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Bazı Yeni İmin Bileşiklerinin Sentezi Ve Spektroskopik Yöntemlerle Yapılarının Aydınlatılması

Year 2005, Volume: 7 Issue: 2, 4 - 11, 01.12.2005

Abstract

3-Metoksi-4-hidroksibenzaldehit (vanilin), 3,4-dimetoksibenzaldehit (veratraldehit) ve pirol-2karboksaldehit’in, 2-aminometilfuran (furfurilamin) ve 4-amino-1,2-dihidro-1,5-dimetil-2-metil-3Hpirazol-3-on (4-amino-fenazon, 4-aminoantipirin, 4-AAP) ile kondensasyanundan yeni Schiff bazları elde edilmiştir. Sentezlenen bu bileşiklerin yapıları element analizi, IR, 1H, 13C-NMR ve MS spektroskopik yöntemleri ile aydınlatılmıştır

References

  • [1] Park, S., Mathur, V. K. and Planalp, Roy P., “Syntheses, Solubilities and Oxygen Absorption Properties of New Cobalt(II) Schiff Base Complexes” Polyhedron, 17: (2-3), 325-330, (1998).
  • [2] Lu, X., Qin, S. Y., Zhou, Z. Y. and Yam, V. W. W. “Synthesis, Structure, and Ion-Binding Studies of Cobalt(II) Complexes with Aza-crown Substituted Salicylaldimine Schiff Base Ligand” Inorganica Chimica Acta, 346: (25) 49-56, (2003).
  • [3] Olie, G. H., Olive, S., “The Chemistry of The Catalyzes Hydrogenation of Carbon Monoxide” Springer, Berlin, 152, (1984).
  • [4] Rahaman, S. H., Choowdhury, H., Bose, D., Ghosh, R., Chen-Hsing, G., Barindra Kumar Ghosh, H., “Synthesis, Structure and Properties of Mononuclear Cobalt (II) and Cobalt (III) Pseudohalide Complexes Containing N-Donor Schiff Bases: Synthetic Control of Metal Oxidation Levels” Polyhedron, 24: 1755-1763, (2005).
  • [5] Kunkely, H. and Vogler, A. “Photochemistry of N, N′-Bis(3,5-di-tertbutylsalicylidene)-1,2-Diaminocyclohexane and its Co(II) Complex in Chloroform” Journal of Photochemistry and Photobiology A: Chemistry, 138: 51-54, (2001).
  • [6] Mederos, A., Domínguez, S., Hernández-Molina, R., Sanchiz J. and Brito, F., “Coordinating Ability of Ligands Derived From Phenylenediamines” Coordination Chemistry Reviews, 193-195: 857-911, (1999).
  • [7] Hökelek, T., Gündüz, N., Hayvalı, Z. and Kılıç, Z., “Schiff Bases and Their Complexes with Metal Ions. I. 2-Hydroxy-N-n-propyl-1-naphthaldimine (1) and Bis(2-hydroxy-κO-N-n-propyl-1-naphthaldiminato-κN)Nickel(II) (2),” Acta Cryst., C51, 880-884, (1995).
  • [8] Hökelek, T., Gündüz, N., Hayvalı, Z. and Kılıç, Z., “Schiff Bases and Their Complexes with Metal Ions. Part II. Structures of N-n-butyl-2-hydroxy-1- naphthaldimine and Bis[N-n-pentyl-2-hydroxy-1-naphthaldiminato]nickel(II),” J. of Chemical Crystallography, 25: (12), 827-832, (1995).
  • [9] Hayvalı, Z., Gündüz, N., Kılıç, Z. ve Weber, E., “Synthesis and Characterization of New Bis(crown ether)s of Schiff Base Type Containing Recognition Sites For Sodium And Nickel Guest Cations,” J. Prakt. Chem., 341: (6), 568-573, (1999).
  • [10] Zeng, W., Mao, Z., Wei, X., Li, J., Hong, Z. and Qin, S., “Synthesis, Dioxygen Affinities And Biomimetic Catalytic Oxidation Performance of Crown Ethertethered Schiff Base Transition-Metal Complexes” Journal of Supramolecular Chemistry, 2: (6), 501-507, (2002).
  • [11] Yıldız, M., Hayvalı, Z. ve Kılıç, Z. “Synthesis and Characterization of Some Novel Bis(crown ether) Ligands of Schiff Base Type,” Gazi Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 14: (3), 869-876, (2001).
  • [12] Hayvalı, Z., Hayvalı, M., Kılıç, Z., Hökelek, T. ve Weber, E., “New Benzo-15- crow-5 Ethers Featuring Salicylic Schiff Base Substitutions Synthesis, Complexes and Structural Study,” J. of Inclusion Phenomena and Macrocyclic Chemistry, 45: 285-294, (2003).
  • [13] Hayvalı, M. ve Hayvalı, Z., “The Synthesis of Some New Mono and bis(Crown Ether)s and Their Sodium Complexes. Tautomerism in o-Hydroxybenzo-15- crown-5 Schiff Bases as Studied by UV-VIS Spectrophotometry,” Synthesis.and Reactivity in Inorganic and Metal-Organic Chemistry, 34: (4), 713-732, (2004).
  • [14] Hayvalı, Z., Hayvalı, M. and Dal, H., “Synthesis, and Spectroscopic Characterization of New Schiff Bases Containing the Benzo-15-Crown-5 Moiety”, Molecules, 9: 860-866, (2004).
  • [15] Ismail, Z. K., El-Dissouky, A. and Shehada, A.Z., “Spectroscopic And Magnetic Studies on Some Copper (II) Complexes of Antipyrine Schiff Base Derivatives” Polyhedron, 16: (17), 2909-2916, (1997).
  • [16] Higasio, Ya S. and Shoji, T., “Heterocyclic Compounds Such as Pyrroles, Pyridines, Pyrollidins, Piperdines, Indoles, Imidazol And Pyrazins” Applied Catalysis A: General, 221: 1-2, (30), 197-207, (2001).
  • [17] Kumar, K. N. and Ramesh, R., “Synthesis, Characterization, Redox Property and Biological Activity of Ru(II) Carbonyl Complexes Containing O,N-Donor Ligands And Heterocyclic Bases” Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 60: (12), 2913-2918, (2004).
  • [18] Juhász, L., Dinya, Z., Antus, S. and Gunda, T. E., “A New Approach For The Synthesis of Naturally Occurring Dihydrobenzo[b]furan-type Neolignans of Potential Biological Activity” Tetrahedron Letters, 41: (14), 2491-2494, (2000).
  • [19] Emregül, K. C. and Hayvali, M. “Studies on The Effect of a Newly Synthesized Schiff Base Compound From Phenazone And Vanillin on The Corrosion of Steel in 2M HCl” Corrosion Science, baskıda, (2005).
  • [20] El-Dissouky, A., Shehata, A. K. And El-Mahdey, G., “Synthesis And Characterization of Oxovanadium (IV) And Dichloro Vanadium (IV) Complexes of Biologically Active 4-Aminoantipyrine Derivatives” Polyhedron, 16: (7), 1247-1253, (1997)
Year 2005, Volume: 7 Issue: 2, 4 - 11, 01.12.2005

Abstract

The new Schiff bases were synthesized by condensation of 3-Methoxy-4-hydroxybenzaldehyde (vanilline), 3,4-dimethoxybenzaldehyde (veratraldehyde) and pyrol-2-carboxaldehyde with 2aminomethylfuran (furfurylamine) and 4-amino-1,2-dihydro-1,5-dimethyl-2-phenyl-3H-pyrazole-3-one (4-amino-phenazone, 4-aminoantipyrine, 4-AAP). The structure of these compounds has been elucidated on the basis of elemental analysis, IR, 1H, 13C-NMR and MS spectroscopic techniques

References

  • [1] Park, S., Mathur, V. K. and Planalp, Roy P., “Syntheses, Solubilities and Oxygen Absorption Properties of New Cobalt(II) Schiff Base Complexes” Polyhedron, 17: (2-3), 325-330, (1998).
  • [2] Lu, X., Qin, S. Y., Zhou, Z. Y. and Yam, V. W. W. “Synthesis, Structure, and Ion-Binding Studies of Cobalt(II) Complexes with Aza-crown Substituted Salicylaldimine Schiff Base Ligand” Inorganica Chimica Acta, 346: (25) 49-56, (2003).
  • [3] Olie, G. H., Olive, S., “The Chemistry of The Catalyzes Hydrogenation of Carbon Monoxide” Springer, Berlin, 152, (1984).
  • [4] Rahaman, S. H., Choowdhury, H., Bose, D., Ghosh, R., Chen-Hsing, G., Barindra Kumar Ghosh, H., “Synthesis, Structure and Properties of Mononuclear Cobalt (II) and Cobalt (III) Pseudohalide Complexes Containing N-Donor Schiff Bases: Synthetic Control of Metal Oxidation Levels” Polyhedron, 24: 1755-1763, (2005).
  • [5] Kunkely, H. and Vogler, A. “Photochemistry of N, N′-Bis(3,5-di-tertbutylsalicylidene)-1,2-Diaminocyclohexane and its Co(II) Complex in Chloroform” Journal of Photochemistry and Photobiology A: Chemistry, 138: 51-54, (2001).
  • [6] Mederos, A., Domínguez, S., Hernández-Molina, R., Sanchiz J. and Brito, F., “Coordinating Ability of Ligands Derived From Phenylenediamines” Coordination Chemistry Reviews, 193-195: 857-911, (1999).
  • [7] Hökelek, T., Gündüz, N., Hayvalı, Z. and Kılıç, Z., “Schiff Bases and Their Complexes with Metal Ions. I. 2-Hydroxy-N-n-propyl-1-naphthaldimine (1) and Bis(2-hydroxy-κO-N-n-propyl-1-naphthaldiminato-κN)Nickel(II) (2),” Acta Cryst., C51, 880-884, (1995).
  • [8] Hökelek, T., Gündüz, N., Hayvalı, Z. and Kılıç, Z., “Schiff Bases and Their Complexes with Metal Ions. Part II. Structures of N-n-butyl-2-hydroxy-1- naphthaldimine and Bis[N-n-pentyl-2-hydroxy-1-naphthaldiminato]nickel(II),” J. of Chemical Crystallography, 25: (12), 827-832, (1995).
  • [9] Hayvalı, Z., Gündüz, N., Kılıç, Z. ve Weber, E., “Synthesis and Characterization of New Bis(crown ether)s of Schiff Base Type Containing Recognition Sites For Sodium And Nickel Guest Cations,” J. Prakt. Chem., 341: (6), 568-573, (1999).
  • [10] Zeng, W., Mao, Z., Wei, X., Li, J., Hong, Z. and Qin, S., “Synthesis, Dioxygen Affinities And Biomimetic Catalytic Oxidation Performance of Crown Ethertethered Schiff Base Transition-Metal Complexes” Journal of Supramolecular Chemistry, 2: (6), 501-507, (2002).
  • [11] Yıldız, M., Hayvalı, Z. ve Kılıç, Z. “Synthesis and Characterization of Some Novel Bis(crown ether) Ligands of Schiff Base Type,” Gazi Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 14: (3), 869-876, (2001).
  • [12] Hayvalı, Z., Hayvalı, M., Kılıç, Z., Hökelek, T. ve Weber, E., “New Benzo-15- crow-5 Ethers Featuring Salicylic Schiff Base Substitutions Synthesis, Complexes and Structural Study,” J. of Inclusion Phenomena and Macrocyclic Chemistry, 45: 285-294, (2003).
  • [13] Hayvalı, M. ve Hayvalı, Z., “The Synthesis of Some New Mono and bis(Crown Ether)s and Their Sodium Complexes. Tautomerism in o-Hydroxybenzo-15- crown-5 Schiff Bases as Studied by UV-VIS Spectrophotometry,” Synthesis.and Reactivity in Inorganic and Metal-Organic Chemistry, 34: (4), 713-732, (2004).
  • [14] Hayvalı, Z., Hayvalı, M. and Dal, H., “Synthesis, and Spectroscopic Characterization of New Schiff Bases Containing the Benzo-15-Crown-5 Moiety”, Molecules, 9: 860-866, (2004).
  • [15] Ismail, Z. K., El-Dissouky, A. and Shehada, A.Z., “Spectroscopic And Magnetic Studies on Some Copper (II) Complexes of Antipyrine Schiff Base Derivatives” Polyhedron, 16: (17), 2909-2916, (1997).
  • [16] Higasio, Ya S. and Shoji, T., “Heterocyclic Compounds Such as Pyrroles, Pyridines, Pyrollidins, Piperdines, Indoles, Imidazol And Pyrazins” Applied Catalysis A: General, 221: 1-2, (30), 197-207, (2001).
  • [17] Kumar, K. N. and Ramesh, R., “Synthesis, Characterization, Redox Property and Biological Activity of Ru(II) Carbonyl Complexes Containing O,N-Donor Ligands And Heterocyclic Bases” Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 60: (12), 2913-2918, (2004).
  • [18] Juhász, L., Dinya, Z., Antus, S. and Gunda, T. E., “A New Approach For The Synthesis of Naturally Occurring Dihydrobenzo[b]furan-type Neolignans of Potential Biological Activity” Tetrahedron Letters, 41: (14), 2491-2494, (2000).
  • [19] Emregül, K. C. and Hayvali, M. “Studies on The Effect of a Newly Synthesized Schiff Base Compound From Phenazone And Vanillin on The Corrosion of Steel in 2M HCl” Corrosion Science, baskıda, (2005).
  • [20] El-Dissouky, A., Shehata, A. K. And El-Mahdey, G., “Synthesis And Characterization of Oxovanadium (IV) And Dichloro Vanadium (IV) Complexes of Biologically Active 4-Aminoantipyrine Derivatives” Polyhedron, 16: (7), 1247-1253, (1997)
There are 20 citations in total.

Details

Other ID JA22DM74PV
Journal Section Research Articles
Authors

Zeliha Hayvalı This is me

Publication Date December 1, 2005
Submission Date December 1, 2005
Published in Issue Year 2005 Volume: 7 Issue: 2

Cite

APA Hayvalı, Z. (2005). Bazı Yeni İmin Bileşiklerinin Sentezi Ve Spektroskopik Yöntemlerle Yapılarının Aydınlatılması. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 7(2), 4-11.
AMA Hayvalı Z. Bazı Yeni İmin Bileşiklerinin Sentezi Ve Spektroskopik Yöntemlerle Yapılarının Aydınlatılması. BAUN Fen. Bil. Enst. Dergisi. December 2005;7(2):4-11.
Chicago Hayvalı, Zeliha. “Bazı Yeni İmin Bileşiklerinin Sentezi Ve Spektroskopik Yöntemlerle Yapılarının Aydınlatılması”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 7, no. 2 (December 2005): 4-11.
EndNote Hayvalı Z (December 1, 2005) Bazı Yeni İmin Bileşiklerinin Sentezi Ve Spektroskopik Yöntemlerle Yapılarının Aydınlatılması. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 7 2 4–11.
IEEE Z. Hayvalı, “Bazı Yeni İmin Bileşiklerinin Sentezi Ve Spektroskopik Yöntemlerle Yapılarının Aydınlatılması”, BAUN Fen. Bil. Enst. Dergisi, vol. 7, no. 2, pp. 4–11, 2005.
ISNAD Hayvalı, Zeliha. “Bazı Yeni İmin Bileşiklerinin Sentezi Ve Spektroskopik Yöntemlerle Yapılarının Aydınlatılması”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 7/2 (December 2005), 4-11.
JAMA Hayvalı Z. Bazı Yeni İmin Bileşiklerinin Sentezi Ve Spektroskopik Yöntemlerle Yapılarının Aydınlatılması. BAUN Fen. Bil. Enst. Dergisi. 2005;7:4–11.
MLA Hayvalı, Zeliha. “Bazı Yeni İmin Bileşiklerinin Sentezi Ve Spektroskopik Yöntemlerle Yapılarının Aydınlatılması”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 7, no. 2, 2005, pp. 4-11.
Vancouver Hayvalı Z. Bazı Yeni İmin Bileşiklerinin Sentezi Ve Spektroskopik Yöntemlerle Yapılarının Aydınlatılması. BAUN Fen. Bil. Enst. Dergisi. 2005;7(2):4-11.