Year 2020, Volume 20 , Issue 4, Pages 565 - 575 2020-09-25

Removal of Heavy Metal Ions with Phenoxy Substituted Cyclotriphosphazene Derivatives Bearing Imine
İmin Grupları Taşıyan Fenoksi Sübstitüe Siklotrifosfazen Türevleri ile Ağır Metal İyonları Giderimi

Tahsin ÖZER [1] , Tuba ERDOGAN [2] , Ali İHSAN [3]


Hexa [4-(4-hydroxy-phenyliminomethyl) phenoxy] cyclotriphosphazene (A1) and Hexa [4-(2- hydroxy- phenyliminomethyl) phenoxy] cyclotriphosphazene (A2) were derived from the reactions of hexa(4- formyl-phenoxy)cyclotriphosphazene and hexa(2-formyl-phenoxy)cyclotriphosphazene with 4- aminophenol and 2-aminophenol. Adsorption process in an aqueous solution of Cu, Fe, Mn and Zn ions of the organophosphazenes bearing imine groups were performed depending on the initial concentration of metal ions and time. All of the compounds adsorbed the selected metal ions in the first 10 minutes. When the initial concentration of metal ions increases, the amount of metal ions adsorbed of organophosphazene with imine groups increased. Although the chemical structures of the compounds are different, the amount of adsorbed metal was about the same.
Hekza[4-{(4-hidroksi-fenilimino)metil}fenoksi]siklotrifosfazenin(A1) ve hekza[4-{(2-hidroksi-fenilimino)metil}fenoksi]siklotrifosfazenin(A2), 4-aminofenol ve 2-aminofenol ile heksa (4-formil-fenoksi) siklotriposfazen ve heksa (2-formil-fenoksi) siklotriposfazen reaksiyonlarından türetildi. İmin gruplarını taşıyan organofosfazelerin sulu Cu, Fe, Mn ve Zn iyonları çözeltisinde adsorpsiyon işlemi, metal iyonlarının başlangıç konsantrasyonuna ve süresine bağlı olarak gerçekleştirildi. Bileşiklerin tümü seçilen metal iyonlarını ilk 10 dakika içerisinde adsorbe etti. Metal iyonlarının başlangıç konsantrasyonu arttığında, imin gruplarıyla organofosfazene adsorbe edilen metal iyonlarının miktarı arttı. Bileşiklerin kimyasal yapıları farklı olmasına rağmen, adsorbe edilen metal miktarı yaklaşık olarak aynıydı.
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Primary Language en
Subjects Engineering
Journal Section Articles
Authors

Orcid: 0000-0003-0344-7118
Author: Tahsin ÖZER (Primary Author)
Institution: OSMANIYE KORKUT ATA UNIVERSITY
Country: Turkey


Orcid: 0000-0003-0344-7118
Author: Tuba ERDOGAN
Institution: HARRAN UNIVERSITY
Country: Turkey


Orcid: 0000-0002-3912-0670
Author: Ali İHSAN
Institution: OSMANIYE KORKUT ATA UNIVERSITY
Country: Turkey


Supporting Institution HÜBAK
Project Number 12102
Thanks This study was supported by HÜBAK (Project No: 12102). We thank HÜBAK.
Dates

Application Date : March 22, 2020
Publication Date : September 25, 2020

Bibtex @research article { akufemubid707429, journal = {Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi}, issn = {}, eissn = {2149-3367}, address = {}, publisher = {Afyon Kocatepe University}, year = {2020}, volume = {20}, pages = {565 - 575}, doi = {}, title = {Removal of Heavy Metal Ions with Phenoxy Substituted Cyclotriphosphazene Derivatives Bearing Imine}, key = {cite}, author = {Özer, Tahsin and Erdogan, Tuba and İhsan, Ali} }
APA Özer, T , Erdogan, T , İhsan, A . (2020). Removal of Heavy Metal Ions with Phenoxy Substituted Cyclotriphosphazene Derivatives Bearing Imine . Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi , 20 (4) , 565-575 . Retrieved from https://dergipark.org.tr/en/pub/akufemubid/issue/56836/707429
MLA Özer, T , Erdogan, T , İhsan, A . "Removal of Heavy Metal Ions with Phenoxy Substituted Cyclotriphosphazene Derivatives Bearing Imine" . Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 20 (2020 ): 565-575 <https://dergipark.org.tr/en/pub/akufemubid/issue/56836/707429>
Chicago Özer, T , Erdogan, T , İhsan, A . "Removal of Heavy Metal Ions with Phenoxy Substituted Cyclotriphosphazene Derivatives Bearing Imine". Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 20 (2020 ): 565-575
RIS TY - JOUR T1 - Removal of Heavy Metal Ions with Phenoxy Substituted Cyclotriphosphazene Derivatives Bearing Imine AU - Tahsin Özer , Tuba Erdogan , Ali İhsan Y1 - 2020 PY - 2020 N1 - DO - T2 - Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi JF - Journal JO - JOR SP - 565 EP - 575 VL - 20 IS - 4 SN - -2149-3367 M3 - UR - Y2 - 2020 ER -
EndNote %0 Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi Removal of Heavy Metal Ions with Phenoxy Substituted Cyclotriphosphazene Derivatives Bearing Imine %A Tahsin Özer , Tuba Erdogan , Ali İhsan %T Removal of Heavy Metal Ions with Phenoxy Substituted Cyclotriphosphazene Derivatives Bearing Imine %D 2020 %J Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi %P -2149-3367 %V 20 %N 4 %R %U
ISNAD Özer, Tahsin , Erdogan, Tuba , İhsan, Ali . "Removal of Heavy Metal Ions with Phenoxy Substituted Cyclotriphosphazene Derivatives Bearing Imine". Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 20 / 4 (September 2020): 565-575 .
AMA Özer T , Erdogan T , İhsan A . Removal of Heavy Metal Ions with Phenoxy Substituted Cyclotriphosphazene Derivatives Bearing Imine. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2020; 20(4): 565-575.
Vancouver Özer T , Erdogan T , İhsan A . Removal of Heavy Metal Ions with Phenoxy Substituted Cyclotriphosphazene Derivatives Bearing Imine. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2020; 20(4): 565-575.