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Determination of mechanical and tribological performance of polyamide-6 composites with wollastonite and kaolin filler

Year 2020, Volume: 22 Issue: 2, 617 - 627, 10.04.2020
https://doi.org/10.25092/baunfbed.742675

Abstract

In this experimental study, mechanical and tribological behaviors of unfilled polyamide-6 (PA-6) polymer, 10wt.% of wollastonite and 10wt.% kaolin filled polyamide-6 based polymer composites have been studied. Polyamide-6 based polymer composites are produced in granular form on an industrial twin screw extruder machine. The mechanical and tribological test samples used in the experiments were molded using a conventional type an injection molding machine. The wear and friction behaviors of unfilled PA-6 polymer and PA-6 composites were carried out in the pin-disc wear device and under dry sliding conditions. Wear and friction behaviors were performed at a sliding speed of 0.5 m/s and under the loads of 60N, 120N and 180N. As a result of the study, when wollastonite and kaolin additives are added to the PA-6 based polymer, tensile strength and elastic modulus values of composite materials increase while coefficient of friction and specific wear rate values decrease. In addition, both coefficient of friction and specific wear rate values of all materials used decreased with the increase in applied load in tribological tests.

References

  • Kodal, M., Erturk, S., Sanli, S., Ozkoc, G., Properties of Talc/Wollastonite/Polyamide 6 Hybrid Composites, Polymer Composites, 36(4), 739-746, (2015).
  • Yue, Q., Hongfeng, Y., Yun, T., Jinshi, B., Yan, L., Huodie, Y., Mechanical properties of the nano-CaCO3 and GB coreinforced CF/PA6 composites, Materials Research Express, 6(10), 1-12, (2019).
  • Gang, T., Wangjuan, H., Daofang, C., Wenzhong, N., Weijian, M., Wei, Y., The Friction and Wear of Aramid Fiber-Reinforced Polyamide 6 Composites Filled with Nano-MoS2, Polymer-Plastics Technology and Engineering, 50, 1537-1540, (2011).
  • Aslan, Ç., Ahmet, D., Ferit, F., Optimization of Wear Parameters of Polyamide-6 Composite Materials Filled with Wollastonite Particles, Perıodicals of Engineering and Natural Sciences, 2(1), 1-6, (2014).
  • Mimaroglu, A., Sen, U., Unal, H., Abrasive Wear Volume Maps for PA6 and PA6 Composites Under Dry Working Condition, Applied Composite Materials, 15, 13-25, (2008).
  • Unal, H., Mimaroglu, A., Alkan, M., Mechanical properties and morphology of nylon-6 hybrid composites, Polymer International, 53, 56-60, (2004).
  • Capela,C., Ferreira, J.M., Costa, J.M., Mendes, N., Mechanical Properties of Injection-Molded Glass Microsphere-Reinforced Polyamide, Journal of Materials Engineering and Performance, 25, 4256-4265, (2016).
  • Unal, H., Fındık, F., Mimaroglu, A., Mechanical Behaviour of Nylon Composites Containing Talc and Kaolin, Journal of Applied Polymer Science, 88, 1694-1697, (2003).
  • Unal, Η., Performance of Polyamide-6/Wollastonite/Kaolin Hybrid Composites, Science and Engineering of Composite Materials, 10(6), 407-414, (2002).
  • Gustavo, D.D., Adriana M.C.de S., Influence of reprocessing on the mechanical properties of polyamide 6 containing talc, AIP Conference Proceedings, 1779, 1-4, (2016).
  • Hadal, R., Dasari, A., Rohrmann, J., Misra, R.D.K., Susceptibility to scratch surface damage of wollastonite- and talc-containing polypropylene micrometric composites, Materials Science and Engineering A, 380(1), 326-339, (2004).
  • Kumar, V., Manohar, S.S., Kanungo, B.K., Shishir, S., Effect of Various Additives on Mechanical Properties of Rice Husk Polypropylene (RHPP) Composites, Journal of Polymer Engineering, 32(3), 163-166, (2012).
  • Sudeepan, J., Kumar, K., Barman, T.K., Sahoo, P., Study of Friction and Wear Properties of ABS/Kaolin Polymer Composites Using Grey Relational Technique, Procedia Technology,14, 196-203, (2014).
  • Sleptsova,S.A., Laukkanen, S., Gladkina, N.P., Fedoseeva, V.I., Okhlopkova, A.A., Grigoryeva, L.A., Effect of Kaolinite on the Properties and Structure of PTFE, AIP Conference Proceedings, 2053, 040092, (2018).
  • Mei, L., Yaoguang, C., Lijun, W., Zishou, Z., Kancheng, M., A novel polypropylene composite filled by kaolin particles with β-nucleation, Journal of Thermal Analysis and Calorimetry, 135, 2137-2145, (2019).
  • Tej, S., Avinash, T., Amar, P., Ranchan, C., Sharafat, A., Influence of wollastonite shape and amount on tribo-performance of non-asbestos organic brake friction composites, Wear, 386-387, 157-164, (2017).
  • Lubomir, La., David, M., Barbora, L., Martin, V., Michal, S., Klara, C., Jakub, V., Kristian, E.W., Richard, W.G., Neil, A.R., Effect of filler particle shape on plastic-elastic mechanical behavior of high density poly(ethylene)/mica and poly(ethylene)/wollastonite composites, Composites Part B: Engineering, 141, 92-99, (2018).
  • Iztok, S., Vojko, M., Mirela, L., The Adhesion Phenomena in Polypropylene/Wollastonite Composites, Acta Chimica Slovenica, 52, 264-271, (2005).
  • Rohit, S.T., Prakash, A.M., Mechanical, Thermal and Morphological Properties of Recycled and Virgin PC/ wollastonite Composite and its Compatibilization by SBC, Journal of Materials and Environmental Sciences, 10(4), 357-366, (2019).
  • Guofang, G., Yang, H., Fu, X., Tribological properties of kaolin filled UHMWPE composites in unlubricated sliding, Wear, 256, 88–94, 2004.
  • Tong, J., Yunhai, M., Man, J., Effects of the wollastonite fiber modification on the sliding wear behavior of the UHMWPE composites, Wear, 255, 734-741, (2003).
  • Akıncı, A., Dry sliding friction and wear behaviour of self-lubricating wollastonite filled polycarbonate composites, Industrial Lubrication and Tribology, 67(1), 22-29, (2015).
  • Nizar, J.H., Ammar, Al-K., Ahmed, F.H., Dhey, J.M., New Approach to Predict Mechanical and Tribological Behaviour Through Rheological Properties of Polypropylene Composites, 9th International Conference on Mechanical and Aerospace Engineering (ICMAE 2018), 556-560, 10-13 July 2018, Budapest, Hungary.

Vollastonit ve kaolin katkılı poliamid-6 esaslı kompozitlerin mekanik ve tribolojik performanslarının belirlenmesi

Year 2020, Volume: 22 Issue: 2, 617 - 627, 10.04.2020
https://doi.org/10.25092/baunfbed.742675

Abstract

Bu çalışmada, katkısız poliamid 6 (PA-6) ile ağırlık olarak ayrı ayrı %10 oranında vollastonit ve kaolin katkılı poliamid-6 esaslı polimer kompozitlerin mekanik ve tribolojik özellikleri incelenmiştir. Poliamid-6 esaslı polimer kompozitler, endüstriyel tip ikiz vidalı bir ekstrüder makinesinde granül formda üretilmiştir. Deneylerde kullanılan mekanik ve tribolojik test numuneleri geleneksel enjeksiyon makinesi kullanılarak basılmıştır. Katkısız PA-6 ve PA-6 kompozitlerin aşınma ve sürtünme davranışları pim-disk aşınma cihazında ve kuru kayma şartları altında gerçekleştirilmiştir. Aşınma ve sürtünme davranışları 0.5m/s kayma hızında ve 60N, 120N ve 180N yükler altında yapılmıştır. Çalışma sonucunda, PA-6 polimerine ilave edilen vollastonit ve kaolin katkılar, kompozit malzemelerin çekme dayanımı ve elastiklik modülünü değerlerini artırırken sürtünme katsayısı ve spesifik aşınma hızı değerlerinin azalmasına sebep olmuştur. Buna ilave olarak, tribolojik deneylerde uygulanan yükün artması ile tüm malzemelerin hem sürtünme katsayısı hem de spesifik aşınma hızı değerleri azalmıştır.

References

  • Kodal, M., Erturk, S., Sanli, S., Ozkoc, G., Properties of Talc/Wollastonite/Polyamide 6 Hybrid Composites, Polymer Composites, 36(4), 739-746, (2015).
  • Yue, Q., Hongfeng, Y., Yun, T., Jinshi, B., Yan, L., Huodie, Y., Mechanical properties of the nano-CaCO3 and GB coreinforced CF/PA6 composites, Materials Research Express, 6(10), 1-12, (2019).
  • Gang, T., Wangjuan, H., Daofang, C., Wenzhong, N., Weijian, M., Wei, Y., The Friction and Wear of Aramid Fiber-Reinforced Polyamide 6 Composites Filled with Nano-MoS2, Polymer-Plastics Technology and Engineering, 50, 1537-1540, (2011).
  • Aslan, Ç., Ahmet, D., Ferit, F., Optimization of Wear Parameters of Polyamide-6 Composite Materials Filled with Wollastonite Particles, Perıodicals of Engineering and Natural Sciences, 2(1), 1-6, (2014).
  • Mimaroglu, A., Sen, U., Unal, H., Abrasive Wear Volume Maps for PA6 and PA6 Composites Under Dry Working Condition, Applied Composite Materials, 15, 13-25, (2008).
  • Unal, H., Mimaroglu, A., Alkan, M., Mechanical properties and morphology of nylon-6 hybrid composites, Polymer International, 53, 56-60, (2004).
  • Capela,C., Ferreira, J.M., Costa, J.M., Mendes, N., Mechanical Properties of Injection-Molded Glass Microsphere-Reinforced Polyamide, Journal of Materials Engineering and Performance, 25, 4256-4265, (2016).
  • Unal, H., Fındık, F., Mimaroglu, A., Mechanical Behaviour of Nylon Composites Containing Talc and Kaolin, Journal of Applied Polymer Science, 88, 1694-1697, (2003).
  • Unal, Η., Performance of Polyamide-6/Wollastonite/Kaolin Hybrid Composites, Science and Engineering of Composite Materials, 10(6), 407-414, (2002).
  • Gustavo, D.D., Adriana M.C.de S., Influence of reprocessing on the mechanical properties of polyamide 6 containing talc, AIP Conference Proceedings, 1779, 1-4, (2016).
  • Hadal, R., Dasari, A., Rohrmann, J., Misra, R.D.K., Susceptibility to scratch surface damage of wollastonite- and talc-containing polypropylene micrometric composites, Materials Science and Engineering A, 380(1), 326-339, (2004).
  • Kumar, V., Manohar, S.S., Kanungo, B.K., Shishir, S., Effect of Various Additives on Mechanical Properties of Rice Husk Polypropylene (RHPP) Composites, Journal of Polymer Engineering, 32(3), 163-166, (2012).
  • Sudeepan, J., Kumar, K., Barman, T.K., Sahoo, P., Study of Friction and Wear Properties of ABS/Kaolin Polymer Composites Using Grey Relational Technique, Procedia Technology,14, 196-203, (2014).
  • Sleptsova,S.A., Laukkanen, S., Gladkina, N.P., Fedoseeva, V.I., Okhlopkova, A.A., Grigoryeva, L.A., Effect of Kaolinite on the Properties and Structure of PTFE, AIP Conference Proceedings, 2053, 040092, (2018).
  • Mei, L., Yaoguang, C., Lijun, W., Zishou, Z., Kancheng, M., A novel polypropylene composite filled by kaolin particles with β-nucleation, Journal of Thermal Analysis and Calorimetry, 135, 2137-2145, (2019).
  • Tej, S., Avinash, T., Amar, P., Ranchan, C., Sharafat, A., Influence of wollastonite shape and amount on tribo-performance of non-asbestos organic brake friction composites, Wear, 386-387, 157-164, (2017).
  • Lubomir, La., David, M., Barbora, L., Martin, V., Michal, S., Klara, C., Jakub, V., Kristian, E.W., Richard, W.G., Neil, A.R., Effect of filler particle shape on plastic-elastic mechanical behavior of high density poly(ethylene)/mica and poly(ethylene)/wollastonite composites, Composites Part B: Engineering, 141, 92-99, (2018).
  • Iztok, S., Vojko, M., Mirela, L., The Adhesion Phenomena in Polypropylene/Wollastonite Composites, Acta Chimica Slovenica, 52, 264-271, (2005).
  • Rohit, S.T., Prakash, A.M., Mechanical, Thermal and Morphological Properties of Recycled and Virgin PC/ wollastonite Composite and its Compatibilization by SBC, Journal of Materials and Environmental Sciences, 10(4), 357-366, (2019).
  • Guofang, G., Yang, H., Fu, X., Tribological properties of kaolin filled UHMWPE composites in unlubricated sliding, Wear, 256, 88–94, 2004.
  • Tong, J., Yunhai, M., Man, J., Effects of the wollastonite fiber modification on the sliding wear behavior of the UHMWPE composites, Wear, 255, 734-741, (2003).
  • Akıncı, A., Dry sliding friction and wear behaviour of self-lubricating wollastonite filled polycarbonate composites, Industrial Lubrication and Tribology, 67(1), 22-29, (2015).
  • Nizar, J.H., Ammar, Al-K., Ahmed, F.H., Dhey, J.M., New Approach to Predict Mechanical and Tribological Behaviour Through Rheological Properties of Polypropylene Composites, 9th International Conference on Mechanical and Aerospace Engineering (ICMAE 2018), 556-560, 10-13 July 2018, Budapest, Hungary.
There are 23 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Research Articles
Authors

Hüseyin Ünal This is me 0000-0003-0521-6647

S. Hakan Yetgin This is me 0000-0002-6068-9204

Publication Date April 10, 2020
Submission Date January 21, 2020
Published in Issue Year 2020 Volume: 22 Issue: 2

Cite

APA Ünal, H., & Yetgin, S. H. (2020). Vollastonit ve kaolin katkılı poliamid-6 esaslı kompozitlerin mekanik ve tribolojik performanslarının belirlenmesi. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 22(2), 617-627. https://doi.org/10.25092/baunfbed.742675
AMA Ünal H, Yetgin SH. Vollastonit ve kaolin katkılı poliamid-6 esaslı kompozitlerin mekanik ve tribolojik performanslarının belirlenmesi. BAUN Fen. Bil. Enst. Dergisi. April 2020;22(2):617-627. doi:10.25092/baunfbed.742675
Chicago Ünal, Hüseyin, and S. Hakan Yetgin. “Vollastonit Ve Kaolin katkılı Poliamid-6 Esaslı Kompozitlerin Mekanik Ve Tribolojik performanslarının Belirlenmesi”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22, no. 2 (April 2020): 617-27. https://doi.org/10.25092/baunfbed.742675.
EndNote Ünal H, Yetgin SH (April 1, 2020) Vollastonit ve kaolin katkılı poliamid-6 esaslı kompozitlerin mekanik ve tribolojik performanslarının belirlenmesi. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22 2 617–627.
IEEE H. Ünal and S. H. Yetgin, “Vollastonit ve kaolin katkılı poliamid-6 esaslı kompozitlerin mekanik ve tribolojik performanslarının belirlenmesi”, BAUN Fen. Bil. Enst. Dergisi, vol. 22, no. 2, pp. 617–627, 2020, doi: 10.25092/baunfbed.742675.
ISNAD Ünal, Hüseyin - Yetgin, S. Hakan. “Vollastonit Ve Kaolin katkılı Poliamid-6 Esaslı Kompozitlerin Mekanik Ve Tribolojik performanslarının Belirlenmesi”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22/2 (April 2020), 617-627. https://doi.org/10.25092/baunfbed.742675.
JAMA Ünal H, Yetgin SH. Vollastonit ve kaolin katkılı poliamid-6 esaslı kompozitlerin mekanik ve tribolojik performanslarının belirlenmesi. BAUN Fen. Bil. Enst. Dergisi. 2020;22:617–627.
MLA Ünal, Hüseyin and S. Hakan Yetgin. “Vollastonit Ve Kaolin katkılı Poliamid-6 Esaslı Kompozitlerin Mekanik Ve Tribolojik performanslarının Belirlenmesi”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 22, no. 2, 2020, pp. 617-2, doi:10.25092/baunfbed.742675.
Vancouver Ünal H, Yetgin SH. Vollastonit ve kaolin katkılı poliamid-6 esaslı kompozitlerin mekanik ve tribolojik performanslarının belirlenmesi. BAUN Fen. Bil. Enst. Dergisi. 2020;22(2):617-2.