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Montmorillonit / HEC ve Sepiyolit / HEC Nanokompozitlerinin Termal Özelliklerinin Karşılaştırılması

Year 2018, Volume: 18 Issue: 1, 382 - 389, 30.04.2018

Sevim İşçi Nur Alan

Abstract

Bu çalışmada hidroksietil seliloz (HEC) polimerinin yapısal ve termal özellikleri üzerine Na-Montmorillonit (NaMMT) yada Sepiolit (Sp) kil ilavelerinin etkilerini inceleyebilmek için kil-polimer nanokompozitleri hazırlanmıştır. Polimerik filmler HEC polimerinin sulu çözeltisi ile killerin sulu dispersiyonlarının birleştirilmesi esasına dayanan çözeltilerin birleştirilmesi yöntemi ile hazırlanmıştır. Suda çözülebilen polimer matrikslerinde çözeltilerin birleştirilmesi yöntemi polimerin kararlılığı, killerin kolayca dağılabilmesi bakımından kullanışlı bir yöntemdir. Hazırlanan nanokompoziteler Fourier Transform infrered (FT/IR) ve geçirimli elektron mikroskopisi (TEM) yöntemleri ile karakterize edilmiş, termal özellikleri termogravimetrik analiz (TGA) ve taramalı diferansiyel kalorimetri (DSC) yöntemleri ile araştırılmıştır.

Keywords

Montmorillonit Sepiyolit HEC Nanokompozit Termal özellikler.

References

  • Alan, N., & Isci, S. (2014). Surface modification of sepiolite particles with polyurethane and polyvinyl alcohol. Progress in Organic Coatings, 77(2), 444-448. doi:DOI 10.1016/j.porgcoat.2013.11.005
  • Alexandre, M., & Dubois, P. (2000). Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Materials Science & Engineering R-Reports, 28(1-2), 1-63. doi:Doi 10.1016/S0927-796x(00)00012-7
  • Alvarez, A. (1984). Sepiolite: Properties and Uses. 37, 253-287. doi:10.1016/s0070-4571(08)70044-x
  • Amarelis, P., Carrado, K. A., Bergaya, F., Clay Minerals Society., & Groupe français des argiles. (2007). Clay-based polymer nanocomposites (CPN). Chantilly, VA: Clay Minerals Society.
  • Bergaya, F., Theng, B. K. G., & Lagaly, G. (2006). Handbook of clay science. Amsterdam ; London: Elsevier.
  • Bheda, J., Fellers, J. F., & White, J. L. (1980a). Phase-Behavior and Structure of Liquid-Crystalline Solutions of Cellulose Derivatives. Colloid and Polymer Science, 258(12), 1335-1342. doi:Doi 10.1007/Bf01668781
  • Bheda, J., Fellers, J. F., & White, J. L. (1980b). Phase-Transitions and Structure of Liquid-Crystalline Solutions of Cellulose Derivatives. Abstracts of Papers of the American Chemical Society, 179(Mar), 7-Cell.
  • Chang, J. H., & An, Y. U. (2002). Nanocomposites of polyurethane with various organoclays: Thermomechanical properties, morphology, and gas permeability. Journal of Polymer Science Part B-Polymer Physics, 40(7), 670-677.
  • Frost, R. L., & Rintoul, L. (1996). Lattice vibrations of montmorillonite: An FT Raman and X-ray diffraction study. Applied Clay Science, 11(2-4), 171-183. doi:Doi 10.1016/S0169-1317(96)00017-8
  • Galan, E. (1996). Properties and applications of palygorskite-sepiolite clays. Clay Minerals, 31(4), 443-453. doi:DOI 10.1180/claymin.1996.031.4.01
  • Gul, S., Kausar, A., Muhammad, B., & Jabeen, S. (2016). Research Progress on Properties and Applications of Polymer/Clay Nanocomposite. Polymer-Plastics Technology and Engineering, 55(7), 684-703. doi:10.1080/03602559.2015.1098699
  • Gul, V. E., Khanchich, O. A., & Savchenko, N. A. (1996). Characteristics of the liquid crystalline state of cellulose derivatives. Fibre Chemistry, 28(3), 145-147. doi:Doi 10.1007/Bf01053556
  • Isci, E., & Turutoglu, S. I. (2011). Stabilization of the mixture of bentonite and sepiolite as a water based drilling fluid. Journal of Petroleum Science and Engineering, 76(1-2), 1-5. doi:DOI 10.1016/j.petrol.2010.11.021
  • Isci, S. (2015). Surface Treatment of Sepiolite Particles with Polymers. In V. Mittal (Ed.), Surface Modification of Nanoparticle and Natural Fiber Fillers: Wiley.
  • Isci, S., Gunister, E., Ece, O. I., & Gungor, N. (2004). The modification of rheologic properties of clays with PVA effect. Materials Letters, 58(12-13), 1975-1978. doi:DOI 10.1016/j.matlet.2003.01.001
  • Isci S, Ü. C. H., Atıcı O, Güngör N. . (2006). Rheology and structure of aqueous bentonite; polyvinyl alcohol dispersions. Bulletin Material Science 29, 449-456.
  • Jones, B. F. G., E. (1988). Sepiolite and Palygorskite. Hydrous Phillosilicates, Reviews in Mineralogy, 19, 631-337.
  • Loh, E. (1973). Optical Vibrations in Sheet Silicates. Journal of Physics C-Solid State Physics, 6(6), 1091-1104. doi:Doi 10.1088/0022-3719/6/6/022
  • Lv, P. Z., Liu, C. Z., & Rao, Z. H. (2017). Review on clay mineral-based form-stable phase change materials: Preparation, characterization and applications. Renewable & Sustainable Energy Reviews, 68, 707-726. doi:10.1016/j.rser.2016.10.014
  • Nagy, B. B., W.F. (1955). The structural scheme of sepiolite. American Mineralogist, 40, 885-892.
  • Pinnavaia, T. J., & Beall, G. W. (2000). Polymer-clay nanocomposites. Chichester, England ; New York: Wiley.
  • Qian, Y., Lindsay, C. I., Macosko, C., & Stein, A. (2011). Synthesis and Properties of Vermiculite-Reinforced Polyurethane Nanocomposites. Acs Applied Materials & Interfaces, 3(9), 3709-3717. doi:Doi 10.1021/Am2008954
  • Ray, S. S. (2013). Clay-containing polymer nanocomposites from fundamentals to real applications (pp. 1 online resource.). Retrieved from http://www.sciencedirect.com/science/book/9780444594372
  • Ray, S. S., & Okamoto, M. (2003). Polymer/layered silicate nanocomposites: a review from preparation to processing. Progress in Polymer Science, 28(11), 1539-1641. doi:DOI 10.1016/j.progpolymsci.2003.08.002
  • Serna, C. J., & Vanscoyoc, G. E. (1979). Infrared Study of Sepiolite and Palygorskite Surfaces. 27, 197-206. doi:10.1016/s0070-4571(08)70715-5
  • Utracki, L. A. (2004). Clay-containing polymeric nanocomposites. Shrewsbury: Rapra Technology Ltd.
  • Wang, K. L., & Ye, L. (2010). Structure and Property of Cationic Hydroxyethyl Cellulose. Polymer-Plastics Technology and Engineering, 49(8), 807-811. doi:10.1080/03602551003749619

Year 2018, Volume: 18 Issue: 1, 382 - 389, 30.04.2018

Sevim İşçi Nur Alan

Abstract

References

  • Alan, N., & Isci, S. (2014). Surface modification of sepiolite particles with polyurethane and polyvinyl alcohol. Progress in Organic Coatings, 77(2), 444-448. doi:DOI 10.1016/j.porgcoat.2013.11.005
  • Alexandre, M., & Dubois, P. (2000). Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Materials Science & Engineering R-Reports, 28(1-2), 1-63. doi:Doi 10.1016/S0927-796x(00)00012-7
  • Alvarez, A. (1984). Sepiolite: Properties and Uses. 37, 253-287. doi:10.1016/s0070-4571(08)70044-x
  • Amarelis, P., Carrado, K. A., Bergaya, F., Clay Minerals Society., & Groupe français des argiles. (2007). Clay-based polymer nanocomposites (CPN). Chantilly, VA: Clay Minerals Society.
  • Bergaya, F., Theng, B. K. G., & Lagaly, G. (2006). Handbook of clay science. Amsterdam ; London: Elsevier.
  • Bheda, J., Fellers, J. F., & White, J. L. (1980a). Phase-Behavior and Structure of Liquid-Crystalline Solutions of Cellulose Derivatives. Colloid and Polymer Science, 258(12), 1335-1342. doi:Doi 10.1007/Bf01668781
  • Bheda, J., Fellers, J. F., & White, J. L. (1980b). Phase-Transitions and Structure of Liquid-Crystalline Solutions of Cellulose Derivatives. Abstracts of Papers of the American Chemical Society, 179(Mar), 7-Cell.
  • Chang, J. H., & An, Y. U. (2002). Nanocomposites of polyurethane with various organoclays: Thermomechanical properties, morphology, and gas permeability. Journal of Polymer Science Part B-Polymer Physics, 40(7), 670-677.
  • Frost, R. L., & Rintoul, L. (1996). Lattice vibrations of montmorillonite: An FT Raman and X-ray diffraction study. Applied Clay Science, 11(2-4), 171-183. doi:Doi 10.1016/S0169-1317(96)00017-8
  • Galan, E. (1996). Properties and applications of palygorskite-sepiolite clays. Clay Minerals, 31(4), 443-453. doi:DOI 10.1180/claymin.1996.031.4.01
  • Gul, S., Kausar, A., Muhammad, B., & Jabeen, S. (2016). Research Progress on Properties and Applications of Polymer/Clay Nanocomposite. Polymer-Plastics Technology and Engineering, 55(7), 684-703. doi:10.1080/03602559.2015.1098699
  • Gul, V. E., Khanchich, O. A., & Savchenko, N. A. (1996). Characteristics of the liquid crystalline state of cellulose derivatives. Fibre Chemistry, 28(3), 145-147. doi:Doi 10.1007/Bf01053556
  • Isci, E., & Turutoglu, S. I. (2011). Stabilization of the mixture of bentonite and sepiolite as a water based drilling fluid. Journal of Petroleum Science and Engineering, 76(1-2), 1-5. doi:DOI 10.1016/j.petrol.2010.11.021
  • Isci, S. (2015). Surface Treatment of Sepiolite Particles with Polymers. In V. Mittal (Ed.), Surface Modification of Nanoparticle and Natural Fiber Fillers: Wiley.
  • Isci, S., Gunister, E., Ece, O. I., & Gungor, N. (2004). The modification of rheologic properties of clays with PVA effect. Materials Letters, 58(12-13), 1975-1978. doi:DOI 10.1016/j.matlet.2003.01.001
  • Isci S, Ü. C. H., Atıcı O, Güngör N. . (2006). Rheology and structure of aqueous bentonite; polyvinyl alcohol dispersions. Bulletin Material Science 29, 449-456.
  • Jones, B. F. G., E. (1988). Sepiolite and Palygorskite. Hydrous Phillosilicates, Reviews in Mineralogy, 19, 631-337.
  • Loh, E. (1973). Optical Vibrations in Sheet Silicates. Journal of Physics C-Solid State Physics, 6(6), 1091-1104. doi:Doi 10.1088/0022-3719/6/6/022
  • Lv, P. Z., Liu, C. Z., & Rao, Z. H. (2017). Review on clay mineral-based form-stable phase change materials: Preparation, characterization and applications. Renewable & Sustainable Energy Reviews, 68, 707-726. doi:10.1016/j.rser.2016.10.014
  • Nagy, B. B., W.F. (1955). The structural scheme of sepiolite. American Mineralogist, 40, 885-892.
  • Pinnavaia, T. J., & Beall, G. W. (2000). Polymer-clay nanocomposites. Chichester, England ; New York: Wiley.
  • Qian, Y., Lindsay, C. I., Macosko, C., & Stein, A. (2011). Synthesis and Properties of Vermiculite-Reinforced Polyurethane Nanocomposites. Acs Applied Materials & Interfaces, 3(9), 3709-3717. doi:Doi 10.1021/Am2008954
  • Ray, S. S. (2013). Clay-containing polymer nanocomposites from fundamentals to real applications (pp. 1 online resource.). Retrieved from http://www.sciencedirect.com/science/book/9780444594372
  • Ray, S. S., & Okamoto, M. (2003). Polymer/layered silicate nanocomposites: a review from preparation to processing. Progress in Polymer Science, 28(11), 1539-1641. doi:DOI 10.1016/j.progpolymsci.2003.08.002
  • Serna, C. J., & Vanscoyoc, G. E. (1979). Infrared Study of Sepiolite and Palygorskite Surfaces. 27, 197-206. doi:10.1016/s0070-4571(08)70715-5
  • Utracki, L. A. (2004). Clay-containing polymeric nanocomposites. Shrewsbury: Rapra Technology Ltd.
  • Wang, K. L., & Ye, L. (2010). Structure and Property of Cationic Hydroxyethyl Cellulose. Polymer-Plastics Technology and Engineering, 49(8), 807-811. doi:10.1080/03602551003749619
There are 27 citations in total.

Details

Primary Language Turkish
Journal Section Articles
Authors

Sevim İşçi This is me

Nur Alan This is me

Publication Date April 30, 2018
Submission Date May 24, 2017
Published in Issue Year 2018 Volume: 18 Issue: 1

Cite

APA İşçi, S., & Alan, N. (2018). Montmorillonit / HEC ve Sepiyolit / HEC Nanokompozitlerinin Termal Özelliklerinin Karşılaştırılması. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 18(1), 382-389.
AMA İşçi S, Alan N. Montmorillonit / HEC ve Sepiyolit / HEC Nanokompozitlerinin Termal Özelliklerinin Karşılaştırılması. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. April 2018;18(1):382-389.
Chicago İşçi, Sevim, and Nur Alan. “Montmorillonit / HEC Ve Sepiyolit / HEC Nanokompozitlerinin Termal Özelliklerinin Karşılaştırılması”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 18, no. 1 (April 2018): 382-89.
EndNote İşçi S, Alan N (April 1, 2018) Montmorillonit / HEC ve Sepiyolit / HEC Nanokompozitlerinin Termal Özelliklerinin Karşılaştırılması. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 18 1 382–389.
IEEE S. İşçi and N. Alan, “Montmorillonit / HEC ve Sepiyolit / HEC Nanokompozitlerinin Termal Özelliklerinin Karşılaştırılması”, Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 18, no. 1, pp. 382–389, 2018.
ISNAD İşçi, Sevim - Alan, Nur. “Montmorillonit / HEC Ve Sepiyolit / HEC Nanokompozitlerinin Termal Özelliklerinin Karşılaştırılması”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 18/1 (April 2018), 382-389.
JAMA İşçi S, Alan N. Montmorillonit / HEC ve Sepiyolit / HEC Nanokompozitlerinin Termal Özelliklerinin Karşılaştırılması. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2018;18:382–389.
MLA İşçi, Sevim and Nur Alan. “Montmorillonit / HEC Ve Sepiyolit / HEC Nanokompozitlerinin Termal Özelliklerinin Karşılaştırılması”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 18, no. 1, 2018, pp. 382-9.
Vancouver İşçi S, Alan N. Montmorillonit / HEC ve Sepiyolit / HEC Nanokompozitlerinin Termal Özelliklerinin Karşılaştırılması. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2018;18(1):382-9.