Removal of diazo-dye Direct Blue 2 (DB2) in aqueus solution by P(HEMA) nanoparticles

Abstract

In this work, the adsorption of diazo-dye Direct Blue 2 (DB2) in aqueus solution were worked by poly(hydroxyethyl methacrilate) [P(HEMA)].  The effect of pH, temperature, initial dye concentration and contact time to adsorption were investigated.  Under optimum conditions, 50 mg/mL initial dye concentration and 2 mg of polymer were used and removal of dye was obtained as 89.1 % .  To understand the adsorption mechanism, Langmuir, Freundlich and Sips (Langmuir-Freundlich) isotherm constants were calculated.  According to the data obtained, it was reported that the adsorption was suitable for Langmuir isotherm model (R2: 0.993, Qmax: 27.1 mg/g).  Concentrations of dye were measured before and after adsorption by UV-Vis spectrophotometer, polymer was characterized by FTIR and SEM before and after adsorption. 

Keywords

• rect Blue 2,P(HEMA),adsorption,nanoparticle

Direct Blue 2 diazo-boyarmaddesinin sulu çözeltiden P(HEMA) nanopartiküller ile uzaklaştırılması

Abstract

Bu çalışmada, Direct Blue 2 (DB2) diazo-boyar maddesinin poli(Hidroksietil metakrilat) [P(HEMA)] nanopartikülleri ile sulu çözeltiden giderimi çalışılmıştır.  Adsorpsiyona ortam pH’ının, sıcaklığın, başlangıç boya derişiminin ve temas süresinin etkileri incelenmiştir.  Optimum koşullar altında, 50 mg/mL başlangıç boya derişimi ve 2 mg polimer kullanılarak % 89.1 giderim elde edilmiştir.  Adsorpsiyon mekanizmasının anlaşılabilmesi için Langmuir, Freundlich ve Sips (Langmuir-Freundlich) izoterm sabitleri hesaplanmıştır.  Elde edilen verilere göre adsorpsiyonun Langmuir izoterm modeline uygun olduğu (R2: 0.993, Qmax: 27.1 mg/g) rapor edilmiştir.  Adsorpsiyon öncesi ve sonrası boya derişimleri UV-Vis spektrofotometresinde ölçülmüş, adsorpsiyon öncesi ve sonrası polimer FTIR ve SEM ile karakterize edilmiştir. 

Keywords

• Direct Blue 2,P(HEMA),adsorpsiyon,nanopartikül

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