Impregnation and Characterization of ZnO Nanoparticles on Hemp Woven Fabrics by Dip Coating Method

Year 2024, Volume: 24 Issue: 4, 931 - 939, 20.08.2024

Abdullah Gül

https://doi.org/10.35414/akufemubid.1414283

Abstract

In this study, nano-sized zinc oxide coating was applied to woven fabrics made from 100% hemp yarns by dip-coating method. Obtained modified hemp woven fabrics; Some analyzes and tests were performed and compared with raw hemp fabric to determine its structural, morphological, physical, mechanical and thermal properties. As a result of Fourier transform infrared spectroscopy (FTIR) and energy dispersive X-ray spectroscopy (EDS) analyses, the presence of zinc oxide in hemp fabrics modified with zinc oxide was detected. The morphological properties of zinc oxide coated fabrics were examined with scanning electron microscopy (SEM) and it was observed that there was a smooth coating on the fabric structure, although there were gaps in some places. With the thermogravimetric analysis (TGA) study, it was determined that the mass changes of the zinc oxide coated fabrics with temperature were higher than the raw sample. As a result of the breaking strength analysis performed for mechanical properties, a partial increase in the fabric strength and breaking elongation values of the zinc oxide coating was detected. Finally, it was understood from the tests that the contact angle properties of zinc oxide coated hemp fabrics were <90 and it was determined that it further increased the hydrophilicity. The results from this research confirm that ZnO is one of the most promising materials for the development of high-performance hemp textiles and will therefore be intensively investigated in the future.

Keywords

Hemp, Zinc oxide, ZnO, SEM, Strength, Contact angle

Daldırmalı kaplama yöntemi ile ZnO Nanoparçacıkların Kenevir Dokuma Kumaşlara Emdirilmesi ve Karakterizasyonu

Abstract

Bu çalışmada %100 kenevir ipliklerinden elde edilmiş dokuma kumaşlara daldırmalı kaplama (dip-coating) yöntemi ile çinko oksit (ZnO) nanoparçacıklar emdirilmiştir. Ham ve modifiyeli kenevir dokuma kumaşların yapısal, morfolojik, fiziksel, mekanik ve termal özellikleri karşılaştırılmıştır. Yapılan Fourier dönüşümlü kızılötesi spektroskopisi (FTIR) ve enerji dağılımlı X-ışınları spektroskopisi (EDS) analizleri sonucunda modifiyeli kenevir dokuma kumaşlarında ZnO metal oksit varlığı tespit edilmiştir. ZnO nanoparçacık emdirilmiş kumaşların tarama elektron mikroskobu (SEM) ile morfolojik özellikleri incelenmiş ve kumaş yapısı üzerinde yer yer boşluklu olsa da homojen kaplama elde edildiği gözlemlenmiştir. Termogravimetrik analiz (TGA) sonuçları ZnO nanoparçacık ihtiva eden kumaşların sıcaklıkla kütle değişimlerinin ham kumaşa göre daha yüksek olduğunu göstermiştir. Kopma mukavemeti analizi ile ZnO nanoparçacık içeren kumaşın mukavemet ve kopma uzama değerlerinde belirgin bir değişim olmadığı tespit edilmiştir. ZnO nanoparçacık emdirilen kumaşların temas açısının (56.95o) ham kumaş temas açısından (62.83o) daha küçük olduğu, bunun sonucu olarak kumaş hidrofilik özelliğinin arttığı tespit edilmiştir. Bu çalışmada elde edilen sonuçlar, ZnO nanoparçacıkların daldırmalı kaplama ile kumaşa emdirilmesi yaklaşımının yüksek performanslı kenevir tekstil ürünlerinin geliştirilmesi için umut verici olduğunu göstermiştir.

Keywords

Kenevir, Çinko oksit, ZnO, Mukavemet, Temas açısı

Ethical Statement

Bu çalışmanın, özgün bir çalışma olduğunu; çalışmanın hazırlık, veri toplama, analiz ve bilgilerin sunumu olmak üzere tüm aşamalarından bilimsel etik ilke ve kurallarına uygun davrandığımı; bu çalışma kapsamında elde edilmeyen tüm veri ve bilgiler için kaynak gösterdiğimi ve bu kaynaklara kaynakçada yer verdiğimi; kullanılan verilerde herhangi bir değişiklik yapmadığımı kabul ederek etik görev ve sorumluluklara riayet ettiğimi beyan ederim.

Thanks

Hayata geçirilen bu çalışmada, 1919B012200897 proje koduna sahip TÜBİTAK 2209/A projesi ile desteklenmiş yürütücülüğünü Fatma Nur KAÇAN, Danışmanlığı ise Doç. Dr. Nesrin KORKMAZ’ın yaptığı “Çevre Dostu Yeni Biyolojik Ajan; Çinko Oksit Nanopartikül” başlıklı proje çıktısı olan ZnO nanopartiküller kullanılmıştır. Bu kapsamda her iki araştırmacıya katkılarından dolayı teşekkür ederim.

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