
geçiş sıcaklığı 98 oC olarak bulundu. Tg’nin altındaki sıcaklıklarda adsorpsiyon ısısı Ha ve Tg’nin
üzerindeki sıcaklıklarda sorpsiyona ait G1
s, H1
s ve S1
s değerleri hesaplandı. Sonsuz seyreltik
hal için polimer-çözücü etkileşimleri
 1 ,
12  , G1
 ve H1
 değerleri ve aynı sıcaklık
aralığında kopolimerin çözünürlük parametreleri (2) bulundu. P(HBFPMA0.45-ko-BMA)’nin
çözünürlük parametreleri (2) sıcaklık arttıkça azaldı. Bulunan sonuçlar kullanılan probların
kopolimer için zayıf çözücü olduğunu gösterdi.

Keywords

Termodinamik Özellikler” “Ağırlık Kesri Aktiflik Katsayısı” “Flory- Huggins Etkileşim Parametresi” “Sorpsiyon”

References

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  • Açıkses, A., Kaya, İ., Horoz, G., 2006. Synthesis, charectrization end thermodynamic properties of poly (3-mesitiltyl–2- hydroxypropyl methacrylate). Journal of Applied Polymer Science, Vol. 101, 101- 109.
  • Açikses, A., Kaya, İ., Sezek, U., Kırılmış, C., 2005. Synthesis, characterization and thermodynamic properties of poly(3- mesityl-2- hydrıxypropyl methacrylateco- an vinyl-2- pyrolidone), Polymer, 46, 11322-11329.
  • Al-Saigh, Z.Y., 1987. Miscibility and surface characterization of a poly(vinylidene fluoride)- poly(vinyl methyl ketone) blend by inverse gas chromatography, Polymer, 40: 3479
  • Al-Saigh, Z.Y., 1996. Inverse gas chromatography characterization of poly(ethyl oxide), Polymer, 40, 25-32.
  • Aspler, J.S., 1985. Theory and applications of inverse gas chromatography. In Liebman S.A, Levy EJ editors. Chromatographic science. New York: Marcel Dekker, p.29.
  • Biryan, F., Demirelli, K., 2017. Copolymerization of benzyl methacylate and methacrylate beaving benzophenoxy and hydroxyl side groups: monomer reactivity rations, thermal studies and dielectric measurements, Fibers and polymers, Vol. 18, No: 9, 1629- 1637.
  • Braun, J.M., Guillet, J.E, 1977. Determination of crystallinity by gas chromatography effect of gurvilinearity of retention ditagrams, Macromolecules, 10, 101.
  • Chen, C.T., Al-Saigh, Z.Y., 1990. Charectrization of poly (ethyl-methacrylat) by inverse gas chromeatography. Polymer, 3, 1170.
  • Desphande, D.D., Patterson, D., Screiber, H.P., Su, C.S., 1974. Prob dependency of polymer-plasticizer end polymerpolymer interaction parameters in inverse gas chromeatography. Macromolecules, 7, 530.
  • Di Paola-Baranyi, G., and Guillet, J.E., 1978. Estimation of polymer solubility parameters by gas chromeatography, Macromolecules, Vol. 11, 228–235.
  • Etxeberria, A., Alfageme, J., Uriarte, C., Iruin, J.J., 1992. Inverse gas chromeatography in the charecterization of polymeric materials. Journal of Chromeatography, 607, 227.
  • Erdik, E., 1975. Denel Organik Kimya, A.Ü. Fen Fakültesi Yayınları No: 45, Ankara.
  • Galin, M, 1989. Gas-liquid chromatography study of the thermodynamic of interactions between linear polyethylene end non-polar and polar solutes. Polymer, Vol. 30, 2074
  • Guillet, J.E., Purnel, J.H., 1973. Advences in Analytical Chemistry and Instrumentation Gas Chromatography, New York.
  • İlter, Z., Öncü, İ., Karagöz, M.H., Ercan, S., Alhanlı, F., 2016. Synthesis, Characterization and Thermodynamic Properties of two New 1,3-Dioxolane Containing Copolymers, Journal of the Chemical Society of Pakistan, Vol. 38, No. 3.
  • Karagöz, M.H., Erge, M.H., İlter, Z., 2009. Analysis of Physical and Thermodynamic Properties of Poly(2-Phenyl-1,3-Dioxolane-4-Yl-Methyl-Methacrylate-co-Ethyl methacrylate) Polymer with Inverse Gas Chromatography, Asian Journal of Chemistry, Vol. 21, No. 5, 403
  • Klein, J., Jeberien, H.E., 1980. Depence of thermodynamic properties of poly(ethylene glicol), Macromolecules Chemistry, 181, 1237.
  • Kong, X., Dulce, M.,Silveira, L.V., Zhao, L. and Choi, P., 2002. A Pseudo Equation-of-State Approach for the Estimation of Solubility Parameters of Polyethylene by Inverse Gas Chromatography, Macromolecules ,35, 8586-8590
  • Mandal, B.M, Bhattacharya, C, Bhattacharya, S.N., 1989. Thermodynamic characterization of binary polymer blends by inverse gas-chromatography, Journal of Macromolecular Science-Chemstry, A26: 1, 175-212
  • . Munk, P., Al-Saigh, Z.Y., Card, T.W., 1985. Inverse gas chromatography. 3. Dependence of retention volume on the amount of probe injected, Macromolecules, 18, 2196.
  • Price, G.J., Guillet, J.E, Purnell, J.H, 1986. Measument of solibility parameters by gas-liquid chromatography, J. Chromatogr. A(369): 273.
  • Sanetra, R., Kolarz, B.N., Wlochowicz, A., 1987. Determination of thermodynamic data fort he interaction of aliphatic alcohols with poly (styreneco-divinyl benzene) using inverse gas chromeatography. Polymer, 28: 1753.
  • Smidsrod, O. and Guillet, J.E., 1969. Study of polymer-solute interactions by gas chromeatography, Macromolecules, 11 (1): 228–235.
  • Smidsrod, O., Guillet, J.E., 1973. Advances in analitical chemistry and instrumentation gas chromatography, New York, Vol. 11, p. 187.
  • Vilcu, R., Leca, M., 1990. Polymer thermodynamic by gas chromatography. Studies in Polymer Science. Vol. 4. Amsterdam. Elsevier, p.132. Yampolskii, Y., Belov, N., 2015. Investigation of Polymers by Inverse Gas Chromatography, Macromolecules, 48, 6751-6767.
  • Yazıcı, D.T., Aşkın, A., Bütün, V., 2008. GC investigation of the solubility parameters of water- soluble homopolymers and doublehydrophilic diblock copolymers. Chromatographia, Vol. 67, 741–747

Year 2018, Volume: 18 Issue: 1, 178 - 189, 30.04.2018

Aslışah Açıkses Fatih Biryan

Abstract

References

  • Açıkses, A., Kaya, I., Ilter, Z., 2003. Study of some thermodynamic of poly[2-phenyl- 1,3-dioxolane-t-yl) methyl methacrylateco- buthyl methacrylate] by ınvers gas chromatography, Polym. Plast Technol. Eng., 42(3), 431.
  • Açıkses, A., Kaya, İ., Horoz, G., 2006. Synthesis, charectrization end thermodynamic properties of poly (3-mesitiltyl–2- hydroxypropyl methacrylate). Journal of Applied Polymer Science, Vol. 101, 101- 109.
  • Açikses, A., Kaya, İ., Sezek, U., Kırılmış, C., 2005. Synthesis, characterization and thermodynamic properties of poly(3- mesityl-2- hydrıxypropyl methacrylateco- an vinyl-2- pyrolidone), Polymer, 46, 11322-11329.
  • Al-Saigh, Z.Y., 1987. Miscibility and surface characterization of a poly(vinylidene fluoride)- poly(vinyl methyl ketone) blend by inverse gas chromatography, Polymer, 40: 3479
  • Al-Saigh, Z.Y., 1996. Inverse gas chromatography characterization of poly(ethyl oxide), Polymer, 40, 25-32.
  • Aspler, J.S., 1985. Theory and applications of inverse gas chromatography. In Liebman S.A, Levy EJ editors. Chromatographic science. New York: Marcel Dekker, p.29.
  • Biryan, F., Demirelli, K., 2017. Copolymerization of benzyl methacylate and methacrylate beaving benzophenoxy and hydroxyl side groups: monomer reactivity rations, thermal studies and dielectric measurements, Fibers and polymers, Vol. 18, No: 9, 1629- 1637.
  • Braun, J.M., Guillet, J.E, 1977. Determination of crystallinity by gas chromatography effect of gurvilinearity of retention ditagrams, Macromolecules, 10, 101.
  • Chen, C.T., Al-Saigh, Z.Y., 1990. Charectrization of poly (ethyl-methacrylat) by inverse gas chromeatography. Polymer, 3, 1170.
  • Desphande, D.D., Patterson, D., Screiber, H.P., Su, C.S., 1974. Prob dependency of polymer-plasticizer end polymerpolymer interaction parameters in inverse gas chromeatography. Macromolecules, 7, 530.
  • Di Paola-Baranyi, G., and Guillet, J.E., 1978. Estimation of polymer solubility parameters by gas chromeatography, Macromolecules, Vol. 11, 228–235.
  • Etxeberria, A., Alfageme, J., Uriarte, C., Iruin, J.J., 1992. Inverse gas chromeatography in the charecterization of polymeric materials. Journal of Chromeatography, 607, 227.
  • Erdik, E., 1975. Denel Organik Kimya, A.Ü. Fen Fakültesi Yayınları No: 45, Ankara.
  • Galin, M, 1989. Gas-liquid chromatography study of the thermodynamic of interactions between linear polyethylene end non-polar and polar solutes. Polymer, Vol. 30, 2074
  • Guillet, J.E., Purnel, J.H., 1973. Advences in Analytical Chemistry and Instrumentation Gas Chromatography, New York.
  • İlter, Z., Öncü, İ., Karagöz, M.H., Ercan, S., Alhanlı, F., 2016. Synthesis, Characterization and Thermodynamic Properties of two New 1,3-Dioxolane Containing Copolymers, Journal of the Chemical Society of Pakistan, Vol. 38, No. 3.
  • Karagöz, M.H., Erge, M.H., İlter, Z., 2009. Analysis of Physical and Thermodynamic Properties of Poly(2-Phenyl-1,3-Dioxolane-4-Yl-Methyl-Methacrylate-co-Ethyl methacrylate) Polymer with Inverse Gas Chromatography, Asian Journal of Chemistry, Vol. 21, No. 5, 403
  • Klein, J., Jeberien, H.E., 1980. Depence of thermodynamic properties of poly(ethylene glicol), Macromolecules Chemistry, 181, 1237.
  • Kong, X., Dulce, M.,Silveira, L.V., Zhao, L. and Choi, P., 2002. A Pseudo Equation-of-State Approach for the Estimation of Solubility Parameters of Polyethylene by Inverse Gas Chromatography, Macromolecules ,35, 8586-8590
  • Mandal, B.M, Bhattacharya, C, Bhattacharya, S.N., 1989. Thermodynamic characterization of binary polymer blends by inverse gas-chromatography, Journal of Macromolecular Science-Chemstry, A26: 1, 175-212
  • . Munk, P., Al-Saigh, Z.Y., Card, T.W., 1985. Inverse gas chromatography. 3. Dependence of retention volume on the amount of probe injected, Macromolecules, 18, 2196.
  • Price, G.J., Guillet, J.E, Purnell, J.H, 1986. Measument of solibility parameters by gas-liquid chromatography, J. Chromatogr. A(369): 273.
  • Sanetra, R., Kolarz, B.N., Wlochowicz, A., 1987. Determination of thermodynamic data fort he interaction of aliphatic alcohols with poly (styreneco-divinyl benzene) using inverse gas chromeatography. Polymer, 28: 1753.
  • Smidsrod, O. and Guillet, J.E., 1969. Study of polymer-solute interactions by gas chromeatography, Macromolecules, 11 (1): 228–235.
  • Smidsrod, O., Guillet, J.E., 1973. Advances in analitical chemistry and instrumentation gas chromatography, New York, Vol. 11, p. 187.
  • Vilcu, R., Leca, M., 1990. Polymer thermodynamic by gas chromatography. Studies in Polymer Science. Vol. 4. Amsterdam. Elsevier, p.132. Yampolskii, Y., Belov, N., 2015. Investigation of Polymers by Inverse Gas Chromatography, Macromolecules, 48, 6751-6767.
  • Yazıcı, D.T., Aşkın, A., Bütün, V., 2008. GC investigation of the solubility parameters of water- soluble homopolymers and doublehydrophilic diblock copolymers. Chromatographia, Vol. 67, 741–747
There are 27 citations in total.

Details

Primary Language Turkish
Journal Section Articles
Authors

Aslışah Açıkses

Fatih Biryan This is me

Publication Date April 30, 2018
Submission Date December 22, 2017
Published in Issue Year 2018 Volume: 18 Issue: 1

Cite

APA Açıkses, A., & Biryan, F. (2018). Poli(2-Hidroksi-3-Benzofenoksipropil Metakrilat-Benzil Metakrilat) Kopolimerinin Ters Gaz Kromatografisi ile Termodinamik Özelliklerinin İncelenmesi. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 18(1), 178-189.
AMA Açıkses A, Biryan F. Poli(2-Hidroksi-3-Benzofenoksipropil Metakrilat-Benzil Metakrilat) Kopolimerinin Ters Gaz Kromatografisi ile Termodinamik Özelliklerinin İncelenmesi. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. April 2018;18(1):178-189.
Chicago Açıkses, Aslışah, and Fatih Biryan. “Poli(2-Hidroksi-3-Benzofenoksipropil Metakrilat-Benzil Metakrilat) Kopolimerinin Ters Gaz Kromatografisi Ile Termodinamik Özelliklerinin İncelenmesi”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 18, no. 1 (April 2018): 178-89.
EndNote Açıkses A, Biryan F (April 1, 2018) Poli(2-Hidroksi-3-Benzofenoksipropil Metakrilat-Benzil Metakrilat) Kopolimerinin Ters Gaz Kromatografisi ile Termodinamik Özelliklerinin İncelenmesi. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 18 1 178–189.
IEEE A. Açıkses and F. Biryan, “Poli(2-Hidroksi-3-Benzofenoksipropil Metakrilat-Benzil Metakrilat) Kopolimerinin Ters Gaz Kromatografisi ile Termodinamik Özelliklerinin İncelenmesi”, Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 18, no. 1, pp. 178–189, 2018.
ISNAD Açıkses, Aslışah - Biryan, Fatih. “Poli(2-Hidroksi-3-Benzofenoksipropil Metakrilat-Benzil Metakrilat) Kopolimerinin Ters Gaz Kromatografisi Ile Termodinamik Özelliklerinin İncelenmesi”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 18/1 (April 2018), 178-189.
JAMA Açıkses A, Biryan F. Poli(2-Hidroksi-3-Benzofenoksipropil Metakrilat-Benzil Metakrilat) Kopolimerinin Ters Gaz Kromatografisi ile Termodinamik Özelliklerinin İncelenmesi. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2018;18:178–189.
MLA Açıkses, Aslışah and Fatih Biryan. “Poli(2-Hidroksi-3-Benzofenoksipropil Metakrilat-Benzil Metakrilat) Kopolimerinin Ters Gaz Kromatografisi Ile Termodinamik Özelliklerinin İncelenmesi”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 18, no. 1, 2018, pp. 178-89.
Vancouver Açıkses A, Biryan F. Poli(2-Hidroksi-3-Benzofenoksipropil Metakrilat-Benzil Metakrilat) Kopolimerinin Ters Gaz Kromatografisi ile Termodinamik Özelliklerinin İncelenmesi. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2018;18(1):178-89.