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Synthesis of Yttria-Stabilized Zirconia (YSZ) Ceramic Powder Using Modified Sol-Gel Method

Year 2019, Volume: 19 Issue: 3, 871 - 875, 31.12.2019
https://doi.org/10.35414/akufemubid.619424

Abstract

Zirconia is widely used
ceramic powders as a biomaterial in medical applications due to its similarity
with tooth color, good mechanical and bioinert properties. Its high temperature
forms can be fully or partially stabilized by the addition of oxides such as
MgO, CaO and Y2O3. Recently, yttria stabilized zirconia
has been mostly studied because of its lots of advantages. In this study, 3%
mol and 8% mol yttria stabilized zirconia powders have been synthesized using a
simple sol-gel process. ZrO(NO3)2.xH2O and
Y(NO3)3.6H2O was dissolved in ethylene glycol
and pure water, respectively and mixed together. After mixing pH was adjusted
to 3.5 using HNO3. Final suspension was stirred until it becomes
homogenized. Homogeneous mixture dried at 120°C and then sintered at 1200°C.
Crystallite sizes and mineralogical composition were determined by XRD. Surface
area was measured by BET method and particle size was calculated. Density of
powders was measured by ultrapicnometer. Also, morphological structure was
examined by SEM. Tetragonal ZrO2 and tetragonal ZrO2-Y2O3
phases were observed. Current studies showed that YSZ powder can be effectively
synthesis with the present method.

Supporting Institution

The Office of Scientific Research Project Coordination; Yildiz Technical University

Project Number

2013-07-02-KAP01

Thanks

This study was supported by the Office of Scientific Research Project Coordination; Yildiz Technical University within the scope of the project number is 2013-07-02-KAP01.

References

  • Amézaga-Madrid, P., Hurtado-Macías, A., Antúnez-Flores, W., Estrada-Ortiz, F., Pizá-Ruiz, P., and Miki-Yoshida, M. (2012). Synthesis, microstructural, optical and mechanical properties of yttria stabilized zirconia thin films. Journal of Alloys and Compounds, 536, S412–S417.
  • Chen, S.-G., Yin, Y.-S., Wang, D.-P., and Li, J. (2004). Reduced activation energy and crystalline size for yttria-stabilized zirconia nano-crystals:: an experimental and theoretical study. Journal of Crystal Growth, 267(1–2), 100–109.
  • Denry, I., and Kelly, J. R. (2008). State of the art of zirconia for dental applications. Dental Materials, 24(3), 299–307.
  • Hsu, Y.-W., Yang, K.-H., Chang, K.-M., Yeh, S.-W., and Wang, M.-C. (2011). Synthesis and crystallization behavior of 3 mol% yttria stabilized tetragonal zirconia polycrystals (3Y-TZP) nanosized powders prepared using a simple co-precipitation process. Journal of Alloys and Compounds, 509(24), 6864–6870.Kaya, G. (2013). Production and characterization of self-colored dental zirconia blocks. Ceramics International, 39(1), 511–517.
  • Kelly, J. R., and Denry, I. (2008). Stabilized zirconia as a structural ceramic: an overview. Dental Materials, 24(3), 289–298.
  • Kuo, C.-W., Lee, Y.-H., Fung, K.-Z., and Wang, M.-C. (2005). Effect of Y2O3 addition on the phase transition and growth of YSZ nanocrystallites prepared by a sol–gel process. Journal of Non-Crystalline Solids, 351(4), 304–311.
  • Manicone, P. F., Iommetti, P. R., and Raffaelli, L. (2007). An overview of zirconia ceramics: basic properties and clinical applications. Journal of Dentistry, 35(11), 819–826.
  • Piconi, C., and Maccauro, G. (1999). Zirconia as a ceramic biomaterial. Biomaterials, 20(1), 1–25.
  • Pilathadka, S., Vahalová, D., and Vosáhlo, T. (2007). The Zirconia: a new dental ceramic material. An overview. Prague Med Rep, 108(1), 5–12.
  • Ray, J. C., Pati, R. K., and Pramanik, P. (2000). Chemical synthesis and structural characterization of nanocrystalline powders of pure zirconia and yttria stabilized zirconia (YSZ). Journal of the European Ceramic Society, 20(9), 1289–1295.
  • Wang, C.-H., Wang, M.-C., Du, J.-K., Sie, Y.-Y., Hsi, C.-S., and Lee, H.-E. (2013). Phase transformation and nanocrystallite growth behavior of 2 mol% yttria-partially stabilized zirconia (2Y-PSZ) powders. Ceramics International, 39(5), 5165–5174.
  • Zhu, Q., and Fan, B. (2005). Low temperature sintering of 8YSZ electrolyte film for intermediate temperature solid oxide fuel cells. Solid State Ionics, 176(9–10), 889–894.

Modifiye Sol-Jel Yöntemi Kullanılarak İtriya Katkılı Zirkonya Sentezi

Year 2019, Volume: 19 Issue: 3, 871 - 875, 31.12.2019
https://doi.org/10.35414/akufemubid.619424

Abstract

Zirkonya, tıbbi
uygulamalarda, diş rengine benzerliği, iyi mekanik ve biyoinert özellikleri
nedeniyle yaygın olarak kullanılan seramik tozlarıdır. Yüksek sıcaklık formları
MgO, CaO ve Y2O3 gibi oksitlerin eklenmesi ile tamamen
veya kısmen dengelenebilir. Son zamanlarda, itriya stabilize zirkonya
çoğunlukla avantajları nedeniyle incelenmiştir. Bu çalışmada, basit bir sol-jel
işlemi kullanılarak %3 mol ve %8 mol itriya stabilize zirkonya tozları
sentezlenmiştir. ZrO(NO3)2.xH2O ve Y(NO3)3.6H2O
sırası ile etilen glikol ve saf su içerisinde çözündürüldü ve karıştırıldı.
Karıştırmanın ardından pH, HNO3 ile 3.5'e ayarlandı. Elde edilen
süspansiyon homojen hale gelinceye kadar karıştırıldı. Homojen karışım,
120°C'de kurutuldu ve daha sonra 1200°C'de sinterlendi. Elde edilen tozların
kristal boyutları ve mineralojik kompozisyon XRD ile belirlenmiştir. Yüzey
alanı BET metodu ile ölçülmüş ve partikül büyüklüğü hesaplanmıştır. Tozların
yoğunluğu ise ultrapiknometre ile ölçülmüştür. Ayrıca SEM ile morfolojik yapı
incelenmiştir. Tetragonal ZrO2 ve tetragonal ZrO2-Y2O3
fazları gözlendi. Mevcut çalışmalar, YSZ tozunun bu yöntemle etkili bir şekilde
sentezlenebileceğini göstermektedir.

Project Number

2013-07-02-KAP01

References

  • Amézaga-Madrid, P., Hurtado-Macías, A., Antúnez-Flores, W., Estrada-Ortiz, F., Pizá-Ruiz, P., and Miki-Yoshida, M. (2012). Synthesis, microstructural, optical and mechanical properties of yttria stabilized zirconia thin films. Journal of Alloys and Compounds, 536, S412–S417.
  • Chen, S.-G., Yin, Y.-S., Wang, D.-P., and Li, J. (2004). Reduced activation energy and crystalline size for yttria-stabilized zirconia nano-crystals:: an experimental and theoretical study. Journal of Crystal Growth, 267(1–2), 100–109.
  • Denry, I., and Kelly, J. R. (2008). State of the art of zirconia for dental applications. Dental Materials, 24(3), 299–307.
  • Hsu, Y.-W., Yang, K.-H., Chang, K.-M., Yeh, S.-W., and Wang, M.-C. (2011). Synthesis and crystallization behavior of 3 mol% yttria stabilized tetragonal zirconia polycrystals (3Y-TZP) nanosized powders prepared using a simple co-precipitation process. Journal of Alloys and Compounds, 509(24), 6864–6870.Kaya, G. (2013). Production and characterization of self-colored dental zirconia blocks. Ceramics International, 39(1), 511–517.
  • Kelly, J. R., and Denry, I. (2008). Stabilized zirconia as a structural ceramic: an overview. Dental Materials, 24(3), 289–298.
  • Kuo, C.-W., Lee, Y.-H., Fung, K.-Z., and Wang, M.-C. (2005). Effect of Y2O3 addition on the phase transition and growth of YSZ nanocrystallites prepared by a sol–gel process. Journal of Non-Crystalline Solids, 351(4), 304–311.
  • Manicone, P. F., Iommetti, P. R., and Raffaelli, L. (2007). An overview of zirconia ceramics: basic properties and clinical applications. Journal of Dentistry, 35(11), 819–826.
  • Piconi, C., and Maccauro, G. (1999). Zirconia as a ceramic biomaterial. Biomaterials, 20(1), 1–25.
  • Pilathadka, S., Vahalová, D., and Vosáhlo, T. (2007). The Zirconia: a new dental ceramic material. An overview. Prague Med Rep, 108(1), 5–12.
  • Ray, J. C., Pati, R. K., and Pramanik, P. (2000). Chemical synthesis and structural characterization of nanocrystalline powders of pure zirconia and yttria stabilized zirconia (YSZ). Journal of the European Ceramic Society, 20(9), 1289–1295.
  • Wang, C.-H., Wang, M.-C., Du, J.-K., Sie, Y.-Y., Hsi, C.-S., and Lee, H.-E. (2013). Phase transformation and nanocrystallite growth behavior of 2 mol% yttria-partially stabilized zirconia (2Y-PSZ) powders. Ceramics International, 39(5), 5165–5174.
  • Zhu, Q., and Fan, B. (2005). Low temperature sintering of 8YSZ electrolyte film for intermediate temperature solid oxide fuel cells. Solid State Ionics, 176(9–10), 889–894.
There are 12 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Aysu Aydınoğlu 0000-0002-1875-2249

Afife Binnaz Hazar Yoruç This is me 0000-0001-7281-2305

Project Number 2013-07-02-KAP01
Publication Date December 31, 2019
Submission Date September 12, 2019
Published in Issue Year 2019 Volume: 19 Issue: 3

Cite

APA Aydınoğlu, A., & Hazar Yoruç, A. B. (2019). Synthesis of Yttria-Stabilized Zirconia (YSZ) Ceramic Powder Using Modified Sol-Gel Method. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 19(3), 871-875. https://doi.org/10.35414/akufemubid.619424
AMA Aydınoğlu A, Hazar Yoruç AB. Synthesis of Yttria-Stabilized Zirconia (YSZ) Ceramic Powder Using Modified Sol-Gel Method. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. December 2019;19(3):871-875. doi:10.35414/akufemubid.619424
Chicago Aydınoğlu, Aysu, and Afife Binnaz Hazar Yoruç. “Synthesis of Yttria-Stabilized Zirconia (YSZ) Ceramic Powder Using Modified Sol-Gel Method”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 19, no. 3 (December 2019): 871-75. https://doi.org/10.35414/akufemubid.619424.
EndNote Aydınoğlu A, Hazar Yoruç AB (December 1, 2019) Synthesis of Yttria-Stabilized Zirconia (YSZ) Ceramic Powder Using Modified Sol-Gel Method. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 19 3 871–875.
IEEE A. Aydınoğlu and A. B. Hazar Yoruç, “Synthesis of Yttria-Stabilized Zirconia (YSZ) Ceramic Powder Using Modified Sol-Gel Method”, Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 19, no. 3, pp. 871–875, 2019, doi: 10.35414/akufemubid.619424.
ISNAD Aydınoğlu, Aysu - Hazar Yoruç, Afife Binnaz. “Synthesis of Yttria-Stabilized Zirconia (YSZ) Ceramic Powder Using Modified Sol-Gel Method”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 19/3 (December 2019), 871-875. https://doi.org/10.35414/akufemubid.619424.
JAMA Aydınoğlu A, Hazar Yoruç AB. Synthesis of Yttria-Stabilized Zirconia (YSZ) Ceramic Powder Using Modified Sol-Gel Method. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2019;19:871–875.
MLA Aydınoğlu, Aysu and Afife Binnaz Hazar Yoruç. “Synthesis of Yttria-Stabilized Zirconia (YSZ) Ceramic Powder Using Modified Sol-Gel Method”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 19, no. 3, 2019, pp. 871-5, doi:10.35414/akufemubid.619424.
Vancouver Aydınoğlu A, Hazar Yoruç AB. Synthesis of Yttria-Stabilized Zirconia (YSZ) Ceramic Powder Using Modified Sol-Gel Method. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2019;19(3):871-5.