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Membran Kapasitif Deiyonizasyon Prosesi ile Sertlik Giderimi

Year 2019, Volume: 7 Issue: 3, 341 - 346, 28.09.2019
https://doi.org/10.21541/apjes.491791

Abstract

Kalsiyum ve Magnezyum
elementlerinin (+2) değerlikli iyon halleri sularda sertlik oluşturmaktadır.
İnsan sağlığı açısından ciddi riskler oluşturmasa da sert sular sanayide üretim
kalitesinin düşmesi, boruların ömrünün azalması, sıcak su üreten ya da tüketen
cihazların ömrünün azalması gibi olumsuzluklara sebep olur. Sular CaCO3
eşdeğeri olarak (0 – 75 mg/L) yumuşak, (75 – 150 mg/L) orta sert, (150 – 300
mg/L) sert, ( >300 mg/L) çok sert su şeklinde sınıflandırılmaktadır. Membran
Kapasitif deiyonizasyon (MCDI), sertlik türlerinin giderilmesinde etkili bir
prosestir. Bu çalışmada sertlik gideriminde arıtılmış suyun kullanım alanı da
göz önünde bulundurularak çok sert su sınıfına giren farklı oranlarda Ca2+
ve Mg2+ içeren sular MCDI ile arıtılarak proses suyu ve içme suyu
elde edilmeye çalışılmıştır. Çalışmalar neticesinde 300 mg CaCO3/L sertlik
içeren sular proses suyu üretiminde %90 - %97 aralığında; içme suyu eldesinde
ise %71 - %82 oranlarında arıtılmıştır. Enerji için Maliyet analizi
yapıldığında proses suyu için maliyetler 0,01 – 0,02 $/m3 aralığında
değişirken içme suyu eldesi için bu maliyet 0,009 – 0,016 $/m3
aralığında değişmektedir.

References

  • J. M. Symons, L. C. Bradley, T. C. Cleveland, "The drinking water dictionary", American Water Works Association. Mc Graw Hill, 2000.
  • Ö. F. Tekbaş, G. Mahir, “Suların Sertlik Dereceleri ve Sağlık Etkileri,” TSK Koruyucu Hekim. Bülteni, vol. 3.7, pp. 156–161, 2004.
  • C. Gabrielli, G. Maurin, H. Francy-Chausson, P. Thery, T. T. M. Tran, and M. Tlili, “Electrochemical water softening: principle and application,” Desalination, 2006.
  • J. S. Park, J. H. Song, K. H. Yeon, and S. H. Moon, “Removal of hardness ions from tap water using electromembrane processes,” Desalination, 2007.
  • B. Boysal, F, Şengörür, “Su Sertliğinin İnsan Sağlığı İçin Önemi,” SAÜ Fen Bilim. Derg., vol. 13:1, pp. 7–10, 2009.
  • J. G. Dean, F. L. Bosqui, and K. H. Lanouette, “Removing heavy metals from waste water,” Environ. Sci. Technol., 1972.
  • A. R. Hauck, S. Sourirajan, “Performance of porous cellulose acetate membranes for the reverse osmosis treatment of hard and waste waters,” Environ. Sci. Technol., vol. 3.12, pp. 1269–1275, 1969.
  • M. K. Nagarajan and H. L. Paine, “Water hardness control by detergent builders,” J. Am. Oil Chem. Soc., 1984.
  • B. H. Wiers, R. J. Grosse, and W. a Cilley, “Divalent and trivalent ion exchange with zeolite A.,” Environ. Sci. Technol., 1982.
  • S. Ghizellaoui, A. Chibani, and S. Ghizellaoui, “Use of nanofiltration for partial softening of very hard water,” Desalination, 2005.
  • K. H. Yeon, J. H. Song, and S. H. Moon, “A study on stack configuration of continuous electrodeionization for removal of heavy metal ions from the primary coolant of a nuclear power plant,” Water Res., 2004.
  • J. H. Song, K. H. Yeon, J. Cho, and S. H. Moon, “Effects of the operating parameters on the reverse osmosis- electrodeionization performance in the production of high purity water,” Korean J. Chem. Eng., 2005.
  • P. Čuda, P. Pospíšil, and J. Tenglerová, “Reverse osmosis in water treatment for boilers,” Desalination, 2006.
  • Y. Oren, “Capacitive deionization (CDI) for desalination and water treatment - past, present and future (a review),” Desalination, vol. 228, no. 1–3, pp. 10–29, 2008.
  • S. Porada, R. Zhao, A. Van Der Wal, V. Presser, and P. M. Biesheuvel, “Review on the science and technology of water desalination by capacitive deionization,” Progress in Materials Science. 2013.
  • M. E. Suss, S. Porada, X. Sun, P. M. Biesheuvel, J. Yoon, and V. Presser, “Water desalination via capacitive deionization: What is it and what can we expect from it?,” Energy and Environmental Science. 2015.
  • H. J. Ahn, J. H. Lee, Y. Jeong, J. H. Lee, C. S. Chi, and H. J. Oh, “Nanostructured carbon cloth electrode for desalination from aqueous solutions,” Mater. Sci. Eng. A, 2007.
  • J. F. Farmer, J. C., Fix, D. V., Mack, G. V., Pekala, R. W., & Poco, “Capacitive deionization of NaCl and NaNO3 solutions with carbon aerogel electrodes,” J. Electrochem. Soc., vol. 143(1), p. 159–169., 1996.
  • P. M. Biesheuvel and A. van der Wal, “Membrane capacitive deionization,” J. Memb. Sci., vol. 346, no. 2, pp. 256–262, 2010.
  • J. B. Lee, K. K. Park, H. M. Eum, and C. W. Lee, “Desalination of a thermal power plant wastewater by membrane capacitive deionization,” Desalination, vol. 196, no. 1–3, pp. 125–134, 2006.
  • T. J. Welgemoed and C. F. Schutte, “Capacitive Deionization TechnologyTM: An alternative desalination solution,” Desalination, vol. 183, no. 1–3, pp. 327–340, 2005.
  • H. I. Uzun and E. Debik, “Economical approach to nitrate removal via membrane capacitive deionization,” Sep. Purif. Technol., vol. 209, 2019.
  • P. Długołecki and A. Van Der Wal, “Energy recovery in membrane capacitive deionization,” Environ. Sci. Technol., 2013.
  • E. Debik, H. İ., Uzun, F. İlhan, Y. Avşar, “Yeni Bir Deiyonizasyon Prosesi: Kapasitif Deiyonizasyon,” Uluslararası Katılımlı Çevre Sempozyumu, vol. 1, pp. 172–177, 2014.
  • S. J. Seo, H. Jeon, J. K. Lee, G. Y. Kim, D. Park, H. Nojima, J. Lee, and S. H. Moon, “Investigation on removal of hardness ions by capacitive deionization (CDI) for water softening applications,” Water Res., vol. 44, no. 7, pp. 2267–2275, 2010.
Year 2019, Volume: 7 Issue: 3, 341 - 346, 28.09.2019
https://doi.org/10.21541/apjes.491791

Abstract

References

  • J. M. Symons, L. C. Bradley, T. C. Cleveland, "The drinking water dictionary", American Water Works Association. Mc Graw Hill, 2000.
  • Ö. F. Tekbaş, G. Mahir, “Suların Sertlik Dereceleri ve Sağlık Etkileri,” TSK Koruyucu Hekim. Bülteni, vol. 3.7, pp. 156–161, 2004.
  • C. Gabrielli, G. Maurin, H. Francy-Chausson, P. Thery, T. T. M. Tran, and M. Tlili, “Electrochemical water softening: principle and application,” Desalination, 2006.
  • J. S. Park, J. H. Song, K. H. Yeon, and S. H. Moon, “Removal of hardness ions from tap water using electromembrane processes,” Desalination, 2007.
  • B. Boysal, F, Şengörür, “Su Sertliğinin İnsan Sağlığı İçin Önemi,” SAÜ Fen Bilim. Derg., vol. 13:1, pp. 7–10, 2009.
  • J. G. Dean, F. L. Bosqui, and K. H. Lanouette, “Removing heavy metals from waste water,” Environ. Sci. Technol., 1972.
  • A. R. Hauck, S. Sourirajan, “Performance of porous cellulose acetate membranes for the reverse osmosis treatment of hard and waste waters,” Environ. Sci. Technol., vol. 3.12, pp. 1269–1275, 1969.
  • M. K. Nagarajan and H. L. Paine, “Water hardness control by detergent builders,” J. Am. Oil Chem. Soc., 1984.
  • B. H. Wiers, R. J. Grosse, and W. a Cilley, “Divalent and trivalent ion exchange with zeolite A.,” Environ. Sci. Technol., 1982.
  • S. Ghizellaoui, A. Chibani, and S. Ghizellaoui, “Use of nanofiltration for partial softening of very hard water,” Desalination, 2005.
  • K. H. Yeon, J. H. Song, and S. H. Moon, “A study on stack configuration of continuous electrodeionization for removal of heavy metal ions from the primary coolant of a nuclear power plant,” Water Res., 2004.
  • J. H. Song, K. H. Yeon, J. Cho, and S. H. Moon, “Effects of the operating parameters on the reverse osmosis- electrodeionization performance in the production of high purity water,” Korean J. Chem. Eng., 2005.
  • P. Čuda, P. Pospíšil, and J. Tenglerová, “Reverse osmosis in water treatment for boilers,” Desalination, 2006.
  • Y. Oren, “Capacitive deionization (CDI) for desalination and water treatment - past, present and future (a review),” Desalination, vol. 228, no. 1–3, pp. 10–29, 2008.
  • S. Porada, R. Zhao, A. Van Der Wal, V. Presser, and P. M. Biesheuvel, “Review on the science and technology of water desalination by capacitive deionization,” Progress in Materials Science. 2013.
  • M. E. Suss, S. Porada, X. Sun, P. M. Biesheuvel, J. Yoon, and V. Presser, “Water desalination via capacitive deionization: What is it and what can we expect from it?,” Energy and Environmental Science. 2015.
  • H. J. Ahn, J. H. Lee, Y. Jeong, J. H. Lee, C. S. Chi, and H. J. Oh, “Nanostructured carbon cloth electrode for desalination from aqueous solutions,” Mater. Sci. Eng. A, 2007.
  • J. F. Farmer, J. C., Fix, D. V., Mack, G. V., Pekala, R. W., & Poco, “Capacitive deionization of NaCl and NaNO3 solutions with carbon aerogel electrodes,” J. Electrochem. Soc., vol. 143(1), p. 159–169., 1996.
  • P. M. Biesheuvel and A. van der Wal, “Membrane capacitive deionization,” J. Memb. Sci., vol. 346, no. 2, pp. 256–262, 2010.
  • J. B. Lee, K. K. Park, H. M. Eum, and C. W. Lee, “Desalination of a thermal power plant wastewater by membrane capacitive deionization,” Desalination, vol. 196, no. 1–3, pp. 125–134, 2006.
  • T. J. Welgemoed and C. F. Schutte, “Capacitive Deionization TechnologyTM: An alternative desalination solution,” Desalination, vol. 183, no. 1–3, pp. 327–340, 2005.
  • H. I. Uzun and E. Debik, “Economical approach to nitrate removal via membrane capacitive deionization,” Sep. Purif. Technol., vol. 209, 2019.
  • P. Długołecki and A. Van Der Wal, “Energy recovery in membrane capacitive deionization,” Environ. Sci. Technol., 2013.
  • E. Debik, H. İ., Uzun, F. İlhan, Y. Avşar, “Yeni Bir Deiyonizasyon Prosesi: Kapasitif Deiyonizasyon,” Uluslararası Katılımlı Çevre Sempozyumu, vol. 1, pp. 172–177, 2014.
  • S. J. Seo, H. Jeon, J. K. Lee, G. Y. Kim, D. Park, H. Nojima, J. Lee, and S. H. Moon, “Investigation on removal of hardness ions by capacitive deionization (CDI) for water softening applications,” Water Res., vol. 44, no. 7, pp. 2267–2275, 2010.
There are 25 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Articles
Authors

Halil İbrahim Uzun 0000-0001-6158-743X

Eyüp Debik

Publication Date September 28, 2019
Submission Date December 3, 2018
Published in Issue Year 2019 Volume: 7 Issue: 3

Cite

IEEE H. İ. Uzun and E. Debik, “Membran Kapasitif Deiyonizasyon Prosesi ile Sertlik Giderimi”, APJES, vol. 7, no. 3, pp. 341–346, 2019, doi: 10.21541/apjes.491791.