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Investigation of the Chemical Effect Using EDXRF Spectrometry on the Lines of Bromine Kα and Kβ X-Ray Emission Spectra

Year 2019, NSP2018 Special Issue, 107 - 112, 28.03.2019

Merve Meltem Hatipoğulları Harun Çümen Paşa Yalçın , Sevil Porikli Durdağı

Abstract

Bromine
is used in many areas such as agricultural chemicals, dyestuffs, insecticides,
pharmaceuticals and chemical intermediates. Some uses are being phased out for
environmental reasons, but new uses continue to be found. In this work, the
effects caused by different chemical environments in several bromine compounds
were studied using EDXRF spectrometry. The samples were excited by 59,5 keV
gamma rays emitted from Am-241 radioisotope source and characteristic K X-rays emitted from the samples were
counted by Si(Li) detector. Modifications
in values of energy of X-Ray line, full width at half maximum (FWHM), asymmetry
index (AI) were determined. In conclusion, the results of the present paper
demonstrate that the Bromine Kα and Kβ emission energies depend on the Br
chemical state and, therefore, their determination allows the chemical state
speciation of Br in a given sample.




Keywords

EDXRF Chemical Effect Bromine X-Ray line Full width at half maximum (FWHM) Asymmetry index (AI)

References

  • [1] C. Mande, M.Y. Apte, Bull. Mater. Sci. 3 (1981) 193.
  • [2] A.K. Nigam, M.K. Gupta, J. Phys. F: Metal Phys. 4 (1974) 1084.
  • [3] H.K. Hinge, S.K. Joshi, B.D. Shrivastava, J. Prasad, K. Srivastava, Ind. J. Pure Appl. Phys. 49 (2011) 168.
  • [4] S.K. Pandey, A.R. Chetal, P.R. Sarode, J. Phys. Soc. Jpn. 59 (1990) 1848.
  • [5] J. Kawai, K. Fujisawa, Y. Gohshi, Spectrochim. Acta 42B (6) (1987) 729–743.
  • [6] S. Wonglee, T. Tada, H. Fukuda, J. Hasegawa, Y. Oguri, Nucl. Instrum. Methods Phys. B 269 (2011) 3111–3114.
  • [7] Z. Kertész, E. Furu, M. Kavčič, Spectrochim. Acta B 79–80 (2013) 58–62.
  • [8] S. Nishibu, S. Yonezawa, M. Takashima, J. Fluorine Chem. 126 (2005) 1048–1053.
  • [9] M. Kavčič, A. Karydas, C. Zarkadas, Nuc. Instr. and Met.s in Phys. Res. Sec. B (2004) 222(3-4):601-608.
  • [10] T. Tada, M. Hayashi, H. Fukuda, J. Hasegawa, Y. Oguri, Nucl. Instrum. Methods Phys. B 266 (2008) 2292–2295.
  • [11] R.M. Harrison, C.A. Pio, Environ. Sci. Technol. 17 (1983) 169–174.
  • [12] S. Mirji, A.S. Bennal, N.M. Badiger, M.K. Tiwari, G.S. Lodha, Chem. Phys. Lett. 634 (2015) 271-276.
  • [13] K. Taniguchi, Bull. Chem. Soc. Jpn., 57 (1984) 915-920.
  • [14] T. Deluigi, M. Perino, E. Olsina, R. Riveros de la Vega, Spectrochim. Acta Part B, 58 (2003) 1699-1707.
  • [15] M. Fichter, Spectrochim. Acta Part B, 30 (1975) 417-431.
  • [16] G. Leonhardt, A. Meisel, J. Chem. Phys. 52 (1970) 6189-6198.
  • [17] Meisel, G. Leonhardt, R. Szargan, (1989). Springer-Verlag, Berlin, Heidelberg.
  • [18] S. Porikli, Y. Kurucu, Instrumentation Science & Technology, 36:4, (2008) 341-354.

-

Year 2019, NSP2018 Special Issue, 107 - 112, 28.03.2019

Merve Meltem Hatipoğulları Harun Çümen Paşa Yalçın , Sevil Porikli Durdağı

Abstract

-

Keywords

EDXRF Chemical Effect Bromine X-Ray line Full width at half maximum (FWHM) Asymmetry index (AI)

References

  • [1] C. Mande, M.Y. Apte, Bull. Mater. Sci. 3 (1981) 193.
  • [2] A.K. Nigam, M.K. Gupta, J. Phys. F: Metal Phys. 4 (1974) 1084.
  • [3] H.K. Hinge, S.K. Joshi, B.D. Shrivastava, J. Prasad, K. Srivastava, Ind. J. Pure Appl. Phys. 49 (2011) 168.
  • [4] S.K. Pandey, A.R. Chetal, P.R. Sarode, J. Phys. Soc. Jpn. 59 (1990) 1848.
  • [5] J. Kawai, K. Fujisawa, Y. Gohshi, Spectrochim. Acta 42B (6) (1987) 729–743.
  • [6] S. Wonglee, T. Tada, H. Fukuda, J. Hasegawa, Y. Oguri, Nucl. Instrum. Methods Phys. B 269 (2011) 3111–3114.
  • [7] Z. Kertész, E. Furu, M. Kavčič, Spectrochim. Acta B 79–80 (2013) 58–62.
  • [8] S. Nishibu, S. Yonezawa, M. Takashima, J. Fluorine Chem. 126 (2005) 1048–1053.
  • [9] M. Kavčič, A. Karydas, C. Zarkadas, Nuc. Instr. and Met.s in Phys. Res. Sec. B (2004) 222(3-4):601-608.
  • [10] T. Tada, M. Hayashi, H. Fukuda, J. Hasegawa, Y. Oguri, Nucl. Instrum. Methods Phys. B 266 (2008) 2292–2295.
  • [11] R.M. Harrison, C.A. Pio, Environ. Sci. Technol. 17 (1983) 169–174.
  • [12] S. Mirji, A.S. Bennal, N.M. Badiger, M.K. Tiwari, G.S. Lodha, Chem. Phys. Lett. 634 (2015) 271-276.
  • [13] K. Taniguchi, Bull. Chem. Soc. Jpn., 57 (1984) 915-920.
  • [14] T. Deluigi, M. Perino, E. Olsina, R. Riveros de la Vega, Spectrochim. Acta Part B, 58 (2003) 1699-1707.
  • [15] M. Fichter, Spectrochim. Acta Part B, 30 (1975) 417-431.
  • [16] G. Leonhardt, A. Meisel, J. Chem. Phys. 52 (1970) 6189-6198.
  • [17] Meisel, G. Leonhardt, R. Szargan, (1989). Springer-Verlag, Berlin, Heidelberg.
  • [18] S. Porikli, Y. Kurucu, Instrumentation Science & Technology, 36:4, (2008) 341-354.
There are 18 citations in total.

Details

Primary Language English
Journal Section Makaleler
Authors

Merve Meltem Hatipoğulları This is me

Harun Çümen This is me

Paşa Yalçın

Sevil Porikli Durdağı

Publication Date March 28, 2019
Submission Date December 2, 2018
Acceptance Date February 12, 2019
Published in Issue Year 2019 NSP2018 Special Issue

Cite

APA Hatipoğulları, M. M., Çümen, H., Yalçın, P., Porikli Durdağı, S. (2019). Investigation of the Chemical Effect Using EDXRF Spectrometry on the Lines of Bromine Kα and Kβ X-Ray Emission Spectra. ALKÜ Fen Bilimleri Dergisi107-112.
AMA Hatipoğulları MM, Çümen H, Yalçın P, Porikli Durdağı S. Investigation of the Chemical Effect Using EDXRF Spectrometry on the Lines of Bromine Kα and Kβ X-Ray Emission Spectra. ALKÜ Fen Bilimleri Dergisi. Published online March 1, 2019:107-112.
Chicago Hatipoğulları, Merve Meltem, Harun Çümen, Paşa Yalçın, and Sevil Porikli Durdağı. “Investigation of the Chemical Effect Using EDXRF Spectrometry on the Lines of Bromine Kα and Kβ X-Ray Emission Spectra”. ALKÜ Fen Bilimleri Dergisi, March (March 2019), 107-12.
EndNote Hatipoğulları MM, Çümen H, Yalçın P, Porikli Durdağı S (March 1, 2019) Investigation of the Chemical Effect Using EDXRF Spectrometry on the Lines of Bromine Kα and Kβ X-Ray Emission Spectra. ALKÜ Fen Bilimleri Dergisi 107–112.
IEEE M. M. Hatipoğulları, H. Çümen, P. Yalçın, and S. Porikli Durdağı, “Investigation of the Chemical Effect Using EDXRF Spectrometry on the Lines of Bromine Kα and Kβ X-Ray Emission Spectra”, ALKÜ Fen Bilimleri Dergisi, pp. 107–112, March 2019.
ISNAD Hatipoğulları, Merve Meltem et al. “Investigation of the Chemical Effect Using EDXRF Spectrometry on the Lines of Bromine Kα and Kβ X-Ray Emission Spectra”. ALKÜ Fen Bilimleri Dergisi. March 2019. 107-112.
JAMA Hatipoğulları MM, Çümen H, Yalçın P, Porikli Durdağı S. Investigation of the Chemical Effect Using EDXRF Spectrometry on the Lines of Bromine Kα and Kβ X-Ray Emission Spectra. ALKÜ Fen Bilimleri Dergisi. 2019;:107–112.
MLA Hatipoğulları, Merve Meltem et al. “Investigation of the Chemical Effect Using EDXRF Spectrometry on the Lines of Bromine Kα and Kβ X-Ray Emission Spectra”. ALKÜ Fen Bilimleri Dergisi, 2019, pp. 107-12.
Vancouver Hatipoğulları MM, Çümen H, Yalçın P, Porikli Durdağı S. Investigation of the Chemical Effect Using EDXRF Spectrometry on the Lines of Bromine Kα and Kβ X-Ray Emission Spectra. ALKÜ Fen Bilimleri Dergisi. 2019:107-12.