Nadir Toprak Elementi İlaveli ZK60 (Ca/Ag) Alaşımlarının Korozyon Özelliklerinin İncelenmesi

Levent Elen; Deniz Ergin; Yunus Türen

Research Article

Investigation of Corrosion Properties of ZK60 (Ca/Ag) Alloys with Rare Earth Element Addition

Year 2025, Volume: 25 Issue: 2, 395 - 406

Abstract

In this study, the ZK60 alloy was prepared with rare earth elements (Y, Nd and Ce) added at different composition (0.5–1 wt%) and elements (Ca, Ag) added at a fixed composition (0.5 wt%) and extrusion. The effect of its application on microstructure and corrosion properties was examined. The extrusion process was carried out at 270 °C, at a speed of 0.3 m/s and at a ratio of 2.24:1. Corrosion tests were performed in Hank's solution at 36 °C. As a result of phase analysis, in addition to the main matrix (α-Mg) phase, Zn2Zr and MgZn2 intermetallic phases were detected in the microstructure of the ZK60 alloy. In addition to these phases, the presence of, Mg41Nd5, Mg3Y2Zn3 and Mg54Ag17 phases was detected in the structure of ZK60-0.5E and ZK60-1E alloys containing rare earth elements. Additionally, it was observed that the grain structures became thinner and the secondary phase particles increased with the addition of rare earth elements. Potentiodynamic corrosion tests conducted on the ZK60 alloy revealed that the corrosion rate was rather high. Additionally, the ZK60-0.5E and ZK60-1E alloys made with rare earth element additions showed increased corrosion resistance and slower corrosion rates.

Keywords

Mg alloys, ZK60, Microstructure, Corrosion

Project Number

KBUBAP-22-YL-029

References

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Nadir Toprak Elementi İlaveli ZK60 (Ca/Ag) Alaşımlarının Korozyon Özelliklerinin İncelenmesi

Year 2025, Volume: 25 Issue: 2, 395 - 406

Levent Elen , Deniz Ergin , Yunus Türen

Abstract

Bu çalışmada, ZK60 alaşımının farklı oranlarda (ağ. %0,5–1) ilave edilen nadir toprak elementleri (Y, Nd ve Ce) ile sabit oranda (ağ. %0,5) ilave edilen elementlerin (Ca, Ag) ve ekstrüzyon uygulamasının mikroyapı ve korozyon özellikleri üzerine etkisi incelenmiştir. Ekstrüzyon işlemi, 270 °C’de, 0,3 m/s hızda ve 2,24:1 oranında yapılmıştır. Korozyon testleri Hank solüsyonu içerisinde ve 36 °C’de yapılmıştır. Faz analizi sonucunda ZK60 alaşımının mikroyapısında ana matris (α-Mg) fazının yanı sıra yapıda ve Zn2Zr MgZn2 intermetalik fazlar tespit edilmiştir. Nadir toprak elementi içeren ZK60-0,5E ile ZK60-1E alaşımlarının yapısında ise bu fazlara ek olarak Mg54Ag17, Mg3Y2Zn3 ve Mg41Nd5 fazlarının varlığı tespit edilmiştir. Ayrıca nadir toprak elementi ilavesi ile tane yapılarının inceldiği ve ikincil faz partiküllerinin arttığı gözlenmiştir. ZK60 alaşımına uygulanan potansiyodinamik korozyon testleri neticesinde korozyon hızının oldukça yüksek olduğu, nadir toprak element ilaveleri ile oluşturulmuş olan ZK60-0,5E ve ZK60-1E alaşımlarda korozyon direncinin arttığı ve korozyon hızlarının da yavaşladığı görülmüştür.

Keywords

Mg alaşımları, ZK60, Mikroyapı, Korozyon

Project Number

KBUBAP-22-YL-029

References

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Details

Primary Language	Turkish
Subjects	Materials Engineering (Other)
Journal Section	Articles
Authors	Levent Elen 0000-0001-8740-7900 Deniz Ergin 0000-0003-4460-5821 Yunus Türen 0000-0001-8755-1865
Project Number	KBUBAP-22-YL-029
Early Pub Date	March 28, 2025
Publication Date
Submission Date	June 17, 2024
Acceptance Date	November 3, 2024
Published in Issue	Year 2025 Volume: 25 Issue: 2

Cite

APA	Elen, L., Ergin, D., & Türen, Y. (2025). Nadir Toprak Elementi İlaveli ZK60 (Ca/Ag) Alaşımlarının Korozyon Özelliklerinin İncelenmesi. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 25(2), 395-406.
AMA	Elen L, Ergin D, Türen Y. Nadir Toprak Elementi İlaveli ZK60 (Ca/Ag) Alaşımlarının Korozyon Özelliklerinin İncelenmesi. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. March 2025;25(2):395-406.
Chicago	Elen, Levent, Deniz Ergin, and Yunus Türen. “Nadir Toprak Elementi İlaveli ZK60 (Ca/Ag) Alaşımlarının Korozyon Özelliklerinin İncelenmesi”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 25, no. 2 (March 2025): 395-406.
EndNote	Elen L, Ergin D, Türen Y (March 1, 2025) Nadir Toprak Elementi İlaveli ZK60 (Ca/Ag) Alaşımlarının Korozyon Özelliklerinin İncelenmesi. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 25 2 395–406.
IEEE	L. Elen, D. Ergin, and Y. Türen, “Nadir Toprak Elementi İlaveli ZK60 (Ca/Ag) Alaşımlarının Korozyon Özelliklerinin İncelenmesi”, Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 25, no. 2, pp. 395–406, 2025.
ISNAD	Elen, Levent et al. “Nadir Toprak Elementi İlaveli ZK60 (Ca/Ag) Alaşımlarının Korozyon Özelliklerinin İncelenmesi”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 25/2 (March 2025), 395-406.
JAMA	Elen L, Ergin D, Türen Y. Nadir Toprak Elementi İlaveli ZK60 (Ca/Ag) Alaşımlarının Korozyon Özelliklerinin İncelenmesi. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2025;25:395–406.
MLA	Elen, Levent et al. “Nadir Toprak Elementi İlaveli ZK60 (Ca/Ag) Alaşımlarının Korozyon Özelliklerinin İncelenmesi”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 25, no. 2, 2025, pp. 395-06.
Vancouver	Elen L, Ergin D, Türen Y. Nadir Toprak Elementi İlaveli ZK60 (Ca/Ag) Alaşımlarının Korozyon Özelliklerinin İncelenmesi. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2025;25(2):395-406.

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